4.7 Article

Carbon nanofibers decorated with platinum nanoparticles: a novel three-dimensional platform for non-enzymatic sensing of hydrogen peroxide

期刊

MICROCHIMICA ACTA
卷 180, 期 13-14, 页码 1249-1255

出版社

SPRINGER WIEN
DOI: 10.1007/s00604-013-1041-4

关键词

Electrospinning; Pt; CNFs; H2O2 sensor; 3-D architecture

资金

  1. National Natural Science Foundation of China [51203013]
  2. Natural Science Foundation of Jiangsu Educational Department of China [12KJB610001]
  3. Practice and Inovation Trainning Project for Jiangsu College students [JX110152012]

向作者/读者索取更多资源

We have developed a 3-dimensional (3-D) electrochemical sensor for highly sensitive detection of hydrogen peroxide (H2O2). Porous 3-D carbon nanofibers (CNFs), prepared by electrospinning, served as scaffold on a glassy carbon electrode. The 3-D CNFs were functionalized with platinum nanoparticles (Pt-NPs) by in-situ gas-phase decomposition of platinum salts at high temperature. The Pt-NPs act as an electrocatalyst for the decomposition of H2O2. TEM revealed that large amounts of Pt-NPs are deposited in the electrospun CNFs electrode even without using any stabilizer or reducing reagent. The sensor was investigated by cyclic voltammetry and amperometry and displays a good response to H2O2 with a linear range between 10 mu M and 15 mM (R = 0.9994), a low detection limit (3.4 mu M at a signal-to-noise ratio of 3), and a response time of 3 s. The sensor shows excellent stability and selectivity.

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