Article
Chemistry, Multidisciplinary
Linna Liu, Boyang Yu, Liangyuqi Kang, Weiwei Deng, Xinyan Zhao
Summary: The study investigates the printing of low-melting-point alloy as top electrodes in organic photovoltaics (OPVs) using blade coating. Field's metal (FM) with a melting point of 62 degrees C is used for the top electrodes due to its ability to be printed at moderate temperatures without damaging the active layers. OPVs with blade-coated FM electrodes achieve a high power conversion efficiency of 17.28% and demonstrate higher thermal stability compared to those with Ag-electrode devices. All-printed OPVs, with FM electrode blade coated and other layers prepared by flexible micro-comb printing, exhibit an efficiency of 16.07%. These results demonstrate the cost-effectiveness and time-saving benefits of printing FM as OPV electrodes.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Yangtai Hao, Jianye Gao, Yonggang Lv, Jing Liu
Summary: This article provides a comprehensive review of the low melting point alloy (LMPA)-enabled stiffness tunable materials. It discusses the material systems, regulation strategies, stiffness regulation modes, and applications of LMPA-enabled stiffness tunable materials. The article also offers a perspective on the potentials and challenges of these materials.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Robert F. Tournier
Summary: Liquid-liquid transitions were observed in Bi and Sn above the melting temperature (T-m), which were interpreted as glass transitions occurring at T-g = Tn+ > T-m for composites nucleated at T-x < T-m and fully melted at Tn+. The disappearance of a glassy fraction (f) was observed at 784 K in Sn. Predictions of the nucleation temperature (T-x), the fully melted temperature (Tn+), and the specific heat were made using a nonclassical model of homogeneous nucleation. The singular values of (f) leading to (Tn+) correspond to percolation thresholds of configurons in glassy phases. A phase diagram of glassy fractions occurring in molten elements was proposed. It was found that the same nucleation temperature (T-x) could result in multiple glass transition temperatures (T-g). The glass transition temperature (T-g = T-n(+)) could be higher than (2 T-m) for T-x/T-m < 0.7069. A specific heat equal to zero was predicted after cooling from T <= 2 T-m, indicating the presence of a glassy phase. Weak glassy fractions were nucleated near (Tn+) after full melting at (T-m) without transition at (T-x). Resistivity decreases were observed after thermal cycling between solid and liquid states with weak and successive values of (f) due to T-x/T-m < 0.7069.
Article
Chemistry, Multidisciplinary
Yuan Chi, Priyank V. Kumar, Jiewei Zheng, Charlie Kong, Ruohan Yu, Lucy Johnston, Mohammad B. Ghasemian, Md. Arifur Rahim, Tushar Kumeria, Dewei Chu, Xunyu Lu, Guangzhao Mao, Kourosh Kalantar-Zadeh, Jianbo Tang
Summary: A liquid-metal solvent-based method was developed for the nanoarchitecting and transformation of solid metals. By reacting liquid gallium with solid metals, crystalline entities were formed, and nanoporous features were created by selectively removing gallium. This method enables low-temperature fabrication of metallic nanoarchitectures with tailored porosity.
Article
Chemistry, Multidisciplinary
Anastasia K. Lavrinenko, Ivan Yu. Chernyshov, Evgeny A. Pidko
Summary: This study presents an alternative model based on machine learning for predicting the melting temperatures of binary metal-free DESs or ionic liquids. The model integrates experimental data, computational simulations, and cheminformatic descriptors, and demonstrates high accuracy in a large-scale database.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Crystallography
Jieying Liu, Jian Tang, Jiaojiao Zhao, Yanchong Zhao, Cheng Shen, Mengzhou Liao, Shuopei Wang, Jinpeng Tian, Yanbang Chu, Jiawei Li, Zheng Wei, Gen Long, Wei Yang, Rong Yang, Na Li, Dongxia Shi, Guangyu Zhang
Summary: As an emerging research field, two-dimensional (2D) metals have received increasing attention due to their potential applications. However, producing 2D metals through exfoliation techniques is challenging. This study presents a PDMS-assisted hot-pressing method to obtain ultraflat nanometer-thick 2D metals/metal oxide amorphous films of different low-melting-point metals and alloys.
Article
Thermodynamics
Hiromichi Watanabe
Summary: The thermophysical properties of tantalum at high temperatures were investigated, and a combined approach of dynamic and static calorimetry was used to determine the enthalpy and emissivity of tantalum. The study considered the influence of reactions between the metal, minor impurities, and residual gas, as well as the absorption and desorption processes of hydrogen and oxygen atoms by the tantalum sample.
THERMOCHIMICA ACTA
(2023)
Article
Multidisciplinary Sciences
Xi Li, Xiang Luo, Shuai Wang, Ke Xie, Xiang-Pei Liu, Hui Hu, Yu-Ao Chen, Xing-Can Yao, Jian-Wei Pan
Summary: In this study, second sound attenuation in a homogeneous Fermi gas of lithium-6 atoms has been observed at the superfluid transition temperature using Bragg spectroscopy in the long-wavelength limit. The temperature dependence of second sound diffusivity and thermal conductivity has been obtained, and a sudden rise in both diffusivity and conductivity near the critical temperature suggests a larger critical region in the Fermi gas compared to liquid helium. These findings lay the groundwork for determining universal critical scaling functions near quantum criticality.
Article
Chemistry, Physical
Robert F. Tournier, Michael I. Ojovan
Summary: Research has shown that a second melting temperature occurs at Tn+ during the melting process, where the melting entropy is either reduced or increased. By using a non-classical homogeneous nucleation model, successful predictions have been made for the glass transition temperature and nucleation temperature of liquid elements.
Article
Materials Science, Multidisciplinary
Roozbeh Abbasi, Jianbo Tang, Mahroo Baharfar, Chengchen Zhang, Francois-Marie Allioux, Jin Zhang, Mohammad Tajik, Jiong Yang, Joanna Biazik, Franco Centurion, Jialuo Han, Sajjad S. Mofarah, Dorna Esrafilzadeh, Pramod Koshy, Charles C. Sorrell, Sammy Lap Ip Chan, Md Arifur Rahim, Kourosh Kalantar-Zadeh
Summary: This study synthesized and characterized two low melting temperature liquid metal alloys (eutectic alloys of indium-tin-bismuth and Field's metal-like alloy with traces of zinc) and assessed their in vitro biocompatibility. The results suggest that these alloys have potential applications as non-invasive bioimplants.
APPLIED MATERIALS TODAY
(2022)
Article
Pharmacology & Pharmacy
Taiga Uekusa, Tomohiro Watanabe, Daiju Watanabe, Kiyohiko Sugano
Summary: The present study experimentally confirmed the thermodynamic correlation between the intrinsic liquid-liquid phase separation (LLPS) concentration and crystalline solubility of drug-like molecules, showing a good correlation between the calculated and observed values.
Article
Green & Sustainable Science & Technology
Robert F. Tournier, Michael I. Ojovan
Summary: This article introduces the characteristics of vitrification during fast quenching of materials and confirms the multiple existence of temperatures in monoatomic elements through molecular dynamics simulations.
Article
Materials Science, Multidisciplinary
P. P. Cao, H. L. Huang, S. H. Jiang, X. J. Liu, H. Wang, Y. Wu, Z. P. Lu
Summary: This study examined the microstructures and aging behaviors of several refractory high entropy alloys annealed at intermediate temperatures. The alloys exhibited decomposition into multiple phases at around 500 degrees C, but reentered the single-phase region at different temperatures. The onset decomposition temperature was found to be influenced by the elemental diffusion rates, while the ending decomposition temperature was strongly dependent on the elemental melting points.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Article
Materials Science, Ceramics
Jianbo Xu, Xinchao Qiu, Bowen Zhang, Gangfu Zhong, Maokang Shen, Xiangli Liu, Jun Ou-Yang, Yue Zhang, Benpeng Zhu, Xiaofei Yang, Shi Chen
Summary: Hafnium oxide (HfO2) fibers were prepared through electrospinning method and post-calcination treatment in this study, showing the formation of different crystal phases at different temperatures. The calcination temperature plays a significant role in the fiber density and grain size. Fibers calcined at 900 degrees C and 1200 degrees C exhibit better thermal shock resistance due to their stable phase and uniform grain growth after thermal shock test.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
M. Czagany, D. Varanasi, A. Sycheva, D. Janovszky, D. Koncz-Horvath, F. Kristaly, P. Baumli, G. Kaptay
Summary: The Cu/AlN-Al2O3 nano-multilayer was deposited on 42CrMo4 steel samples using magnetron sputtering method, revealing that at high temperatures, Cu nanocrystals coarsen and migrate within the multilayer, even forming micron-sized reservoirs. As the temperature increases, cracks appear in the AlN-Al2O3 layers, causing Cu to be exposed on the surface of the NML.
JOURNAL OF MATERIALS SCIENCE
(2021)