期刊
MENDELEEV COMMUNICATIONS
卷 24, 期 4, 页码 187-196出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2014.06.001
关键词
-
资金
- National Science Foundation [CHE - 1212446]
Oxidations with tert-butyl hydroperoxide (TBHP) catalyzed by dirhodium caprolactamate [Rh-2(cap)(4)] provide mild and selective protocols for the oxidative Mannich reaction, conversion of secondary amines to imines, dearomatization of 4-substituted phenols, and oxyfunctionalization of allylic, benzylic, and propargylic positions. The dirhodium catalyst in combination with TBHP is a convenient platform for mechanistic investigations, and their uses point to a variety of directions for the future evolution of the field.
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