4.2 Article

Unusual C-alkylation of pyrazolines with 2-(het)arylcyclopropane-1,1-dicarboxylates in the presence of GaCl3

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MENDELEEV COMMUNICATIONS
卷 22, 期 2, 页码 87-89

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ELSEVIER
DOI: 10.1016/j.mencom.2012.03.012

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  1. Ministry of Education and Science [02.740.11.0258]
  2. Division of Chemistry and Materials Science of the Russian Academy of Sciences

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The reaction outcome between 2-(het)arylcyclopropane-1,1-dicarboxylates and 1- and 2-pyrazolinecarboxylates in the presence of GaCl3 is temperature-dependent: at 5 degrees C 1:1 adducts are formed, whereas at 40 degrees C 2:1 adducts would predominate.

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