4.2 Article

Homogeneous azidophenylselenylation of glucals

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MENDELEEV COMMUNICATIONS
卷 18, 期 5, 页码 241-243

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ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2008.09.003

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  1. Russian Foundation for Basic Research [07-03-00225]
  2. INTAS [03-55-1026]

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The homogeneous azidophenylselenylation of diversely protected mono-, di- and trisaccharide glucals was studied to evaluate the influence of protective groups, N-3 and I donors, temperature and solvent on the stereoselectivity of the formation of corresponding phenyl 2-azido-2-deoxy-1-seleno-alpha-D-gluco- and -manno-adducts.

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