Article
Chemistry, Inorganic & Nuclear
Jiutian Wang, Lihong Jiang, Ran Pang, Su Zhang, Da Li, Kai Li, Chengyu Li, Hongjie Zhang
Summary: In this study, a novel near-infrared phosphor with a single emitting center was successfully synthesized, showing broadband emission characteristics. The relationship between the local coordination environment and the crystal structure on the luminescence properties was analyzed. This research provides important insights for the design and development of super broadband near-infrared phosphors.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Jianbang Zhou, Pengyun Chen, Junhao Li, Mingming Yang, Wei Jiang, Qiuhong Zhang, Haiyong Ni, Jiansheng Huo
Summary: In this study, a series of Cr3+-activated near-infrared (NIR) phosphors with broadband emission and tunable luminescence properties were designed and prepared. The luminescence characteristics of the materials could be controlled by adjusting the crystal field strength. One of the phosphors exhibited high luminous efficiency even at high temperature, and the thermal stability was attributed to the structural confinement and the electron-phonon coupling effect.
DALTON TRANSACTIONS
(2022)
Article
Materials Science, Ceramics
Weiying Zhou, Jiabao Luo, Jiaqi Fan, Haowen Pan, Senxiang Zeng, Liya Zhou, Qi Pang, Xinguo Zhang
Summary: NIR-emitting Cr3+-activated phosphors (NaInGe2O6: Cr3+) covering the entire NIR-I region were successfully designed and prepared, demonstrating excellent NIR emission performance and thermal stability. An efficient pc-LED with high NIR output was fabricated, suitable for various applications.
CERAMICS INTERNATIONAL
(2021)
Article
Optics
Yan Zhang, Shihai Miao, Yanjie Liang, Chao Liang, Dongxun Chen, Xihui Shan, Kangning Sun, Xiao-Jun Wang
Summary: Extensive research on infrared light sources is being conducted due to the growing demand for spectroscopy applications in agriculture, retail, and healthcare. The development of ideal blue-pumped short-wave infrared (SWIR) phosphors is crucial for the design of cost-effective and high-performance phosphor-converted infrared LEDs. In this study, we have developed a series of SWIR-emitting materials with high efficiency and stability by co-doping Cr3+-Yb3+ ion pairs into Lu0.2Sc0.8BO3 host materials. The resulting Lu0.2Sc0.8BO3:Cr3+,Yb3+ phosphor emits intense SWIR light in the 900-1200 nm range under blue light excitation and shows promising potential for practical applications.
LIGHT-SCIENCE & APPLICATIONS
(2022)
Article
Chemistry, Physical
Jianhua Lin, Liuyan Zhou, Long Ren, Yuyu Shen, Yanling Chen, Jie Fu, Lei Lei, Renguang Ye, Degang Deng, Shiqing Xu
Summary: This study introduces a new wide band NIR luminescent phosphor with extensive application prospects. It has a wide emission spectrum, high quantum efficiency, and good thermal stability, making it suitable for practical applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Optics
Chenxu Yuan, Ruiyang Li, Yongfu Liu, Liangliang Zhang, Jiahua Zhang, Grzegorz Leniec, Peng Sun, Zehua Liu, Zhaohua Luo, Rui Dong, Jun Jiang
Summary: A high external quantum efficiency LiGaP2O7:Cr3+ (LGAP:Cr3+) NIR phosphor was discovered with broad NIR emission and excellent performance, promising the use of this phosphor for high-performance broadband NIR LED.
LASER & PHOTONICS REVIEWS
(2021)
Article
Chemistry, Inorganic & Nuclear
Yan Zhang, Yanjie Liang, Shihai Miao, Dongxun Chen, Shao Yan, Jingwei Liu
Summary: A series of Cr3+-doped BaMSi3O9 (M = Zr, Sn, Hf) near-infrared emitting phosphors with tunable luminescence properties have been successfully synthesized, showing a broad emission spectrum and good thermal stability. By combining with a blue LED chip, high-power near-infrared LED prototypes can be constructed for night-vision lighting and blood vessel imaging.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Materials Science, Multidisciplinary
Shihai Miao, Yanjie Liang, Yan Zhang, Dongxun Chen, Xiao-Jun Wang
Summary: A promising broadband SWIR phosphor was designed and developed by incorporating Cr3+-Ni2+ ion pairs into LiMgPO4 host. A phosphor-converted SWIR LED prototype device was fabricated, demonstrating practical applications in medical, surveillance, and spectroscopy fields.
ADVANCED MATERIALS TECHNOLOGIES
(2022)
Article
Optics
Meng Tian, Huabin Yu, Muhammad Hunain Memon, Zhanyong Xing, Chen Huang, Hongfeng Jia, Haochen Zhang, Danhao Wang, Shi Fang, Haiding Sun
Summary: Micro-LEDs with smaller inclined chip sidewall angles exhibit improved external quantum efficiency due to stronger reflection of the inclined sidewall, leading to enhanced light extraction efficiency. The EQE improvement by adopting an inclined sidewall is more significant as the diameter of the LED chip reduces. Numerical optical modeling further verifies the impact of sidewall angles on the light extraction efficiency of micro-LEDs.
Article
Chemistry, Inorganic & Nuclear
Nguyen Van Quang, Nguyen Thi Huyen, Nguyen Tu, Do Quang Trung, Dao Duc Anh, Manh Trung Tran, Nguyen Duy Hung, Dao Xuan Viet, Pham Thanh Huy
Summary: The alpha-Al2O3:Cr3+ phosphor, which emits a narrow peak at 695 nm, shows potential for horticultural lighting as demonstrated in the fabrication of a plant growth LED prototype. The red LED obtained by coating the alpha-Al2O3:0.6%Cr3+ phosphor on a NUV chip exhibits high color purity and QE value.
DALTON TRANSACTIONS
(2021)
Article
Materials Science, Ceramics
Baochen Wang, Cheng Yan, Kaiwei Shen, Weiwei Lin, Yan-gai Liu, Ruiyu Mi, Chao Zeng
Summary: A novel Cr3+ doped broadband NIR garnet Ca3Sc2Ge3O12 phosphor with enhanced luminescence and thermal stability was developed. A high-performance NIR LED was fabricated using this phosphor, with high radiance and photoelectric efficiency.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Jie Chen, Zixin Weng, Yanru Tang, Xuezhuan Yi, Yanna Tian, Di Zhao, Hui Lin, Shengming Zhou
Summary: Phosphor ceramics of ZrO2-Al2O3-YAG:Ce (ZA-YAG:Ce) were successfully fabricated through vacuum solid-state reaction, showing enhanced performance in warm w-LEDs with improved CRI and LE. The results indicate a promising application prospect for ZA-YAG:Ce ceramic phosphors in warm white LEDs.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Article
Chemistry, Inorganic & Nuclear
Zheng-Guang Wu, Bing Yang, Yu-Chen Qiu, Yang Wang, Hong Dai, You-Xuan Zheng, Yi Wang, Lanping Hu, Yi Pan
Summary: Cyclometalated iridium (Ir)(iii) complexes are currently the most promising emitters for OLEDs. Two novel blue Ir(iii) complexes were designed to achieve blue emission and good electron mobility simultaneously, showing improved electroluminescence performances. This provides an effective strategy for the future molecular design of blue Ir(iii) complexes with good electron transport property for OLEDs.
DALTON TRANSACTIONS
(2021)
Article
Engineering, Environmental
Peilan Luo, Menglin Ye, Wenli Zhou, Pingping Wan, Zhongyun Ma, Zhongxian Qiu, Jilin Zhang, Ru-Shi Liu, Shixun Lian
Summary: This study proposes the construction of an impermeable dual-shell on Mn4+-doped fluoride materials to improve their stability. The dual-shell can optimize internal quantum efficiency and significantly enhance water stability.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Optics
Longheng Qi, Peian Li, Xu Zhang, Ka Ming Wong, Kei May Lau
Summary: A prototype of full-color micro-LED micro-display with a pixel density of 391 ppi is demonstrated using InGaN/AlGaInP heterogeneous integration. This display shows the feasibility and prospects of high brightness, good color performance, and high-resolution micro-LED micro-displays in future metaverse applications.
LIGHT-SCIENCE & APPLICATIONS
(2023)
Article
Green & Sustainable Science & Technology
Dennis Roskosch, Valerius Venzik, Burak Atakan
Article
Thermodynamics
Sascha Lau, Burak Atakan
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2020)
Article
Thermodynamics
Dominik Schroeder, Robert Hegner, Ali Gungor, Burak Atakan
ENERGY CONVERSION AND MANAGEMENT
(2020)
Article
Thermodynamics
Dominik Schroeder, Kai Banke, Sebastian A. Kaiser, Burak Atakan
Summary: Fuel-rich combustion of methane with additives such as DME and ozone in an HCCI engine can produce work, heat, and useful chemicals. Experimental results show that ozone is a suitable additive for fuel-rich HCCI, reducing the fuel-fraction of DME needed. The mechanism of ignition differs between fuel-rich and fuel-lean combustion, with ozone showing potential for improving the economics of polygeneration processes.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Article
Thermodynamics
D. Kaczmarek, S. Shaqiri, B. Atakan, T. Kasper
Summary: Methane oxidation exhibits negative temperature coefficient behavior under high pressure and fuel-rich conditions. Reliable kinetic models and reaction path analysis are essential for designing polygeneration processes. The competition between oxidation and recombination pathways plays a key role in the observed NTC region.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Article
Thermodynamics
Charlotte Rudolph, Burak Atakan
Summary: A novel method for energy conversion in piston engines, pyrolysis of natural gas/hydrogen mixtures for energy storage, is investigated. The addition of hydrogen allows for increased yields of certain products but also reduces storage power and efficiency.
Article
Energy & Fuels
Simon Drost, Dennis Kaczmarek, Sven Eckart, Juergen Herzler, Robert Schiessl, Chris Fritsche, Mustapha Fikri, Burak Atakan, Tina Kasper, Hartmut Krause, Christof Schulz, Ulrich Maas
Summary: This study investigates the combustion characteristics of ethanol/air mixtures through experiments and simulations. The simplified reaction mechanism demonstrates performance close to the detailed mechanism. Within certain temperature and pressure ranges, the simplified mechanism shows good predictive capabilities for experimental data and laminar burning velocities.
Article
Thermodynamics
S. Lau, M. Gonchikzhapov, A. Paletsky, A. Shmakov, O. Korobeinichev, T. Kasper, B. Atakan
Summary: This study investigates the thermal behavior of aluminum diethylphosphinate (AlPi) as a flame retardant in ultra-high molecular weight polyethylene (UHMWPE). The research focuses on the effect of the flame retardant on the gas phase activity during polymer pyrolysis or combustion. The study finds that a small amount of AlPi significantly decreases the gas temperature in the flame, indicating its flame retardant effect.
COMBUSTION AND FLAME
(2022)
Article
Thermodynamics
Charlotte Rudolph, Dominik Freund, Dennis Kaczmarek, Burak Atakan
Summary: This study investigates the conversion of chemical plant waste gases into fuel for carbon recovery and simultaneous output of work and heat. Experimental results show that under appropriate conditions of oxygen addition and equivalence ratio, the conversion rate of ammonia in the waste gases can be improved, and high energy efficiency can be achieved.
COMBUSTION AND FLAME
(2022)
Article
Thermodynamics
Julian Quenel, Burak Atakan
Summary: The influence of fin geometries, PCM thermal conductivity, and discharge temperature of the secondary fluid on thermal energy storage systems were investigated. The study found that the improvement methods increased the heat flux, but to a lesser extent than expected. The impact of thermal conductivity was found to be lower at higher fin volume fractions. Increasing the discharge temperature difference had the strongest impact on heat flux but also increased exergy loss.
HEAT AND MASS TRANSFER
(2022)
Article
Materials Science, Multidisciplinary
Sebastian Grimm, Seung-Jin Baik, Patrick Hemberger, Tina Kasper, Andreas M. Kempf, Burak Atakan
Summary: In this study, the thermal decomposition of Zr(acac)(4) was investigated in a SIC-microreactor on the microsecond time scale. Six important zirconium intermediates were identified in the gas phase for the first time using synchrotron radiation and photoelectron photoion coincidence spectroscopy. The flow field in the microreactor was numerically simulated, showing that helium provides a more uniform flow field than argon.
JOURNAL OF MATERIALS RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Sebastian Grimm, Patrick Hemberger, Tina Kasper, Burak Atakan
Summary: This study investigates the decomposition and reduction of ferrocene in the gas-phase. By detecting reactive intermediates and proposing a reaction mechanism, the underlying chemistry is understood. The addition of hydrogen is found to affect the product formation.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Thermodynamics
Tobias Guth, Burak Atakan
Summary: The refrigeration industry is challenged by the replacement of harmful refrigerants and the optimization of the refrigeration system operation for environmental protection. This study presents a semi-empirical model for a variable speed scroll compressor for R-290. The model calculates the refrigerant mass flow, discharge temperature, and power consumption based on physical laws and empirical efficiencies fitted by polynomials. The model shows good accuracy for the investigated operating points and demonstrates transferability to other compressors and refrigerants.
INTERNATIONAL JOURNAL OF REFRIGERATION
(2023)
Article
Thermodynamics
Charlotte Rudolph, Claire M. Gregoire, Sean P. Cooper, Sulaiman A. Alturaifi, Olivier Mathieu, Eric L. Petersen, Burak Atakan
Summary: The need for fundamental research on the decomposition and formation of base chemicals under unusual operating conditions of natural-gas-fueled combustion engines is emphasized. This study investigates the CO formation during the pyrolysis of CO2/CH4 mixtures in engine-based dry methane reforming and tests the validity of literature reaction mechanisms. The results show competing reactions in the pyrolysis and oxidation pathways and the limited availability of H radicals, leading to reduced reactivity. Additionally, none of the tested mechanisms can accurately predict the time-resolved CO formation, highlighting the importance of validating detailed kinetics models under non-typical conditions.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2023)
Article
Chemistry, Physical
Sebastian Grimm, Seung-Jin Baik, Patrick Hemberger, Andras Bodi, Andreas M. Kempf, Tina Kasper, Burak Atakan
Summary: In this study, the thermal decomposition of aluminium acetylacetonate was investigated in a microreactor using i(2)PEPICO between 325 and 1273 K. Quantum chemical calculations and CFD were used to characterize the reaction and flow field. Various decomposition products were identified, including aluminium bis(diketo)acetylacetonate-H and acetylacetone as the major initial products formed at temperatures above 600 K. The formation mechanism of gas-phase aromatic hydrocarbons was discussed and Arrhenius parameters were presented for the gas-phase decomposition kinetics.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)