期刊
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
卷 527, 期 26, 页码 6930-6937出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.msea.2010.07.079
关键词
Biodegradable; Polymer blend; Compatibility; Phase-separation; Poly(L-lactic acid); Poly(epsilon-caprolactone)
类别
资金
- ASEAN University Network/Southeast Asia Engineering Education Development Network (AUN/SEED-Net)
- Japan International Cooperation Agency (JICA) [6050131]
- Universiti Sains Malaysia
- Kyushu University
Incompatibility and immiscible binary blends of poly(L-lactide) (PLLA) and poly(epsilon-caprolactone) (PCL) with 70/30 wt.% composition were modified and prepared by addition of 0.5, 1 and 2 phr of polyethylene oxide-polypropylene oxide-polyethylene oxide (PEO-PPO-PEO) triblock copolymer. The effect of the copolymer ratio on the microstructures and properties of the blends was investigated using proton nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscope (FE-SEM), dynamic mechanical analysis, differential scanning calorimetry, thermo-gravimetric analysis, and Mode I fracture testing. The addition of the copolymer to PLLA/PCL improved its fracture toughness. A reduction in the amount of spherical of PCL upon the addition of copolymers was confirmed by FE-SEM. The glass transition temperature (T-g) and melting temperature (T-m) of PLLA and PCL shifted closer together, indicating that the blend compatibility increased. Thus, PEO-PPO-PEO can be employed as compatibilizer to improve the toughness and compatibility of PLLA/PCL blends. (C) 2010 Elsevier B.V. All rights reserved.
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