4.7 Article

In situ size-strain analysis of nanocrystalline ceria growth

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.msea.2010.03.077

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Growth kinetics; Nanocrystalline materials; Ceria nanocrystals; X-ray diffraction; Line profile analysis

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A xerogel produced from cerium isopropoxide is shown to be made of nanocrystalline ceria domains (ca. 2 nm in diameter), already formed by condensation of the hydrolysed precursor. In situ isothermal X-ray diffraction studies of the xerogel calcination reveal the occurrence of a second stage of nucleation, followed by growth of the grains up to a temperature-dependent asymptotic limit. The process, with an activation energy of 52(4) kJ/mol and an Avrami exponent 0.55-0.75, is interpreted in terms of coalescence of the existing nuclei. (C) 2010 Elsevier B.V. All rights reserved.

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