Article
Chemistry, Physical
Natalia Bulina, Denis K. Rybin, Svetlana Makarova, Dina Dudina, Igor S. Batraev, Alexey Utkin, Igor Yu Prosanov, Mikhail Khvostov, Vladimir Yu Ulianitsky
Summary: Hydroxyapatite (HA) is a suitable mineral for bone tissue engineering and coating metallic implants to enhance their biocompatibility and osteoinductive properties. Deposition of HA coatings on medical titanium alloy implants using detonation spraying technique showcased the potential for producing HA coatings on implants with complex geometries.
Review
Biotechnology & Applied Microbiology
Xiao Sheng, Ao Wang, Zhonghan Wang, He Liu, Jincheng Wang, Chen Li
Summary: This article discusses the principles, processes, and challenges of surface modification of 3D printed titanium alloy implants. Future research directions, such as the combination of multiple modification technologies and the coordination of the structure and composition of composite coatings, are also presented.
FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY
(2022)
Article
Chemistry, Physical
Christie Y. K. Lung, Mohamed M. Abdalla, Chun Hung Chu, Iris Yin, Sofiya-Roksolana Got, Jukka P. Matinlinna
Summary: A novel multi-element-doped porous bioactive glass coating for titanium implants was developed and showed promising biocompatibility and antibacterial activity, suggesting potential clinical applications.
Article
Biotechnology & Applied Microbiology
Mona Sari, Chotimah, Ika Dewi Ana, Yusril Yusuf
Summary: In this study, CHA/Ti and CHA/HCB/Ti plates were coated using the EP2D method, and the cell viability and surface morphology of the coatings were analyzed. The results showed that the cell viability of CHA/Ti plates was superior to that of CHA/HCB/Ti plates, and the surface of CHA/Ti remained unchanged after the coating process. These findings are important for biomedical applications, especially in the field of bone implants.
BIOENGINEERING-BASEL
(2022)
Article
Materials Science, Coatings & Films
S. Ferraris, G. Orlygsson, C. H. Ng, G. Riccucci, S. Spriano
Summary: Coating titanium with chitosan is a promising method for reducing the infection risk and modulating the inflammatory response of bone implants. This research tested two titanium surfaces and employed three coating strategies. The chemically pretreated surface showed the best coating results and interface stability.
SURFACE & COATINGS TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Salih Durdu, Sergen Tosun, Emine Yalcin, Kultigin Cavusoglu, Atilgan Altinkok, Hasan Sagcan, Ilknur Yurtsever, Metin Usta
Summary: By coating CuNPs on nanotube surfaces, the corrosion resistance of Ti6Al4V alloy can be enhanced, and the biological properties such as antibacterial activities, cell viability, and ALP activity can be improved, while reducing protein adsorption and hemolytic activity. This has significant implications for orthopedic and dental implant applications.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Review
Materials Science, Multidisciplinary
Merbin John, Udaya Bhat Kuruveri, Pradeep L. Menezes
Summary: This review provides a comprehensive overview of the laser cladding process and its applications in various industries. The effects of laser cladding on mechanical properties, microstructural features, and potential applications are discussed in detail.
Article
Engineering, Biomedical
Mahdis Nesabi, Alireza Valanezhad, Sirus Safaee, Tetsurou Odatsu, Shigeaki Abe, Ikuya Watanabe
Summary: The study combined alkali treatment and bioactive glass sol dip-coating for titanium surface modification, resulting in a surface with improved mechanical and biological properties. The nanostructure reinforced BG coating layer was shown to outperform unmodified and individually modified surfaces, indicating promising potential for hard-tissue replacement applications.
JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS
(2021)
Review
Engineering, Biomedical
Jingwei Yu, Minghao Zhou, Luxuan Zhang, Hongbo Wei
Summary: This article reviews the process of bacterial adhesion, the material properties that may affect the process, and the effective anti-adhesion strategies in practice. It aims to be a reference for improving antibacterial adhesion strategy in clinical application and related research on titanium implant surfaces.
JOURNAL OF FUNCTIONAL BIOMATERIALS
(2022)
Article
Dentistry, Oral Surgery & Medicine
X. Yu, B. Feng, Y. Lan, J. Li, G. Ye, Q. Li, F. Zhao, Y. Gu, D. You, Y. Zhu, M. Yu, H. Wang, H. Yang
Summary: This study aims to design a personalized two-stage root analog implant (RAI) with a compact structure and uniform roughness to achieve better fracture resistance, initial osseointegration efficiency, and dispersed stress in immediate implantation. RAIs were manufactured using selective laser melting technology, and in vivo experiments showed that they had higher bone-implant contact and bone volume/total volume compared to conventional implants. Customized abutments were also designed for the RAIs, improving the masticatory ability of the beagle dogs.
JOURNAL OF DENTAL RESEARCH
(2023)
Article
Materials Science, Coatings & Films
Paloma Trueba, Carlos Navarro, Jose A. Rodriguez-Ortiz, Ana M. Beltran, Francisco J. Garcia-Garcia, Yadir Torres
Summary: This study evaluated the mechanical behavior of superficially modified porous titanium dental implants fabricated by two different routes and discussed the influence of porosity and surface roughness on the stiffness and yield strength of implants. The results showed that macro-pores can localize stress and act as a barrier to micro-crack propagation, while higher rugosity was observed for implants obtained with spacer particles. Superficial modifications, such as using bioglass 1393 coating and chemical etching, were effective in improving the adhesion and roughness of implant surfaces.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Chemistry, Physical
Yan Jiao, Xiaohong Li, Xiuzhen Zhang, Guoqiang Li, Jiahao Fang, Sensen Xuan, Linlin Liu, Su Wang, Huiqi Xie
Summary: This study developed a surface strategy using a hierarchical microgroove structure and silver adhered by polydopamine (PDA) on a porous titanium alloy. It was found that the surface parameters of the hierarchical structure controlled the total amount and rate of silver release, and PDA improved the total amount of absorbed silver. In vitro tests showed that the modified surface had better antibacterial properties and allowed cell orientation.
APPLIED SURFACE SCIENCE
(2023)
Review
Materials Science, Multidisciplinary
Weijun Liu, Wanqiu Li, Huiru Wang, Hongyou Bian, Kai Zhang
Summary: This study focuses on the surface modification methods of selective laser melting (SLM) implants to remove unmelted powder particles and improve the biological and mechanical properties of the implants. Chemical and electrochemical methods are commonly used for surface modification, which can enhance the implant performance while minimizing health risks.
ADVANCED ENGINEERING MATERIALS
(2023)
Review
Dentistry, Oral Surgery & Medicine
Tian-Xia Zheng, Wen Li, Ying-Ying Gu, Di Zhao, Meng-Chun Qi
Summary: The article reviews the current research progress of surface antimicrobial techniques for titanium implants, including antimicrobial coatings and surface modifications. These techniques exert antimicrobial effects by reducing bacterial adhesion, inhibiting metabolism, or destroying cell structure.
JOURNAL OF DENTAL SCIENCES
(2022)
Article
Chemistry, Physical
Geovana Vilas Boas da Rocha, Joao Henrique Lopes, Virginie Roche, Alberto Moreira Jorge, Rudimar Riva, Aline Capella de Oliveira, Dilermando Nagle Travessa
Summary: Titanium alloys, particularly TMZF, have excellent mechanical properties and biocompatibility. However, their poor osteointegration limits their orthopedic applications. In this study, a bioactive coating was dip-coated onto the TMZF substrate surface using the layer-by-layer method. The coated samples showed a uniform and adherent bioactive coating, resulting from changes in the substrate surface morphology and chemical composition. Immersion in SBF solution demonstrated excellent bioactivity, with apatite-related deposits observed after 24 hours. A model of physical and chemical anchorage of the bioactive glass coating on TMZF was proposed.
APPLIED SURFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Rathinavelu Sokkalingam, Zhao Chao, Katakam Sivaprasad, Veerappan Muthupandi, Jayamani Jayaraj, Parthiban Ramasamy, Juergen Eckert, Konda Gokuldoss Prashanth
Summary: CoCrFeMnNi high-entropy alloy/AISI 316L stainless steel bimetal was fabricated using SLM, showing enhanced hardness and tensile strength due to the composition and structure advantages. However, the presence of defects and higher susceptibility to pitting corrosion in CoCrFeMnNi-HEA make it more prone to corrosion attack in corrosive environments.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Sabine C. Bodner, Kostyantin Hlushko, Kevin Kutlesa, Juraj Todt, Oliver Renk, Michael Meindlhumer, Florian Resch, Marc-Andre Nielsen, Jozef Keckes, Jurgen Eckert
Summary: The correlations between process conditions, microstructure, and mechanical properties of additively manufactured components are explored in this study. The results show that the applied hatch strategy has a significant impact on the microstructure and mechanical properties of the samples, especially the anisotropy observed in the plane perpendicular to the build direction.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Sepide Hadibeik, Florian Spieckermann, Martin Nosko, Farzad Khodabakhshi, Mahmoud Heydarzadeh Sohi, Juergen Eckert
Summary: A novel approach for fabricating bulk metallic glass using additive manufacturing has been studied, however, there are challenges, such as unmelted powder and compositional deviation, that need further investigation to optimize the process parameters.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Jelena Petrusa, Benjamin Meier, Gerda Gruenbacher, Wolfgang Waldhauser, Juergen Eckert
Summary: The effects of laser energy density on the relative density and microstructure of cp-TiGd2 fabricated by LB-PBF were studied, and the influence of printing orientation and different surface treatments on surface topography and biocompatibility were investigated. The aim is to develop additive manufacturing process parameters that can achieve full density and satisfactory biocompatibility for cp-TiGd2 as a low-cost alternative to biomedical materials. An optimized process with high density, improved surface roughness, and noncytotoxicity was achieved using a wide range of process parameters.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Chemistry, Physical
Zequn Zhang, Simon Fellner, Sergey Ketov, Megan J. Cordill, Huaping Sheng, Christian Mitterer, Kaikai Song, Christoph Gammer, Juergen Eckert
Summary: The phase evolution of alloys and atomic diffusion are closely related. However, the influence of reactive diffusion on phase formation in high-entropy alloys (HEAs) is still not clear. This study investigates the phase evolution of a multicomponent CoCrFeNi/Al diffusion couple and reveals the combined effects of enthalpy and entropy on phase formation in HEAs at elevated temperatures. Surface modification of HEAs can be achieved through film deposition and annealing processes.
Review
Electrochemistry
Baran Sarac, A. Sezai Sarac, Juergen Eckert
Summary: This review provides an introduction to the use of advanced amorphous metal catalysts for hydrogen storage and production via electrochemistry. Pd-based metallic glasses have gained significant attention due to their unique atomic structure and properties for energy applications. The review covers the fabrication techniques, hydrogen sorption, hydrogen evolution, kinetics, and future prospects of Pd-based metallic glasses. Overall, it offers a comprehensive overview for large-scale hydrogen energy storage and production systems.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Materials Science, Multidisciplinary
Ming-Zhi Zhang, Kun Zhang, Kai-Kai Song, Xiao-Yu Zou, Wei-Dong Song, Ke-Feng Li, Li-Na Hu, Ze-Qun Zhang, Juergen Eckert
Summary: In this study, CoCrFeMnNi high-entropy alloys with a surface gradient nanostructure were produced using industrial shot blasting, which significantly improved their mechanical properties. The severely plastically deformed surface layer had a multi-scale hierarchical structure and increased in depth with shot-blasting time. The microhardness and tensile strength of the alloy were significantly higher after shot-blasting. The improved strain hardening and prevention of early necking in the gradient-nanostructured surface layer contributed to its high toughness.
Article
Chemistry, Physical
Monika Antoni, Florian Spieckermann, Niklas Plutta, Christoph Gammer, Marlene Kapp, Parthiban Ramasamy, Christian Polak, Reinhard Pippan, Michael J. J. Zehetbauer, Juergen Eckert
Summary: The effects of severe plastic deformation (SPD) by means of high-pressure torsion (HPT) on Fe73.9Cu1Nb3Si15.5B6.6 and Fe81.2Co4Si0.5B9.5P4Cu0.8 iron-based metallic glasses were compared. HPT processing extended the consolidation and deformation ranges for Fe73.9Cu1Nb3Si15.5B6.6, and achieved consolidation and deformation with minimum cracks for Fe81.2Co4Si0.5B9.5P4Cu0.8 for the first time. Various analyses revealed that Fe81.2Co4Si0.5B9.5P4Cu0.8 exhibited HPT-induced crystallization phenomena, while Fe73.9Cu1Nb3Si15.5B6.6 did not crystallize even at high HPT-deformation degrees.
Editorial Material
Chemistry, Multidisciplinary
Juergen Eckert, Daniel Kiener
Article
Chemistry, Physical
Keziban Huner, Baran Sarac, Eray Yuece, Amir Rezvan, Matej Micusik, Maria Omastova, Juergen Eckert, A. Sezai Sarac
Summary: The incorporation of iron and carboxylic acid-functionalized polyaniline into polymeric polycaprolactone structures enhances the electron-donating ability and conductivity of the compound, making it suitable for electrochemical immunosensors.
MOLECULAR SYSTEMS DESIGN & ENGINEERING
(2023)
Article
Engineering, Mechanical
Bin Chen, Yunli Li, Daniel Sopu, Juergen Eckert, Wenping Wu
Summary: The shock-induced dynamic mechanical behavior and spallation failure of Ni-based single crystal superalloys are studied using non-equilibrium molecular dynamic simulations. Two modes of classical spallation and micro-spallation are observed during the spallation failure. The deformation mechanism is dominated by slip and drag of dislocations at low shock velocities, while complex phase transitions from FCC to BCC or disordered structures occur at higher velocities, leading to a decrease in spallation strength. The presence of voids significantly lowers the spallation strength, and the reduction in strength is proportional to the radius of the voids.
INTERNATIONAL JOURNAL OF PLASTICITY
(2023)
Article
Materials Science, Multidisciplinary
Xiaoming Liu, Zongde Kou, Ruitao Qu, Weidong Song, Yijia Gu, Changshan Zhou, Qingwei Gao, Jiyao Zhang, Chongde Cao, Kaikai Song, Vladislav Zadorozhnyy, Zequn Zhang, Juergen Eckert
Summary: This study utilizes high-temperature extrusion and annealing to optimize the microstructures and mechanical properties of the Co34Cr32Ni27Al3.5Ti3.5 multicomponent alloy. Hot extrusion reduces grain sizes and promotes the precipitation of nanoparticles inside the FCC matrix and grain boundaries. Subsequent annealing regulates the microstructures and enhances the mechanical properties.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Ming-Wei Wu, Kai Ni, Yang Lei, Xin-Xing Xiong, Yi-Ting Chuang, Quiao-En Lin, Pei Wang, Parthiban Ramasamy, Juergen Eckert
Summary: Selective laser melting (SLM) was utilized to produce CuZrAl metallic glass (MG) scaffolds with combined lattice structures of body-centered cubic and face-centered cubic (F2BCC), and the effects of lattice structures on mechanical behavior were investigated. The results revealed that curved struts remarkably enhanced compressive ductility by 122% and energy absorption by 106%. The presence of curved struts effectively prevented catastrophic shear fracture and delayed fracture occurrence due to the release of strain concentrations. This study demonstrates the potential of improving the ductility and toughness of SLM MG components through appropriate lattice structure design.
Article
Materials Science, Multidisciplinary
Xintian Wang, Zhiyong Ji, Robert O. Ritchie, Ilya Okulov, Juergen Eckert, Chunlei Qiu
Summary: In this study, TiAl and Cr3C2 particles were added to a CrMnFeCoNi alloy to improve its processibility and mechanical properties. The addition of TiAl particles resulted in the formation of cracks, but the further addition of Cr3C2 particles helped suppress hot cracking. The presence of long-range ordered domains and precipitates contributed to the improved strength of the dual-particle containing alloy.
MATERIALS TODAY ADVANCES
(2023)
Article
Chemistry, Physical
Baran Sarac, Remzi Gurbuz, Matej Micusik, Maria Omastova, Amir Rezvan, Eray Yuece, Lixia Xi, Juergen Eckert, Ali Ozcan, A. Sezai Sarac
Summary: This study focuses on the synthesis and properties comparison of a novel organic composite nanofiber material consisting of styrene-butadiene-styrene (SBS) copolymer blended with polystyrene (PStyr) and carbon nanotubes (CNTs). The addition of CNTs retards the crystallization process and decreases the absorbance of both SBS/PStyr and PStyr/PBu in Fourier transform infrared spectroscopy. The interaction of CNTs with the blend is limited in samples with SBS, as observed in Raman spectroscopy.
MOLECULAR SYSTEMS DESIGN & ENGINEERING
(2023)
Article
Materials Science, Biomaterials
Mohammadreza Kasravi, Alireza Yaghoobi, Tahereh Tayebi, Mahsa Hojabri, Abdolkarim Talebi Taheri, Fatemeh Shirzad, Bahram Jambar Nooshin, Radman Mazloomnejad, Armin Ahmadi, Fatemeh A. Tehrani, Ghasem Yazdanpanah, Mohammad Hadi Farjoo, Hassan Niknejad
Summary: As a promising approach in translational medicine, the decellularization of discarded livers to produce bioscaffolds that support recellularization has potential in overcoming the limitations of conventional liver transplantation. In this study, the researchers investigated the use of matrix metalloproteinase (MMP) inhibition to preserve the extracellular matrix (ECM) during liver decellularization. The results demonstrated that the application of an MMP inhibitor significantly improved the preservation of ECM components and mechanical properties of the bioscaffolds, which supported cell viability and function in vitro. The study also confirmed that the MMP inhibition led to the inhibition of MMP2 and MMP9, providing a novel method to enhance ECM preservation during liver decellularization.
BIOMATERIALS ADVANCES
(2024)
Article
Materials Science, Biomaterials
Mohammadsadegh Nadimifar, Weiguang Jin, Clara Coll-Satue, Gizem Bor, Paul Joseph Kempen, Ali Akbar Moosavi-Movahedi, Leticia Hosta-Rigau
Summary: This study presents a metal-phenolic self-assembly approach that can prepare nanoparticles fully made of hemoglobin. The nanoparticles exhibit good oxygen binding and releasing capabilities.
BIOMATERIALS ADVANCES
(2024)
Article
Materials Science, Biomaterials
Jyoti Kumari, Roel Hammink, Jochem Baaij, Frank A. D. T. G. Wagener, Paul H. J. Kouwer
Summary: Fibrosis is the formation of fibrous connective tissue in response to injury, leading to organ dysfunction. A novel hybrid hydrogel combining synthetic polyisocyanide with hyaluronic acid has been developed, showing strong antifibrotic properties.
BIOMATERIALS ADVANCES
(2024)
Letter
Materials Science, Biomaterials
Melissa Machado Rodrigues, Cristian Padilha Fontoura, Charlene Silvestrin Celi Garcia, Sandro Tomaz Martins, Joao Antonio Pegas Henriques, Carlos Alejandro Figueroa, Mariana Roesch Ely, Cesar Aguzzoli
BIOMATERIALS ADVANCES
(2024)
Article
Materials Science, Biomaterials
Jessica Polak, David Sachs, Nino Scherrer, Adrian Suess, Huan Liu, Mitchell Levesque, Sabine Werner, Edoardo Mazza, Gaetana Restivo, Mirko Meboldt, Costanza Giampietro
Summary: Human skin equivalents (HSEs) play a crucial role in tissue engineering. This study introduces a 3D-printed culture insert to apply a static radial constraint on HSEs and examines its effects on tissue characteristics. The results show that the diameter of the culture insert significantly influences tissue contraction, fibroblast and matrix organization, keratinocyte differentiation, epidermal stratification, and basement membrane formation. This study provides important insights for the design of skin tissue engineering.
BIOMATERIALS ADVANCES
(2024)
Review
Materials Science, Biomaterials
Shiliang Chen, Tianming Du, Hanbing Zhang, Jing Qi, Yanping Zhang, Yongliang Mu, Aike Qiao
Summary: This paper reviewed the primary methods for improving the overall properties of biodegradable zinc stents. It discussed the mechanical properties, degradation behavior, and biocompatibility of various improvement strategies. Alloying was found to be the most common, simple, and effective method for improving mechanical properties. Deformation processing and surface modification further improved the mechanical properties and biological activity of zinc alloys. Meanwhile, structural design could endow stents with special properties. Manufacturing zinc alloys with excellent properties and exploring their interaction mechanism with the human body are areas for future research.
BIOMATERIALS ADVANCES
(2024)