4.6 Article

Fabrication and characterization of n-type aluminum-boron co-doped ZnO on p-type silicon (n-AZB/p-Si) heterojunction diodes

期刊

MATERIALS RESEARCH BULLETIN
卷 48, 期 11, 页码 4596-4600

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2013.07.061

关键词

Oxides; Thin films; Sol-gel chemistry; Electrical properties; Optical properties

向作者/读者索取更多资源

In this paper, the growth of n-type aluminum boron co-doped ZnO (n-AZB) on a p-type silicon (p-Si) substrate by sol gel method using spin coating technique is reported. The n-AZB/p-Si heterojunctions were annealed at different temperatures ranging from 400 to 800 degrees C. The crystallite size of the AZB nanostructures was found to vary from 28 to 38 nm with the variation in annealing temperature. The band gap of the AZB decreased from 3.29 to 3.27 eV, with increasing annealing temperature from 400 to 700 degrees C and increased to 3.30 eV at 800 degrees C probably due to the formation of Zn2SiO4 at the interface. The band gap variation is explained in terms of annealing induced stress in the AZB. The n-AZB/p-Si heterojunction exhibited diode behavior. The best rectifying behavior was exhibited at 700 degrees C. (C) 2013 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Optics

Near-infrared emission in perovskite oxides MZrO3:Bi (M = Ba, Sr) by dopants' selective site occupancy

Yuanyuan Li, Puxian Xiong, Bibo Lou, Hendrik C. Swart, Chonggeng Ma, Zhiguo Xia

Summary: Broadband NIR emission is achieved in Bi3+ activated perovskite oxides MZrO3 (M = Ba, Sr), and the luminescence mechanism is revealed through experimental and first-principles studies. The valence state of Bi3+ ions is confirmed to be trivalent, and the possibility of NIR emission from lower state bismuth is excluded. The selective occupancy of Bi3+ in different sites enables the emission discrepancy, where Bi3+ on M2+ sites accounts for visible emission while Bi3+ on Zr4+ sites shows NIR emission. The existence of Ba2+ vacancy has a significant influence on the emission spectra of Bi3+ visible emission.

JOURNAL OF LUMINESCENCE (2023)

Article Materials Science, Coatings & Films

Method for extracting the intrinsic diffusion coefficient from grain boundary diffusion depth profile

Songyou Lian, Antonie J. Fourie, Jiangyong Wang, Hendrik C. Swart, Jacobus Johannes Terblans

Summary: Numerical research is conducted on grain boundary diffusion of Cu-Ni bilayer thin films, considering the composition-dependent interdiffusion coefficient and the position of the grain boundary. Fick's second law provides a quantitative assessment of the effects of various factors on the depth profile. A method is proposed to eliminate the impacts of grain boundaries and grain size on the grain boundary diffusion profile, yielding a profile similar to the direct volume diffusion profile. The calculated diffusion parameters are within the bounds of available data.

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A (2023)

Article Chemistry, Multidisciplinary

Microwave-assisted hydrothermal synthesis of LaOF:Yb3+, Ho3+nanorods with high thermoresponsive upconversion luminescence for thermometry

Govind B. Nair, Sumedha Tamboli, R. E. Kroon, H. C. Swart

Summary: Non-contact thermometry using upconversion luminescence from lanthanide-doped nanoparticles is the ideal option for high precision, accuracy, sensitivity, and spatial resolution temperature probes. This study demonstrates the use of LaOF:Yb3+,Ho3+ upconversion nanoparticles as thermometers with high sensitivity and thermal stability in the temperature range of 303-673 K. The rod-shaped UCNPs with a trigonal crystal structure were obtained through microwave-assisted hydrothermal synthesis. The upconversion emissions from these UCNPs showed green and red emissions under continuous-wave laser irradiation, corresponding to thermally-coupled levels and Stark-split sublevels of the energy level, respectively.

MATERIALS TODAY CHEMISTRY (2023)

Article Multidisciplinary Sciences

Substrate temperature dependence of structure and optical properties of ZnTiO3:Er3+/Yb3+thin films synthesized by pulsed laser deposition

S. J. Mofokeng, F. V. Molefe, R. E. Kroon, H. C. Swart, T. P. Mokoena, M. S. Dhlamini, M. J. Sithole, L. L. Noto

Summary: ZnTiO3:Er3+,Yb3+ thin film phosphors were successfully deposited by pulsed laser deposition (PLD) at different substrate temperatures. The distribution of the ions in the films was homogeneous and chemical analysis confirmed uniform doping. The optical response of the phosphors varied with the silicon substrate temperature, and under 980 nm diode laser excitation, the ZnTiO3:Er3+,Yb3+ film phosphors displayed up-conversion emission from the Er3+ electronic transitions.

HELIYON (2023)

Article Energy & Fuels

Molybdenum-Tungsten carbides based electrocatalysts for hydrogen evolution reaction

Busisiwe Petunia Mabuea, Elizabeth Erasmus, Hendrik Christoffel Swart

Summary: Tungsten carbide-based and molybdenum carbide-based nano-catalysts were synthesized and evaluated as electrocatalysts. The Ni-WC coated electrode exhibited the best catalytic activity for the hydrogen evolution reaction with the lowest overpotential and Tafel slope compared to Pt/C coated electrodes. The Ni-MoC and Co-MoC coated electrocatalysts also showed improved current production and potential change compared to Pt/C coated electrode. The durability test demonstrated the high stability of Co-WC, NiCo-WC, and Ni-MoC coated electrodes.

INTERNATIONAL JOURNAL OF SUSTAINABLE ENERGY (2023)

Article Biochemical Research Methods

Luminescence Thermometry Based on the Upconversion Luminescence from the Stark Sublevels of BaY2F8:Yb3+, Tm3+ Phosphor

Ashwini K. Sharma, Govind B. Nair, S. J. Dhoble, Robin E. Kroon, J. J. Terblans, H. C. Swart

Summary: Visible and near-infrared upconversion luminescence from BaY2F8: Yb3+, Tm3+ systems was studied under 980 nm laser excitation. BaY2F8:20 mol% Yb3+, x mol% Tm3+ and BaY2F8: y mol% Yb3+, 0.5 mol% Tm3+ phosphors exhibited prominent upconversion luminescence at 800 and 810 nm. The optimized doping concentrations of Yb3+ and Tm3+ in the BaY2F8 host matrix were evaluated, their spectroscopic properties were determined, and temperature-dependent behavior was investigated by studying the fluorescence intensity ratio of the upconversion peaks.

JOURNAL OF FLUORESCENCE (2023)

Article Physics, Condensed Matter

Anomalous emission of Yb2+in CaF2:Tb3+, Yb3+up-conversion phosphor

M. Y. A. Yagoub, H. C. Swart, E. Coetsee

Summary: Anomalous emission of ytterbium was observed in terbium-ytterbium co-doped CaF2 up-conversion nanophosphor, which has potential applications in optical communication, sensing, and imaging. The addition of lithium ions as charge compensators decreased the anomalous emission of ytterbium ions. Understanding and applying the mechanism of this anomalous emission could have significant technological implications.

PHYSICA B-CONDENSED MATTER (2023)

Article Physics, Condensed Matter

Plasmonic photocatalysts as emerging multifunctional nanomaterials for energy and environmental applications

Jai Prakash, Hendrik Swart

Summary: Plasmonic photocatalysts are multifunctional nanomaterials composed of noble metals and wide band gap semiconductors. They show promising opto-electronic and photocatalytic properties due to the unique surface plasmon resonance and photocatalytic properties of noble metals and semiconductors, respectively. Recently, they have shown great potential as multifunctional/multidisciplinary nanomaterials and have been extensively studied for their enhanced functionalities in the fields of energy and environment.

PHYSICA B-CONDENSED MATTER (2023)

Article Physics, Multidisciplinary

Simultaneous realization of FIR-based multimode optical thermometry and photonic molecular logic gates in Er3+ and Yb3+ co-doped SrTiO3 phosphor

Ishant Kumar, Avinash Kumar, Sandeep Kumar, Govind B. Nair, H. C. Swart, Arvind K. Gathania

Summary: In this study, Er3+ and Yb3+ co-doped SrTiO3 phosphors were synthesized and characterized. The phosphors exhibited green and red emissions under infrared excitation and showed temperature sensing capabilities. Additionally, the phosphors were used to design photonic molecular logic gates.

PHYSICA SCRIPTA (2023)

Article Nanoscience & Nanotechnology

LaOF:Yb3+, Er3+ Upconversion Nanophosphors Operating at Low Laser Powers for Nanothermometry Applications

Govind B. B. Nair, Sumedha Tamboli, S. J. Dhoble, Hendrik C. C. Swart

Summary: Luminescence nanothermometers based on LaOF:Yb3+, Er3+ upconversion nanoparticles were studied. The fluorescence intensity ratio (FIR) of the nanoparticles was recorded at different temperatures in the visible and near-infrared regions. Optimal laser conditions were identified to prevent laser heating of the nanoparticles. The behavior of the nanoparticles under laser exposure was analyzed to determine the critical laser power below which laser heating was negligible. This approach serves as a benchmark for testing luminescent nanothermometers.

ACS APPLIED NANO MATERIALS (2023)

Article Chemistry, Multidisciplinary

Luminescence and stability of Tb doped CaF2 nanoparticles

E. H. H. Hasabeldaim, H. C. Swart, R. E. Kroon

Summary: The luminescence properties of CaF2:Tb3+ nanoparticles were investigated to understand the impact of CaF2 native defects on the photoluminescence dynamics of Tb3+ ions. The incorporation of Tb ions into the CaF2 host was confirmed through X-ray diffraction and X-ray photoelectron spectroscopy. Cross-relaxation energy transfer was observed in the photoluminescence spectra and decay curves upon excitation at 257 nm. However, the presence of traps was indicated by the unusually long lifetime of the Tb3+ ion and the decreasing emission lifetime of the D-5(3) level, which was further studied using temperature-dependent photoluminescence measurements, thermoluminescence, and lifetime measurements at different wavelengths. This study highlights the important role of CaF2 native defects in the photoluminescence dynamics of Tb3+ ions incorporated in a CaF2 matrix. The sample doped with 10 mol% of Tb3+ ions exhibited good stability under prolonged 254 nm ultraviolet irradiation.

RSC ADVANCES (2023)

Article Physics, Condensed Matter

Producing ZnO films that exhibited near-infrared (NIR) luminescence with a templated design procedure

Osama K. M. Bashiar, R. E. Kroon, H. C. Swart, R. A. Harris

Summary: ZnO thin films with near-infrared emission were successfully fabricated using pulsed laser deposition under vacuum conditions, without the need for additional gases or implantation methods. The NIR emission was hypothesized to be caused by defects in the ZnO film due to high energy particle impacts on the sample surface.

PHYSICA B-CONDENSED MATTER (2024)

Article Chemistry, Inorganic & Nuclear

Facile synthesis of high surface area of p-n Co3O4-In2O3 heterostructure-based sensor for improved xylene detection at low temperature

Rethabile Makole, Zamaswazi P. Tshabalala, Mudalo Jozela, Franscious R. Cummings, Hendrik C. Swart, David E. Motaung

Summary: This study focuses on the gas sensing properties of Co3O4 - n-type semiconducting metal oxides (Co-nSMOs) heterostructures, particularly the Co3O4-In2O3 (Co-In) heterostructure which exhibited excellent selectivity and response towards xylene. The Co-In sensor showed good sensitivity, low limit of detection, and long-term stability. The improved performance can be attributed to enriched surface oxygen adsorption and the synergistic combination of Co3O4 and In2O3 at the nanoscale p-n heterojunction.

INORGANIC CHEMISTRY COMMUNICATIONS (2023)

Article Chemistry, Physical

Fabrication of metal-organic frameworks derived Co3O4 loaded on TiO2: Influence of Fe loading on the Co3O4/TiO2 heterostructure for low-ppm benzene detection

Thabang J. Theka, Boiketlo R. J. Thamaga, Zamaswazi P. Tshabalala, Rapelang G. Motsoeneng, Hendrik C. Swart, David E. Motaung

Summary: In this study, low-concentration benzene detection was achieved by loading Fe3+ on the surface of Co3O4/TiO2, and low detection limits were provided. The heterostructure-based sensor exhibited good stability and high response to benzene.

APPLIED SURFACE SCIENCE (2024)

Article Materials Science, Multidisciplinary

Structural, optical and temperature-sensing properties of LaOF:Yb3+, Tm3+ nanophosphor prepared by microwave-assisted hydrothermal synthesis

Sumedha Tamboli, Govind B. Nair, Ashwini K. Sharma, S. J. Dhoble, H. C. Swart

Summary: Luminescence thermometry is a unique tool for remote temperature sensing, which exploits the variations in the luminescence properties of the probe. Thermometry based on fluorescence intensity ratios (FIR) is widely used due to its self-referenced measure. A study discovered LaOF:Yb3+,Tm3+ upconversion nanoparticles that exhibit blue and near-infrared upconversion photoluminescence under 980 nm laser excitation, making them suitable for temperature sensing.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Non-synthetic luminescent graphene quantum dots in coconut water for aniline sensing applications

A. Aly, M. Ghali, A. Osman, M. K. El Nimr

Summary: This study reports the discovery of naturally occurring luminescent graphene quantum dots (GQDs) in coconut water for the first time. The GQDs were identified through various measurements and were found to have dual sizes and emit different wavelengths of light. The GQDs were also utilized as an efficient optical sensor for aniline liquid detection.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

High-performance e-VOPO4 cathode materials for sodium ion battery applications

Zehua Chen, Wencheng Ma, Qinglu Fan, Yanhua Liu, Min Sun, Shuo Wang

Summary: The nanoscale e-VOPO4 materials were successfully prepared by hydrothermal synthesis and calcination, showing high purity and suitable particle size. It exhibited satisfactory electrochemical performance as cathode material for sodium ion batteries, making it a potential candidate for high energy storage systems.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Multifunctional terahertz device with active switching between bimodal perfect absorption and plasmon-induced transparency

Tao Liu, Yahui Liu, Le Ling, Zhongxi Sheng, Zao Yi, Zigang Zhou, Yongjia Yang, Bin Tang, Qingdong Zeng, Tangyou Sun

Summary: In this paper, a terahertz (THz) micronano device that can switch between bimodal absorption and plasmon-induced transparency (PIT) is proposed. The device consists of layers of graphene, silica, and vanadium dioxide, and has a simple structure, easy tuning, and wide-angle absorption. The device achieves perfect absorption at specific frequencies and is highly sensitive to environmental refractive index. It also has the functions of a three-frequency asynchronous optical switch and slow light effect.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Direct laser printing of 3D optical imaging based on full-spectrum solar-absorption-enhanced perovskite-type oxides

Xiaobo Luo, Songhan Hu, Qiudong Duan, Dacheng Zhou, Jialin Chen, Yugeng Wen, Jianbei Qiu

Summary: The exploration of solar light absorption by a material is important in photonics and optoelectronics. This study reveals the potential of Ba3-xGa2O6:xBi3+ as a promising candidate for various photonic and optoelectronic applications, and demonstrates the use of the material in double-sided laser printing for three-dimensional optical imaging.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Interface and magnetic-dielectric synergy strategy to develop Fe3O4-Fe2CO3/multi-walled carbon nanotubes/reduced graphene oxide mixed-dimensional multicomponent nanocomposites for microwave absorption

Hemin Wang, Yanling Hao, Lele Xiang, Xiaosi Qi, Lei Wang, Junfei Ding, Yunpeng Qu, Jing Xu, Wei Zhong

Summary: This study designed Fe3O4-FeCO3/MWCNTs/RGO MCNCs composites and fabricated large-scale samples using hydrothermal and freeze-drying methods. The microstructural investigation showed that these materials had a mixed-dimensional structure, which improved impedance matching features, polarization, and conduction loss abilities, leading to significantly enhanced electromagnetic absorption properties.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

All-dielectric terahertz metamaterial with polarization switching characteristic

Zhenshan Yu, Hao Chen, Xuequan Chen, Yu-Sheng Lin

Summary: This study presents a silicon dielectric metamaterial (SDM) composed of two outer symmetric semi-circular rings and two inner symmetric split-ring resonators (SRRs). The electromagnetic responses of the SDM device in different modes were studied through numerical simulations and experiments. Increasing the structure height of the SDM device resulted in red-shifted resonances and stronger intensities. This study provides a new design strategy for the development of frequency filtering, polarization switching, and resonance modulation characteristics in THz-wave applications.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

α-PW11Fe(Co/Ni)/BC derived carbon fiber based nanocomposites for high efficiency electromagnetic wave absorption via synergistic effects of polarization and conductance

Yiming Qi, Na Zhang, Meng Zong, Yangxianzi Liu, Weixing Chen

Summary: This study prepares dielectric/carbon fiber based nanocomposites wave-absorbing materials using liquid diffusion and high temperature carbonization strategies. By tuning the element type, drying mode, and filling amount, the electromagnetic parameters and absorbing properties can be adjusted. The best synthesized sample shows excellent absorbing performance, making it suitable for a wide range of electromagnetic wave absorption applications.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Study of the centers responsible for the TL emission by EPR and PL analysis of Eu-doped CaSiO3 phosphors synthesized by the devitrification method

Carlos D. Gonzales-Lorenzo, T. K. Gundu Rao, Alberto A. Ccollque-Quispe, Jorge Ayala-Arenas, Monise B. Gomes, Betzabel N. Silva-Carrera, Roseli F. Gennari, Valeria S. Pachas, F. Monzon-Macedo, H. Loro, Jose F. D. Chubaci, Nilo F. Cano, Rene R. Rocca, Shigueo Watanabe

Summary: In this study, CaSiO3 doped with different ppm of Eu was synthesized using the devitrification method. Various physical properties were analyzed, revealing that the intensity and temperature of the high-temperature TL peak increased with higher dopant amounts. Fluorescence measurements indicated the presence of Eu2+ and Eu3+ ions in the samples. EPR spectra confirmed the existence of two defect centers.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Synergetic assembly of a molybdenum disulfide/carbon quantum dot heterojunction with enhanced light absorption and electron transfer di-functional properties for photocatalysis

Yanning Qu, Xinyang Li, Mei Cui, Renliang Huang, Wanquan Ma, Yunting Wang, Rongxin Su, Wei Qi

Summary: In this study, a new molybdenum disulfide/N,S-doped carbon quantum dots (MoS2/N,S-CQDs) heterojunction with enhanced light absorption and electrons transfer di-functional properties was constructed via a facile one-pot hydrothermal method. The heterojunction showed remarkable efficiencies in degrading methylene blue (MB) and malachite green (MG) in an actual water system under simulated sunlight irradiation. The facile synthetic technique and effective multifunctional properties of the composite have the potential for further research and industrial applications.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Acid-alkali assisted synthesis of white tremella-like g-C3N4 homojunction for photocatalytic degradation under visible light

Jiayi Wang, Penggang Ren, Xueyan Zhao, Zhengyan Chen, Yanling Jin, Zengping Zhang

Summary: In this study, a novel homojunction photocatalyst was developed by combining defective g-C3N4 and flaked g-C3N4, which showed excellent degradation performance and cycling stability, and exhibited practicality in several simulation experiments.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Zn-MOF-derived hierarchical carbon nanorods superstructures with tunable microwave absorption properties

Jing Yan, Xiaoxiao Zhao, Weixing Chen, Panbo Liu

Summary: This research presents a self-templated strategy to prepare a spherical superstructure of carbon nanorods through material modification and pyrolysis. The resulting material exhibits a large controllable radius of curvature and shows excellent microwave absorbing properties due to its high specific surface area and mesoporous structure.

MATERIALS RESEARCH BULLETIN (2024)

Review Materials Science, Multidisciplinary

Electrolytes for liquid metal batteries

Qinglin Zeng, Zepeng Lv, Shaolong Li, Bin Yang, Jilin He, Jianxun Song

Summary: Liquid metal batteries possess stable safety performance, high rate performance, and thermal stability. The electrolyte, an important component of the battery, plays a significant role in achieving these remarkable performance characteristics. This paper reviews the important research progress of liquid metal batteries electrolyte and discusses the influence of different electrolyte types on energy efficiency. It also highlights the limitations and challenges of existing electrolytes and proposes key development directions for liquid metal electrolytes.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Mn3O4@C micro-flakes modified Ti/TiH2/β-PbO2 anode for accelerating oxygen evolution reaction in zinc electrowinning

Song Wu, Junli Wang, Xuanbing Wang, Di Jiang, Jinlong Wei, Xiaoning Tong, Zhenwei Liu, Qingxiang Kong, Naixuan Zong, Ruidong Xu, Linjing Yang

Summary: In this study, a composite electrode composed of Ti/TiH2/beta-PbO2_Mn3O4@C was fabricated and investigated for zinc electrowinning. The composite electrode exhibited low overpotential, Tafel slope, icorr, and high voltage stability, outperforming most reported Ti-based PbO2 electrode materials. The excellent catalytic activity can be attributed to the low resistance and porous interlayer of TiH2 nanosheets, as well as the addition of Mn3O4@C micro-flakes to the active layer.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Simulation study of a nanomaterial interacting with ionizing radiation through OTOR and IMTS models for different particle sizes

E. Tsoutsoumanos, T. Karakasidis, N. Laskaris, P. G. Konstantinidis, G. S. Polymeris, G. Kitis

Summary: This study investigates the correlation between nanocrystal dimensions and thermoluminescence signal magnitude through simulations conducted in Python. Two mathematical models, OTOR and IMTS, were used to derive theoretical luminescence signals. The obtained results were compared with experimental data and a thorough comparative discussion was conducted.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Enhanced photoresponsivity in Bi2Se3 decorated GaN nanowall network-based photodetectors

Vishnu Aggarwal, Sudhanshu Gautam, Aditya Yadav, Rahul Kumar, Bipul Kumar Pradhan, Brajesh S. Yadav, Govind Gupta, Senthil Kumar Muthusamy, Sumeet Walia, Sunil Singh Kushvaha

Summary: Recently, there has been a great demand for highly responsive photodetectors that can detect a wide range of wavelengths. Researchers have successfully fabricated a broadband metal-semiconductor-metal photodetector by integrating sputtered Bi2Se3 with laser molecular beam epitaxy grown GaN film. This photodetector shows high responsivity in both the ultraviolet and near-infrared regions.

MATERIALS RESEARCH BULLETIN (2024)