4.6 Article

Growth morphology study of cathodically electrodeposited Fe3O4 thin films at elevated temperatures

期刊

MATERIALS RESEARCH BULLETIN
卷 45, 期 11, 页码 1696-1702

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2010.06.065

关键词

Magnetic materials; Electron microscopy; X-ray diffraction; Microstructure

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We investigated the electrodeposition of Fe3O4 thin films in the Fe3+-triethanolamine system by galvanostatic deposition at elevated temperatures. It was found that with a fixed current density, the concentration of Fe3+ ions had a significant impact on the electrodeposition rate, while the deposition temperature and time strongly affected the morphology of the Fe3O4 thin films. Fe3O4 thin films deposited in electrolyte with high Fe3+ concentration and at high temperature (>80 degrees C) exhibited a dense and uniform morphology and were composed of globular or polyhedral crystallites, while the Fe3O4 thin films deposited at low temperatures (<70 degrees C) were loose and flake-like. Based on the empirical observations, a hypothetical growth model for the electrodeposition of Fe3O4 at elevated temperatures was proposed. (C) 2010 Elsevier Ltd. All rights reserved.

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