4.6 Article Proceedings Paper

Solvothermal synthesis of copper sulfide semiconductor micro/nanostructures

期刊

MATERIALS RESEARCH BULLETIN
卷 45, 期 3, 页码 309-313

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2009.12.013

关键词

Semiconductors; Chemical synthesis; Crystal growth; Microstructure

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Covellite copper sulfide (CuS) micro/nanometer crystals in the shape of hierarchical doughnut-shaped, superstructured spheric-shaped and flowerlike architectures congregated from those nanoplates with the thickness of 20-100 nm have been prepared by a solvothermal method. The as-obtained CuS products were characterized by means of scanning electron microscopy (SEM), X-ray diffractometry (XRD) and energy-dispersive X-ray spectroscopy (EDS). A systematic investigation has been carried out to understand the factors influencing the evolution of CuS particle morphology which found to be predominant by solvent, surfactant, sulfur resource and copper salt. The possible formation mechanism for the nanostructure formation was also discussed. These CuS products show potential applications in solar cell, photothermal conversion and chemical sensor. (C) 2009 Elsevier Ltd. All rights reserved.

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