期刊
RESEARCH ON CHEMICAL INTERMEDIATES
卷 42, 期 2, 页码 1537-1556出版社
SPRINGER
DOI: 10.1007/s11164-015-2101-7
关键词
ZrO2/gamma-Al2O3; Methanol; Dehydration; DME
A series of ZrO2/gamma-Al2O3 catalysts were prepared by incipient wetness impregnation of zirconyl nitrate hydrate aqueous solutions on nano-gamma-Al2O3 with ZrO2 loadings (1-30 % w/w) and calcined at 450 and 550 A degrees C for 3 h in a static air atmosphere. Physicochemical properties of the catalysts were determined using TG, DTA, XRD, FT-IR, Raman spectroscopy, TEM, and N-2 sorption measurements. The surface acidity of the catalysts was investigated by dehydration of isopropanol and adsorption of pyridine, 2,6-dimethyl pyridine and TPD-pyridine. This series of catalysts was used for vapor-phase dehydration of methanol to dimethyl ether in a fixed bed reactor. It was found that all catalysts in this study were active and selective for DME synthesis. According to the experimental results, 1 % ZA catalyst exhibited the highest activity with selectivity of 100 % toward DME.
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