4.6 Article

Trimethylamine sensing properties of CdO-Fe2O3 nano-materials prepared using co-precipitation method in the presence of PEG400

期刊

MATERIALS CHEMISTRY AND PHYSICS
卷 123, 期 2-3, 页码 396-400

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2010.04.028

关键词

CdO-Fe2O3; Trimethylamine; Gas sensor

资金

  1. Education Department of Anhui Province [KJ2009A120]
  2. National Basic Research Program of China (973 Program) [2008CB617605]

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CdO-Fe2O3 precursors are prepared using co-precipitation method in the presence of PEG400. CdO-Fe2O3 nano-powders are obtained through heating the precursors under different conditions. CdO-Fe2O3 thick film sensors are fabricated using CdO-Fe2O3 nano-materials as sensing materials. The XRD analysis results reveal that CdO-Fe2O3 is mainly composed of CdFe2O4 when the precursor is heated at 700 degrees C for 2 h and the mole ratio of Cd/Fe is 1:2 in the starting materials. The TEM images show that the average particle sizes increase with heating temperature increasing, the particle sizes are in the range of 15-25 nm when heating temperature is 700 degrees C (2 h). The influence of the heating duration and heating temperature on the gas-sensing properties of the sensors based on CdO-Fe2O3 nano-materials are investigated. The responses to a few kinds of organic gases, such as (CH3)(3)N and C2H5OH are studied. It is found that the sensor based on CdO-Fe2O3 nano-material (700 degrees C, 2 h) exhibits high response to dilute trimethylamine when operating at 230 degrees C. The responses to 1000 ppm and 0.01 ppm (CH3)(3)N at 230 degrees C are 1527 and 2, respectively. The response time and recovery time for 1000 ppm trimethylamine are 70 and 170 S. (C) 2010 Elsevier B.V. All rights reserved.

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