Article
Construction & Building Technology
Meicen Fan, Yue Chen, Keshu Wan
Summary: By analyzing the microstructure information of cement paste through high resolution X-Ray Computed Tomography (XCT), the Representative Elementary Volume (REV) size of hardened cement paste (HCP) can be obtained. REV size is influenced by the selected microstructure information, XCT resolution, and hydration ages, with a decreasing trend as XCT resolution improves and a first increase then decrease pattern with hydration ages.
CONSTRUCTION AND BUILDING MATERIALS
(2021)
Article
Construction & Building Technology
Michal Hlobil, Ivana Kumpova, Adela Hlobilova
Summary: An analysis of digitized 3D cement paste microstructures found a consistent size of cement grains ranging from 30-40 µm throughout hydration. The shape of the particle size distribution (PSD) remained self-similar, and the hydration process was identified to have two distinct stages, correlating with the reactivity peak of calcium sulfate.
CEMENT & CONCRETE COMPOSITES
(2022)
Article
Construction & Building Technology
Zhigang Zhu, Wenxiang Xu, Huisu Chen, Yuan Wang, Xiaofan Gou, Lin Liu, Yue Gu
Summary: The study investigates the relationship between the relative diffusivity of cement paste and the evolution of its microstructure guided by a diffusivity model. The results indicate that an increase in sphericity, as a shape descriptor of cement particles, leads to an increase in relative diffusivity.
CEMENT & CONCRETE COMPOSITES
(2021)
Article
Energy & Fuels
Wei Liu, Dongyang Han, Gang Wang, Xiangyu Chu
Summary: CT scanning is an essential tool for evaluating coal microstructure, providing non-destructive quantization and visualization. By analyzing the representative elementary volume (REV) of coal samples, a relationship between model sizes and pore structure properties has been established. The comprehensive evaluation of REV improves the rationality and reliability of coal microstructure reconstruction.
Article
Construction & Building Technology
Fangfang Zhi, Yu Jiang, Ming-Zhi Guo, Weizhun Jin, Xiancui Yan, Pengfei Zhu, Linhua Jiang
Summary: This study investigated the influence of polyacrylamide on the carbonation behaviors of cement pastes. It was found that polyacrylamide reduces the amount of portlandite and alters its morphology, enhancing its reactivity with CO2. It also results in the formation of C-S-H phases with a higher carbonation rate and improves pore refinement.
CEMENT AND CONCRETE RESEARCH
(2022)
Article
Construction & Building Technology
Jamal Khatib, Rawan Ramadan, Hassan Ghanem, Adel Elkordi
Summary: In this study, it was found that replacing 15% of limestone fines can enhance the chemical shrinkage of the paste, while autogenous shrinkage increases between 0 and 10% replacement and sharply decreases at 15% and 20% replacement. Drying shrinkage increases with the increase in limestone fines content, and expansion increases for replacements above 15% limestone fines.
Article
Construction & Building Technology
Jian Zhang, Hai-long Wang, Zhi-wei Chen, Qing-feng Liu, Xiao-yan Sun, Jian-jun Zheng
Summary: The shape of cement particles has a significant impact on the hydration process, pore structure, and chloride ingression of cement paste. This study proposed a numerical method to analyze the influence of cement particle shape on chloride diffusivity, and verified its effectiveness through experiments.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Construction & Building Technology
Jinrui Zhang, Ziye Kang, Youzhi Yang, Biqin Dong, Hongyan Ma
Summary: The use of natural organic compounds to improve the performance of cement-based materials can promote the green and sustainable development of the construction industry. This study Overcomes the retarding effect of tannic acid (TA) by adding less than 0.1% content and curing samples in thermal regime. The addition of 0.025% TA enhances the strength of heat-cured cement pastes by more than 11.4% and 34.6% for compressive and flexural strengths, respectively.
CEMENT & CONCRETE COMPOSITES
(2023)
Article
Construction & Building Technology
Shuai Bai, Xinchun Guan, Hui Li, Jinping Ou
Summary: The early hydration and microstructure of cement paste with nanocellulose (CNC) at different water-cement ratios were studied. The results showed that CNC can delay the ending time of the induction period and acceleration period, reduce the main exothermic peak, and inhibit early hydration. The inhibition effect becomes more significant with the increase of CNC dosage. CNC also inhibits the formation of ettringite and portlandite, and delays the formation and deposition of early hydration products. The inhibition effects of CNC on early hydration exotherms and hydration products differ at low and high water-cement ratios.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Construction & Building Technology
Van Thong Nguyen, Seon Yeol Lee, Sang-Yeop Chung, Jae-Heum Moon, Dong Joo Kim
Summary: This study investigated the influences of cement particle distribution on the hydration process of cement paste using three-dimensional computer simulation. Random distribution method required less time in generating models and showed similar results to the correlation function method.
CONSTRUCTION AND BUILDING MATERIALS
(2021)
Article
Construction & Building Technology
Shan He, Yu Chen, Minfei Liang, En-Hua Yang, Erik Schlangen
Summary: This study examines the changes in microstructure of cement paste caused by the inclusion of polymeric microfiber under different water-to-cement ratios. It also presents a method to quantify the porosity of epoxy impregnated interfacial transition zone (ITZ). The results show that the microstructures of the ITZ below and above a microfiber are significantly different, with the lower ITZ having a higher porosity. The porosity gradients of the lower ITZs become steeper with higher water-to-cement ratio.
CEMENT & CONCRETE COMPOSITES
(2023)
Article
Chemistry, Multidisciplinary
Kai Cui, Jun Chang, Mohanad Muayad Sabri Sabri, Jiandong Huang
Summary: This study investigated the effect of graphene nanoplates (GNPs) on the hydration process and products of sulfoaluminate cement (SAC). The results showed that GNPs can accelerate SAC hydration, promote the formation of hydration products, and improve the mechanical properties of the cement matrix.
Article
Thermodynamics
Yun Gao, Kai Wu, Zhidan Rong, Qiang Yuan
Summary: The paper presents a general modeling framework for molecular diffusivity in cement paste, which can predict the molecular diffusivity in cement paste from the knowledge of structural features as determined through experiments.
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
(2021)
Article
Construction & Building Technology
Xiangping Xian, Yixin Shao
Summary: This study found that ambient pressure carbonation can achieve comparable carbon uptake and strength gain as high pressure carbonation at both early and late age, making it more economic and practical for precast products. Nitrogen adsorption/desorption results revealed that ambient pressure performed better than high pressure in reducing the cumulative pore volume and refining the capillary pore size.
CONSTRUCTION AND BUILDING MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Wael Emad, Ahmed Salih, Rawaz Kurda, A. M. T. Hassan
Summary: This study investigated the impact of two types of polymer on the stress-strain behavior, elastic modulus, and toughness of cement paste. The addition of polymers increased compressive strength and density of the cement, but reduced ductility over time. The modified cement exhibited improved mechanical properties due to the filling of voids and increased density from the addition of polymers.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Review
Construction & Building Technology
Hui Zhong, Mingzhong Zhang
Summary: This paper presents a comprehensive review of the recent advances in engineered geopolymer composites (EGC), discussing the effects of different material composition factors on their properties and comparing them with typical engineered cementitious composites (ECC). By modifying the material composition, the tensile behavior of EGC can be tailored, making it a cost-effective and sustainable material for various applications.
CEMENT & CONCRETE COMPOSITES
(2023)
Review
Construction & Building Technology
Wenlin Tu, Mingzhong Zhang
Summary: Alkali-activated concrete (AAC) is an innovative and sustainable construction material that can replace Portland cement concrete. However, AAC is vulnerable to deterioration at elevated temperatures due to thermal incompatibility, pore pressure build-up, and phase transformation. This paper provides a comprehensive review on the behavior of various types of AAC at elevated temperatures, including phase stability, microstructural evolution, and thermal and mechanical performance. Effective strategies for improving the high-temperature resistance of AAC are discussed, with a focus on tackling different damage mechanisms. The paper summarizes recent advances in the field and identifies future research challenges and opportunities.
CEMENT & CONCRETE COMPOSITES
(2023)
Review
Construction & Building Technology
Choi Lin Chan, Mingzhong Zhang
Summary: Alkali-activated concrete (AAC) is a sustainable alternative to cementitious materials, and its engineering properties can be influenced by the presence of limestone. This review examines the effects of limestone on AAC synthesized from various precursors, and discusses the underlying mechanisms and environmental impact. The findings provide insights for future research and development in this field.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Construction & Building Technology
Liang-yu Tong, Qing Xiang Xiong, Mingzhong Zhang, Zhaozheng Meng, Fekri Meftah, Qing-feng Liu
Summary: The chloride transport properties of concrete were comprehensively analyzed in this study by considering the multi-scale microstructural characteristics. A multi-scale predictive model was proposed to predict the diffusivity of bulk cement paste, mortar, and concrete. The diffusivities of each scale were validated against experimental results by considering the hydration process, the presence of sand/interfacial transition zones, and the aggregate shape. By adopting a statistical analysis method, it was found that capillary pores and C-S-H components dominate the diffusivity estimation of bulk cement paste, while the consideration of ITZ and multi-species ions interaction can enhance the prediction accuracy for diffusivities of mortars and chloride penetration depths in concrete. The proposed multi-scale framework provides a new perspective to study chloride penetration in concrete and enhances the understanding of deterioration mechanisms for reinforced concrete structures in complex or marine environments.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Construction & Building Technology
Meng Chen, Zegang Chen, Yiwei Xuan, Tong Zhang, Mingzhong Zhang
Summary: This paper presents a systematic experimental study on the static and dynamic compressive behavior of different types of ultra-high performance concrete and steel fiber reinforced UHPC. The results show that re-entrant honeycomb reinforced UHPC has better dynamic compressive behavior at high strain rates compared to other UHPC specimens. The study provides valuable insights for the manufacturing of UHPC with optimal auxetic 3D lattices.
CEMENT & CONCRETE COMPOSITES
(2023)
Review
Construction & Building Technology
Tong Zhang, Meng Chen, Yuting Wang, Mingzhong Zhang
Summary: CO2 mineralisation by recycled concrete is an innovative method to improve the sustainability of concrete products. This review provides a comprehensive overview of the carbonation mechanisms, microstructure, and mechanical properties of concrete containing carbonated recycled concrete fines and aggregates. It highlights the chemistry-microstructure-property relationships and emphasizes the benefits of using carbonated recycled aggregates in enhancing the mechanical properties of concrete. Future research opportunities for developing low-carbon concrete with recycled concrete as a carbon sink are also discussed.
CEMENT & CONCRETE COMPOSITES
(2023)
Article
Construction & Building Technology
Cheng Liu, Mingzhong Zhang
Summary: This paper presents an integrated framework for modelling chloride diffusivity in non-saturated cement paste considering 3D microstructure, water-gas distribution in pore network and electrical double layer effect. The results show that surface electric potential has a dominant influence on chloride diffusivity in C-S-H pore solution regardless of water saturation level, porosity of C-S-H and chloride concentration of bulk solution. The relative chloride diffusivity in cement paste decreases with decreasing water saturation level, and increases with increasing water-to-cement ratio. The simulation results are in good agreement with experimental data.
CEMENT AND CONCRETE RESEARCH
(2023)
Article
Construction & Building Technology
Hui Zhong, Meng Chen, Mingzhong Zhang
Summary: In this study, recycled tyre polymer (RTP) fibres were used to replace a portion of polyvinyl alcohol (PVA) fibres in engineered cementitious composites (ECC). The aim was to develop sustainable ECC with RTP fibres while maintaining engineering properties. Tests showed that the incorporation of RTP fibres improved drying shrinkage resistance but had no positive effect on workability and compressive properties. Strain-hardening behaviour was observed even when 50% of PVA fibres were substituted with RTP fibres. ECC with RTP fibres exhibited a stronger sensitivity under dynamic compression compared to ECC with PVA fibres. The material cost and energy consumption of ECC were reduced when RTP fibres were present, making it a feasible and sustainable option.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Construction & Building Technology
Hui Zhong, Meng Chen, Mingzhong Zhang
Summary: The study found that using recycled tyre steel (RTS) fibres to replace industrial steel (IS) fibres can improve the cost-effectiveness and sustainability of ultra-high performance concrete (UHPC). Through experiments, it was discovered that replacing IS fibres with 0.5-2.0% RTS fibres can enhance the flowability, compressive, flexural, and tensile strengths of UHPC, with 0.5% being the most optimal replacement level.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Construction & Building Technology
Tong Zhang, Meng Chen, Zhiguo Yan, Shuhong Wang, Mingzhong Zhang
Summary: The study investigates the influence of micro fibres on the specific heat capacity of cementitious composites at elevated temperatures. The specific heat capacity of cement mortar reinforced with different types of fibres was measured and a multiscale homogenization model was developed to predict the specific heat capacity evolution. The results show that the addition of polypropylene and glass fibres lead to significant changes in specific heat capacity, and the thermal expansion of polymer fibre enhances the specific heat capacity of mortar.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Engineering, Civil
Meng Chen, Yuting Wang, Tong Zhang, Mingzhong Zhang
Summary: This study systematically investigates the dynamic splitting tensile properties of polyvinyl alcohol (PVA) fibre reinforced engineered cementitious composites (ECC) exposed to temperatures up to 800 degrees C. Tests were conducted to analyze various properties including weight loss, elastic modulus, tensile properties, splitting tensile behavior, pore pressure, chemical evolution, and microstructural evolution of ECC. The results show that the dynamic splitting tensile properties of ECC increase with increasing strain rate regardless of temperature, and reach maximum values at 105 degrees C due to enhanced fibre-matrix bond and further hydration of fly ash. However, the dynamic tensile properties of ECC decrease at temperatures above 250 degrees C due to melting of PVA fibres, thermally induced microcracks, and dehydration of hydration products. At 800 degrees C, the dynamic splitting tensile strength and dissipated energy of ECC significantly decrease compared to room temperature. Additionally, the main role in resisting dynamic loading in ECC gradually shifts from fibre debonding-elongating action to crack propagation at temperatures above 400 degrees C, leading to a change in failure patterns.
ENGINEERING STRUCTURES
(2023)
Article
Construction & Building Technology
Hui Zhong, Yi Wang, Mingzhong Zhang
Summary: This study systematically investigates the effect of hybrid polyvinyl alcohol (PVA) fibres and recycled tyre steel (RTS) fibres on the engineering properties of fly ash-slag based engineered geopolymer composites (EGC). The results show that combining RTS fibres with PVA fibres can effectively enhance the drying shrinkage resistance, tensile strength, and dynamic mechanical properties of EGC. The incorporation of RTS fibres can significantly improve the quasi-static compressive strength and dynamic splitting tensile strength of EGC.
JOURNAL OF ADVANCED CONCRETE TECHNOLOGY
(2023)
Article
Chemistry, Physical
Zhiyuan Xu, Guang Ye
Summary: One of the key problems affecting the durability of reinforced concrete structures is chloride-induced corrosion of rebar. This paper clarifies the definition of the chloride diffusion coefficient, discusses the factors influencing diffusion process, and reviews two commonly used natural diffusion test methods. Three typical errors in numerically determining the diffusion coefficients are also highlighted.
Article
Construction & Building Technology
Tong Zhang, Mingzhong Zhang, Qing Chen, Hehua Zhu, Zhiguo Yan
Summary: This paper presents a study on the feasibility of using synergistic flame-retardant polymer (SFRP) fibers to improve the thermo-mechanical properties of calcium aluminate concrete at elevated temperatures. The tests conducted investigated the effect of SFRP fibers and cement type on thermal conductivity, compressive strength, splitting behavior, and microstructural evolutions, and explored the mechanisms for enhancing the thermo-mechanical properties of the concrete. The experimental results indicate that the combined usage of calcium aluminate binders and SFRP fibers can significantly improve the strength-sustaining capacity and prevent explosive spalling of concrete.
CEMENT & CONCRETE COMPOSITES
(2023)
Article
Construction & Building Technology
Shengqian Ruan, Shikun Chen, Yi Liu, Yajun Zhang, Dongming Yan, Mingzhong Zhang
Summary: This study introduces a new strategy to reduce the early-age shrinkage and achieve hydrophobicity in metakaolin-based geopolymer (MKG) pastes by adding organic admixtures such as polydimethylsiloxane (PDMS) and sodium methylsilicate (SMS). The pore structure, wettability, moisture/water adsorption capacity, and internal moisture distribution were analyzed using various techniques including MIP and LF-NMR. The results showed that the autogenous shrinkage of MKG paste was reduced by 91.2% and 41.6% with the addition of 5% PDMS and replacement with 20% SMS, respectively, and the water contact angle increased to approximately 130 degrees and 140 degrees. The incorporation of organic admixtures significantly reduced moisture adsorption and surface tension of the MKG matrix, leading to the transport of internal water into larger pores and decreasing liquid-vapor meniscus and capillary stress.
CEMENT AND CONCRETE RESEARCH
(2023)