期刊
RENEWABLE ENERGY
卷 77, 期 -, 页码 579-585出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.renene.2014.12.066
关键词
pi-A-porphyrin; DSSC; Optical spectra; Photovoltaic performance; Electrochemical property
资金
- National Natural Science Foundation of China [21076147]
- Natural Science Foundation of Tianjin [10JCZDJC23700]
- China International Science and Technology Project [2012DFG41980]
- Seed Foundation of Tianjin University [60302027]
- Research Fund for the Doctoral Program of Higher Education of China [20120032120011]
- High Performance Computing Centre of Tianjin University, P. R. China
Three pi-A-porphyrins containing long alkoxyl chains attached to the ortho position of phenyl ring and a phenyl carboxylate acid or acrylic acid at the mesa position of porphyrin were synthesized. All compounds were characterized by H-1 NMR and mass spectrometry. Optical and electrochemical properties were also obtained. The photovoltaic properties of these pi-A-porphyrins were examined for the first time and sensitizers N-1 and N-3 achieved comparable light to electricity conversion efficiencies: 3.94% for N-1 and 4.14% for N-3. However, preparation of N-1 required simple and cost-effective synthesis which made it a promising candidate for the future practical DSSC applications. The low efficiency conversion of N-2 was well explained by the amount of dye loading, IPCE and EIS. (c) 2015 Elsevier Ltd. All rights reserved.
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