Article
Chemistry, Multidisciplinary
Ruidong Cheng, Mingwei Xu, Xuehui Zhang, Jinqiang Jiang, Qiuyu Zhang, Yue Zhao
Summary: Poly(acrylic acid-co-N-vinylcaprolactam) (PAN) hydrogels with multiple hydrogen bonds exhibit pH-induced reversible dynamic behaviors. Transparent hydrogels placed in acid or DI water undergo a transition from transparency to opacity due to the formation of hydrogen bonds or protonation/deprotonation of COOH groups, respectively. This two-way dynamic transparency evolution in PAN-based hydrogel material enables a dynamic memory system for information memorizing-forgetting and recalling-forgetting.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Applied
Hegang Lu, Xiaoyan Li, Hongpeng Yang, Jiang Wu, Yi Zhang, Haidong Huang
Summary: The usability of Sanxan as a drug carrier was evaluated in this study, using riboflavin as a model drug. The results showed that the microcapsules prepared with Sanxan had good sphericity and regular appearance, and could be used for the sustained release of riboflavin. The viscosity structure of Sanxan was identified as an important factor in the slow release of riboflavin.
FOOD HYDROCOLLOIDS
(2022)
Article
Chemistry, Applied
Xiaojing Zhang, Yang Meng, Weiwei Shen, Jingcheng Dou, Ruixue Liu, Qingxian Jin, Shaoming Fang
Summary: This study successfully prepared a family of injectable nanocomposite hydrogels through the Schiff base reaction between OCAPS, CS, and HPC, demonstrating good biocompatibility and biodegradability. The addition of OCAPS enhanced the mechanical properties and drug load efficiency of the hydrogels, showing great potential for drug delivery and tissue engineering applications.
REACTIVE & FUNCTIONAL POLYMERS
(2021)
Article
Chemistry, Applied
Ruoyi Xu, Weijun Deng, Yunlu Dai, Jing Hu
Summary: This study successfully addressed the issue of rapid evaporation and oxidation of citral by constructing citral microcapsules. These microcapsules exhibited pH-responsive release and antioxidant properties, resulting in excellent sensory profile and antibacterial effects.
Article
Materials Science, Multidisciplinary
Yung Priscilla Lai, Zhaoxin Li, Hani Naguib, Eric Diller
Summary: The limited space on small-scale biomedical devices makes it difficult to include large actuators and power for mechanical actuation. pH-responsive hydrogels provide a solution for automatic sensing and actuation in the gastrointestinal tract, but they are typically nonload bearing and slow in their actions. To overcome these challenges, researchers have developed a new type of hybrid actuator that uses a pH-responsive hydrogel with magnets to trigger magnetic springs for quick rotational and translational movements. The hydrogel exhibits a large volume transition and high blocking stress, and an analytical model is developed to predict its force and displacement under different conditions.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Biomaterials
Wen Shi, Yunfan Kong, Yajuan Su, Mitchell A. Kuss, Xiping Jiang, Xiaowei Li, Jingwei Xie, Bin Duan
Summary: Dynamic hydrogels based on boronic ester dynamic covalent bonds exhibit good self-healing and shear-thinning capabilities, and the utilization of TA for the green synthesis of silver nanoparticles resulted in a hybrid dynamic hydrogel with potent antibacterial activities. Moreover, these hydrogels can release loaded proteins in response to pH and ROS, while also showing high free radical and ROS scavenging capacities for anti-oxidative properties.
JOURNAL OF MATERIALS CHEMISTRY B
(2021)
Article
Nanoscience & Nanotechnology
Xiaozhuang Zhou, Nan Zhang, Shruthi Kandalai, Huapeng Li, Farzana Hossain, Shiqi Zhang, Jiangjiang Zhu, Junran Zhang, Jiaxi Cui, Qingfei Zheng
Summary: Electro-responsive dynamic hydrogels with robust mechanical properties and precise spatiotemporal resolution are reported. These hydrogels are based on the rearrangement of sodium dodecyl sulfate (SDS) micelles induced by direct current voltage (DCV). The hydrogels show enlarged mesh size, high stretchability (>6000%), and toughness (507 J/m2). They also possess self-healing and malleable properties. These hydrogels have potential applications in wearable bioelectronics and smart drug delivery systems.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Food Science & Technology
Xiuting Hu, Yao Liu, Yimei Chen, Tao Zhang, Ming Miao
Summary: The pH-responsive hydrogels were prepared by carboxymethylation and phosphorylase elongation of phytoglycogen, and the properties of the hydrogels were found to be influenced by the degree of carboxymethylation.
Article
Chemistry, Multidisciplinary
Zilu Lv, Jikun Xu, Chenyu Li, Lin Dai, Huihu Li, Yongda Zhong, Chuanling Si
Summary: This study developed a pH-responsive lignin-based hydrogel inspired by traditional gel filtration and lignin's pH-responding solubility, which can be used for specific lignin fractionation. The hydrogel's pore size and water absorbency can be tuned in different pH environments, enabling efficient separation and release of lignin components. This new strategy provides a green and smart pathway for the development of not only pH-responsive hydrogels, but also lignin valorization.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Biochemistry & Molecular Biology
Pingping Wang, Chun Chen, Xiong Fu
Summary: In order to produce stable Pickering emulsion suitable for targeted delivery in the small intestine under stomach acid conditions, the emulsifying ability and pH responsiveness mechanisms of octenyl succinate anhydride modified amylose (OSA-AM) in formless and nanoparticle form were compared. The results showed that OSA-AM nanoparticles exhibited stronger ability to form stable Pickering emulsion compared to OSA-AMs. Additionally, the stability of the Pickering emulsion was found to be dependent on the pH environment, with OSA-AM nanoparticles showing increased stability in acidic conditions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Energy & Fuels
Narudee Srisawang, Amorn Chaiyasat, Piyalak Ngernchuklin, Preeyaporn Chaiyasat
Summary: Microcapsules containing bismuth vanadate (BiVO4) and magnetite (Fe3O4) nanoparticles were prepared by microsuspension iodine transfer polymerization (ms ITP) for dye treatment in wastewater. These microcapsules showed high efficiency in removing dyes, especially under alkaline conditions, and could be reused for at least five treatment times with the help of an external magnetic field.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Biophysics
Zihao Ma, Xiao Yang, Jie Ma, Jinying Lv, Juan He, Duowuni Jia, Yan Qu, Gongzheng Chen, Hengxiu Yan, Rui Zeng
Summary: A multifunctional hydrogel based on natural polysaccharides was developed with adhesion, antioxidant, pH-responsive, and antibacterial properties, showing great potential in the field of biomedicine.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2021)
Article
Engineering, Environmental
Li-yue Sun, De-hao Yu, Zhao-ge Juan, Yao Wang, Yan-xin Wang, Matt J. Kipper, Lin-jun Huang, Jian-guo Tang
Summary: Graphene oxide (GO) membranes can be used for water treatment to remove organic molecules. However, the effect of pH on GO's properties leads to poor removal of positively charged model compounds. In this study, pH-responsive polymers were used to modify GO membranes, resulting in improved removal performance, water permeance, and long-term stability.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Food Science & Technology
Huan Li, Huiting Yang, Jingjing Xu, Zexin Gao, Jianrong Wu, Li Zhu, Xiaobei Zhan
Summary: A novel OSA-CMCD amphiphilic polymer was prepared for the encapsulation and release of curcumin, demonstrating potential utility in the food and biomedical industries. The polymer showed a decrease in critical micelle concentration with increasing degree of substitution, and the curcumin loaded micelles displayed sustained pH-dependent drug release with high encapsulation efficiency and loading capacity.
LWT-FOOD SCIENCE AND TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Hao Xue, Fei Liu, Ze Wang, Delei Liu, Liang Zhou, Wenbo Su, Shichao Niu, Zhiwu Han, Luquan Ren
Summary: This article presents a simple and rapid in situ polymerization method for preparing dual-responsive photonic crystals (PCs) with ultra-precise micro-/nanoscale hierarchical structures. The obtained P(NIPAAM-co-AAc)-PCs exhibited a dual response to pH and temperature reversibility. This work allows the combination of natural hierarchical PC structures with smart hydrogel to achieve an optical response to pH and temperature, thus opening up the channels for responsive PC to multiple stimulus responses.
MATERIALS & DESIGN
(2023)
Article
Chemistry, Physical
Chaoran Li, Jinpan Zhang, Shenhua Wang, Zhijie Zhu, Haiyan Li, Ao-Bo Xu, Yingying Yu, Xiao Wang, Jie Yao, Liwei Wang, Alexander A. Solovev, Le He
CHEMISTRY OF MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Laura L. A. Adams, Daeyeon Lee, Yongfeng Mei, David A. Weitz, Alexander A. Solovev
ADVANCED MATERIALS INTERFACES
(2020)
Review
Materials Science, Multidisciplinary
Larisa B. Gulina, Valeri P. Tolstoy, Alexander A. Solovev, Vladislav E. Gurenko, Gaoshan Huang, Yongfeng Mei
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL
(2020)
Article
Chemistry, Analytical
Sumayyah Naeem, Farah Naeem, Jing Zhang, Jawayria Mujtaba, Kailiang Xu, Gaoshan Huang, Alexander A. Solovev, Yongfeng Mei
Review
Multidisciplinary Sciences
Xinyi Lin, Borui Xu, Hong Zhu, Jinrun Liu, Alexander Solovev, Yongfeng Mei
Article
Polymer Science
Zhang Wu, Joerg G. Werner, David A. Weitz
Summary: In this study, an asymmetric microcapsule shell architecture was designed to achieve a good combination of desired features, obtained from water-in-oil-in-water double emulsion drops with a graded macroporous shell and dense skin separation layer.
Article
Chemistry, Multidisciplinary
Joerg G. Werner, Hyomin Lee, Ulrich Wiesner, David A. Weitz
Summary: Polymeric microcapsules with mesoporous shells containing uniformly sized nanopores are achieved through self-assembly of amphiphilic block copolymers with a selective porogen in double emulsion drops. The microcapsules can withstand harsh conditions and exhibit pH-responsive permeability to polymeric solutes, showing potential for tunable macromolecular separation and purification as a filtration medium. Further control over shell permeability is achieved through a dual-phase separation method to fabricate microcapsules with hierarchically porous shells.
Article
Chemistry, Physical
Abigail Rendos, Wenhan Cao, Margaret Chern, Marco Lauricella, Sauro Succi, Jorg G. Werner, Allison M. Dennis, Keith A. Brown
Summary: A suspension of nanoparticles can assemble into a macroscopic cellular phase that consists of particle-rich walls and particle-free voids under the influence of AC and DC voltages. This mechanism involves electrophoretic assembly and electrohydrodynamic flow-mediated spinodal decomposition. This work not only reveals the mechanism of cellular phase formation, but also presents a method to reversibly assemble nanoscale particles into microscale continuous structures.
Article
Nanoscience & Nanotechnology
Tom Elkeles, Sinwook Park, Jorg G. Werner, David A. Weitz, Gilad Yossifon
Summary: This work presents the dielectrophoresis and in situ electrorotation characterization of reversible stimuli-responsive dynamic microcapsules that can change their physicochemical properties under varying pH conditions. The study shows that the conductivity of the capsules' shells is most influenced by pH and provides insight into the characteristic time scales of physical processes through transient response measurements. Additionally, the magnetic manipulation of microcapsules with embedded magnetic nanoparticles for lab-on-chip tasks is demonstrated, along with the on-chip determination of their physicochemical state using electrorotation.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Anton B. Resing, Chase Fukuda, Jorg G. Werner
Summary: To optimize the performance of energy storage devices, tailored electrode architectures are required to address mass transport limitations at high current rates. The use of adjustable parameters in the electrode design can enhance electrochemical and structural stability.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Wenlu Wang, Zhaoyi Zheng, Anton B. Resing, Keith A. Brown, Joerg G. Werner
Summary: This report presents an approach for obtaining conformal polymeric thin films on 3D structures using custom-designed dual-functional monomers. The authors demonstrated the full coating of a 3D mesoscaled battery electrode with an ultrathin lithium-ion permeable film using a specific monomer. The study provides insights into the control of thickness, permeability, and electronic properties of the films.
MOLECULAR SYSTEMS DESIGN & ENGINEERING
(2023)
Article
Nanoscience & Nanotechnology
Jawayria Mujtaba, Le He, Hongqin Zhu, Zhijia Xiao, Gaoshan Huang, Alexander A. Solovev, Yongfeng Mei
Summary: This study presents a novel method for preparing hydrogen evolution reaction electrocatalysts, which exhibit excellent electrocatalytic activity under both acidic and alkaline conditions. Utilizing hierarchical structures and synergy, the Co9S8 nanocomposite materials achieve high efficiency and stability.
ACS APPLIED NANO MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Sumayyah Naeem, Jawayria Mujtaba, Farah Naeem, Kailiang Xu, Gaoshan Huang, Alexander A. Solovev, Jing Zhang, Yongfeng Mei
Article
Chemistry, Multidisciplinary
Jinrun Liu, Hong Chen, Xiaojie Shi, Saraf Nawar, Joerg G. Werner, Gaoshan Huang, Miaomiao Ye, David A. A. Weitz, Alexander A. A. Solovev, Yongfeng Mei
ENVIRONMENTAL SCIENCE-NANO
(2020)