期刊
MACROMOLECULES
卷 45, 期 23, 页码 9275-9281出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma302311h
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资金
- DOE [DE-SC00005430]
- NSF [NSF-CHE-0957386]
- NRF of the Korean Ministry of Education, Science and Technology [NRF-2010-C00059]
- Marcus and Amalia Wallenberg Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0957386] Funding Source: National Science Foundation
The ring-opening polymerization of glycerol-derived six-membered cyclic dimethylacetal dihydroxyacetone carbonate (MeO(2)DHAC) have been studied both in solution and bulk conditions with organic catalysts. The guanidine 1,5,7-triazabicyclo[4.4.0]clec-5-ene (TBD) was the most active catalyst in solution, whereas the thiourea/sparteine catalytic system displayed the most predictable kinetics. Ring-opening polymerization of MeO(2)DHAC or copolymerization with epsilon-caprolactone (CL) in the melt occurred readily with TBD as catalyst to afford random copolymers. Acetal deprotection afforded the polycarbonate poly(dihydroxyactone carbonate) (p(DHAC)) or poly(carbonate ester) copolymers p(DHAC-r-CL). The polycarbonate p(DHAC) is a high-melting thermoplastic with a melting point of 246 degrees C. The p(DHAC-r-CL) copolymers all displayed semicrystalline behavior as evidenced by DSC and WAXS analysis with T-8 and T-m changing as a function of comonomer composition. These new materials could have potential use in biomedical applications or as biomass-derived thermoplastics.
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