期刊
MACROMOLECULES
卷 43, 期 1, 页码 168-176出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma902031j
关键词
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资金
- The Mitsubishi Foundation
- Sekisui Chemical Grant Program for Research oil Manufacturing Based oil Learning from Nature
- Tokyo Tech Innovative Research Engineering
- Global COE Program (Education and Research Center for Material Innovation), MEXT, Japan
- Mizuho Foundation For the Promotion of Sciences
The cooperative electrostatic and hydrogen-bonding self-assembly of polymer precursors a and the Subsequent covalent conversion have been demonstrated as ail effective means for the synthesis of polymer catenanes. Thus, a cyclic poly(tetrahydrofuran), poly(THF), having a hydrogen-bonding, isophthaloylbenzylic amide group (1) was prepared through in electrostatic self-assembly, and covalent fixation with a telechelic poly(THF) having N-phenylpyrrolidinium salt groups carrying a dicarboxylate counteranion containing the hydrogen-bonding unit (1). Another telechelic poly(THF) having,in isophthaloylbenzylic amide group at the center position and having N-phenylpyrrolidinium salt end groups carrying a biphenyldicarboxylate counteranion, 2, was subsequently prepared and subjected to a covalent conversion reaction in the presence of the preformed cyclic poly(THF) having a hydrogen-bonding unit (1). A polymer [2]catenane comprised of the two different cyclic poly(THF) components, I and II (from 2), has been isolated up to 7% yield as ail acetone-insoluble fraction and unequivocally characterized by means of MALDI TOF mass spectroscopy together with H-1 NMR and SEC techniques.
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