Article
Engineering, Mechanical
Yanquan Geng, Junshuai Jia, Zihan Li, Yu Liu, Jiqiang Wang, Yongda Yan, Yang Gan
Summary: The study introduced a nanomachining method using a dual-tip probe and single-crystal copper as the sample material, successfully machining symmetrical three-dimensional nanostructures. A depth prediction model accurately predicted the nanoscratching process, but inaccuracies were observed at smaller machined depths.
INTERNATIONAL JOURNAL OF MECHANICAL SCIENCES
(2021)
Article
Chemistry, Multidisciplinary
Mohamed A. Habila, Mohamed S. Moshab, Ahmed Mohamed El-Toni, Zeid A. ALOthman, Ahmed Y. Badjah Hadj Ahmed
Summary: Thermal treatment was used to convert palm stalk waste into magnetic carbon sheets, which showed excellent dye removal performance. The samples prepared at 250 degrees C and 400 degrees C exhibited the best adsorption capacity, with equilibrium reached within 120 to 180 minutes. The second-order kinetic model and Freundlich model were suitable for describing the adsorption process.
Article
Chemistry, Physical
Kyung Hwan Choi, Sooheon Cho, Byung Joo Jeong, Bom Lee, Jiho Jeon, Jinsu Kang, Xiaojie Zhang, Hyung-Suk Oh, Jae-Hyun Lee, Hak Ki Yu, Jae-Young Choi
Summary: For the first time, it has been experimentally demonstrated that bulk InSeI crystals can be delaminated into nanometer-scale nanowires through micromechanical exfoliation. The exfoliated InSeI nanowires exhibit a one-dimensional bundle structure and show thickness-dependent characteristics. InSeI holds promise as a candidate for optoelectronic applications, including photodetectors or photovoltaic devices.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
R. Hsissou, S. Abbout, F. Benhiba, R. Seghiri, Z. Safi, S. Kaya, S. Briche, G. Serdaroglu, H. Erramli, A. Elbachiri, A. Zarrouk, A. El Harfi
Summary: This study investigated the corrosion behavior of carbon steel in hydrochloric acid and sulfuric acid solutions in the presence of a newly synthesized macromolecular epoxy resin. The results showed that the compound significantly reduced the corrosion rate of carbon steel by forming a stable protective film on the metal surface, with corrosion efficiencies of about 95.5% in HCl and 98% in H2SO4. Langmuir isotherm model was the most suitable to describe the adsorption of the epoxy resin on the surface of carbon steel. Theoretical calculations supported the experimental results, confirming the epoxy resin as a highly effective inhibitor against carbon steel corrosion in acidic media.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Jessica M. Bone, Judith L. Jenkins
Summary: Conducting polymers are important materials in organic electronic platforms and wearable electronics. However, most chemistry students lack formal training in these materials. This study describes four learning modules designed to build fundamental understanding and practical skills in conducting polymers. Through completion of these modules, student researchers can learn how to interpret electrochemical and spectroscopic signals and extract key data from multiple complementary characterization techniques.
JOURNAL OF CHEMICAL EDUCATION
(2023)
Article
Spectroscopy
Kaifeng Zhang, Shin-ichi Taniguchi, Tomonori Saeki, Yifan Bao, Maofeng Cao, Masahiro Watanabe, Xiang Wang, Kei Kobayashi, Bin Ren, Hirofumi Yamada
Summary: Researchers propose a method for regenerating TERS tips by removing contaminants through an ultraviolet cleaning procedure, which can effectively remove the contaminants and promote the development of TERS technique.
JOURNAL OF RAMAN SPECTROSCOPY
(2022)
Article
Optics
R. Locht, D. Dehareng
Summary: The vacuum UV photoabsorption spectrum (PAS) of 1,1-Br2C2F2 has been measured using synchrotron radiation for the first time. Quantum chemical calculations were performed to determine excitation and ionization energies. Various transitions and vibrations were observed in the PAS between 5 eV and 15 eV. The Rydberg states and their convergence to the ground state were also analyzed. Strong sharp and broad bands above 11.5 eV were tentatively assigned to transitions to excited ionic states. (c) 2023 Elsevier Ltd. All rights reserved.
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
(2023)
Article
Chemistry, Applied
Changjiang Yu, Xing Guo, Xingbao Fang, Na Chen, Qinghua Wu, Erhong Hao, Lijuan Jiao
Summary: In this study, two isoindole-based fluorescent probes were synthesized with solvatochromic effects, large two-photon absorption cross-section, specificity, high photostability, and excellent performance in monitoring lipid droplet polarity changes in living cells. These probes exhibited high sensitivity between emission wavelength maxima and solvent polarity due to the existence of intramolecular charge transfer process. They also maintained high fluorescence quantum yields. The probes were successfully used for detecting lipid droplet polarity in living cells by confocal laser scanning fluorescence imaging. Importantly, the probes demonstrated photostability after degradation in a zebrafish model, making them suitable for long-term tracking and observation of biological dynamic changes.
Article
Chemistry, Multidisciplinary
Wei Miao, Xing Guo, Xi Yan, Yingjian Shang, Changjiang Yu, En Dai, Ting Jiang, Erhong Hao, Lijuan Jiao
Summary: In this study, a series of 3-pyrrolylBODIPY derivatives and 3,5-dipyrrolylBODIPY derivatives were synthesized by a simple regioselective nucleophilic aromatic substitution reaction. The introduction of a pyrrolic unit onto the 3-position of the BODIPY chromophore resulted in a significant red shift in both absorption and emission. Further functionalization at the 5-position fine-tuned their photophysical properties, and these derivatives exhibited strong absorption and intense near-infrared fluorescence emission. One of the derivatives, pyrrolylBODIPY 6 a, containing a mitochondrion-targeting cationic species, showed selective localization in mitochondria with low cytotoxicity and intense red fluorescence emission.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Applied
Fan Lv, Xing Guo, Zhong-Yuan Li, Qinghua Wu, Juanjie Chen, Changjiang Yu, Lijuan Jiao, Erhong Hao
Summary: A copper-catalyzed direct acylation of BODIPYs with aldehydes via C-H bond activation was developed, where acyl radicals were formed from aldehydes using TBHP as the radical initiator and selectively reacted with BODIPYs at the alpha-positions. This reaction showed excellent tolerance towards different functional groups, allowing for effective reaction between heteroaromatic and aliphatic aldehydes with BODIPYs. The alpha-acylated BODIPYs exhibited red-shifted absorption and emission, as well as decreased HOMO and LUMO energies compared to the starting BODIPYs due to the introduction of electron-deficient carbonyl groups. Moreover, removal of the BF2 protecting groups from the alpha-acylated BODIPY provided a efficient access to alpha-acylated dipyrrin, which showed sensitive and selective turn-on fluorescence response towards Zn2+ ion in aqueous buffer solution and living cells.
Article
Chemistry, Applied
Hua Wang, Xing Guo, Weibin Bu, Zhengxin Kang, Changjiang Yu, Qinghua Wu, Lijuan Jiao, Erhong Hao
Summary: A series of boronic acid derived salicylidenehydrazinopyridine complexes were synthesized and characterized. These complexes display a tetrahedral geometry due to the boron atoms and exhibit stereochemistry and molecular chirality. The curved nonplanar structure and axial-substituted groups of the complexes provide solubility and steric protection. The complexes also show strong absorption, weak emission, and large Stoke shifts, as well as aggregation-induced emission activities, making them potential bioimaging dyes.
Article
Chemistry, Multidisciplinary
Jun Wang, Huiquan Zuo, Qinghua Wu, Erhong Hao, Lijuan Jiao
Summary: In this study, two novel phenylenes bridged dimeric BOBPY were designed and synthesized. The resulting dyes showed high photostability, intense absorption and emission properties, and the electronic interactions were related to the length of the linker.
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
(2023)
Article
Chemistry, Organic
Zhaoyun Wang, Xing Guo, Zhengxin Kang, Qinghua Wu, Heng Li, Cheng Cheng, Changjiang Yu, Lijuan Jiao, Erhong Hao
Summary: An efficient procedure is developed for synthesizing aryl-boron-substituted BODIPY and aza-BODIPY derivatives through functional-nucleophiles in the presence of aluminum chloride. These derivatives exhibit bright emission in aqueous solution, with enhanced aggregation-induced emission and high solid-state emission due to restricted rotation and the formation of J-type aggregates.
Article
Spectroscopy
Wanle Sheng, Xing Guo, Bing Tang, Weibin Bu, Fan Zhang, Erhong Hao, Lijuan Jiao
Summary: The optical properties and aggregation-induced emission (AIE) activities of BODIPYs with TPA groups were studied systematically, and the dynamic behaviors of lipid droplets and lysosomes in living cells were successfully tracked through organelle-specific imaging.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Chemistry, Multidisciplinary
Zhengxin Kang, Long Wang, Zhongxin Li, Qinghua Wu, Ying Wei, Huiquan Zuo, Erhong Hao, Lijuan Jiao
Summary: The reaction of dipyrrolomethane and acetone in the presence of acid and oxidant yields a mixture of 5,15-calixphyrin and 5,10-calixphyrin. The 5,10-calixphyrin forms a Pd(II) complex when treated with Pd(OAc)(2) in acetonitrile and refluxed. The introduction of palladium metal to 5,10-calixphyrin has significant effects on its structure and properties, such as absorption bands and electron density.
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
(2023)
Article
Chemistry, Organic
Zhongxin Li, Lei Zhang, Wei Miao, Yingjian Shang, Long Wang, Changjiang Yu, Lijuan Jiao, Erhong Hao
Summary: Linear pi-conjugated oligopyrroles are attractive precursors for the synthesis of expanded porphyrinoids, chemosensors, and supramolecular motifs. A new method for the synthesis of a set of linear pyrrolyltripyrrins and dipyrrolyltripyrrins through a regioselective S(N)Ar reaction on alpha,alpha '-dibromotripyrrins using various pyrroles or indoles is demonstrated. A representative calixsmaragdyrin was prepared via the 2-fold SNAr reaction between alpha,alpha '-dibromotripyrrin and dipyrromethene through a convergent [3 + 2] strategy. These oligopyrroles showed intense deep red absorptions with an interesting pH response.
Article
Chemistry, Organic
Changjiang Yu, Yingzhu Sun, Lijuan Jiao, Erhong Hao
Summary: In recent years, several series of novel diboron compounds with tunable structures and outstanding spectroscopic properties have been developed as valuable fluorophores. This article mainly focuses on the synthetic strategies and superior properties of the fluorophores BOPHY, BOPPY, and BOAPY developed by our group. It also includes significant photophysical data of these fluorophores in solution and solid states. The facile functionalization of these fluorophores allows for practical structural modifications to generate versatile dyes with excellent chemical and photophysical properties. We believe that these fluorophores have the potential to make important contributions in a wide range of applications.
Review
Chemistry, Inorganic & Nuclear
Zhongxin Li, Qingbao Gong, Erhong Hao, Lijuan Jiao
Summary: In recent years, subporphyrazines and subporphyrins, fascinating ring-contracted porphyrinoids containing boron, have been developed as promising functional dyes due to their interesting structural, photophysical and electrochemical properties. This review provides an overview of their synthesis and summarizes the main structural modification methods, as well as discusses related analogues, dimers and oligomers, and stable subporphyrin radicals. Special attention is given to outstanding free base triphyrin(1.1.1) and free base subporphyrin, as well as hybrid subporphyrinoids.
COORDINATION CHEMISTRY REVIEWS
(2023)
Article
Chemistry, Applied
Xiangmin Wang, Xiaofan Fu, Weibin Bu, Changjian Yu, Erhong Hao, Lijuan Jiao, Qinghua Wu, Rentian Wang, Jinjun Wang, Jiazhu Li
Summary: Fusion of thiophene to BODIPY allows for the development of novel symmetric bisbenzothieno[b]-fused BODIPYs (BTBs) with absorption maxima in the range of 643-665 nm, large molar extinction coefficients, and high singlet oxygen generation. Theoretical calculations show that the smaller singlet-triplet energy gap and larger spin-orbit coupling contribute to efficient intersystem crossing and increased singlet oxygen generation yield. Interestingly, a methyl diphenyl substituted BTB exhibits good reactive oxygen species generation efficiency (0.41) and remarkable photo-cytotoxicity (IC50 = 83.5 nM) in HeLa cells, demonstrating its potential in low-dose photodynamic therapy.
Article
Chemistry, Organic
Long Wang, Qinghua Wu, Zhengxin Kang, Xing Guo, Wei Miao, Zhongxin Li, Huiquan Zuo, Hua Wang, Hongwei Si, Lijuan Jiao, Erhong Hao
Summary: A family of directly β,β-linked BODIPY dimers with amino groups at α-positions were selectively prepared by oxidative coupling reaction of α-amino-substituted BODIPYs. The structure of one representative dimer was elucidated by X-ray diffraction analysis, showing a twisted orientation of two BODIPY units with a dihedral angle of 49°. Compared with the corresponding monomers, these dimers exhibited red-shifted absorptions and emissions along with efficient intersystem crossing, with a quantum yield Φ(Δ) of 43% for dimer 4b in toluene, indicating their potential use as heavy-atom-free photosensitizers.
Article
Chemistry, Multidisciplinary
Haia Kharraz, Hadi Hachem, Yann Le Gal, Thierry Roisnel, Olivier Jeannin, Frederic Barriere, Thierry Guizouarn, Dominique Lorcy
Summary: Tetrathiafulvalenes (TTFs) were functionalized with groups that enhance non-covalent intermolecular interactions. The study involved designing appropriate precursors and assessing the electronic effect of the substituents on the overall donating ability of the TTFs. Charge transfer salts were prepared and their crystal structures were analyzed to understand the stacking mode and non-covalent interactions in the solid state.
Article
Chemistry, Multidisciplinary
Fan Lv, Heng Li, Qinghua Wu, Xing Guo, Hongtao Zhang, Changjiang Yu, Lijuan Jiao, Erhong Hao
Summary: A simplified method using an Ag-mediated radical addition was developed to achieve the selective coupling of dialkyl phosphites and diphenylphosphine oxide with BODIPY compounds. The newly synthesized alpha-phosphorylated BODIPY fluorophores exhibited high solubility and fluorescence in water with a quantum yield of 0.83.
CHEMICAL COMMUNICATIONS
(2022)