期刊
MACROMOLECULES
卷 41, 期 23, 页码 9030-9034出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma8013178
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- Henkel KGaA
Polymerization behavior of N-phenylbenzoxazine in bulk was studies in detail to discover new reaction pathways: (1) formation of an intermediary polymer having N,O-acetal-type linkage in the main chain and (2) its rearrangement into Mannich-type linkage in the solid state. Efficient promotion of the main chain rearrangement was achieved by using a dual system composed of imidazole and sulfonic acid.
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