4.7 Article

Synthesis of methyl-substituted main-chain-type organoboron quinolate, polymers and their emission color tuning

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MACROMOLECULES
卷 41, 期 8, 页码 2809-2813

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AMER CHEMICAL SOC
DOI: 10.1021/ma7025918

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Highly fluorescent main-chain-type organoboron quinolate polymers were prepared by means of Sonogashira-Hagihara coupling reaction between diyne monomers and methyl-substituted diiodo-organoboron quinolates. By combining methyl substitution of quinolinol ligands and incorporation of organoboron quinolate into polymer main chain, more efficiently luminescent materials with blue-shifted emission were successfully synthesized.

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