Article
Chemistry, Physical
Alessandro Ianiro, Jose Augusto Berrocal, Remco Tuinier, Michael Mayer, Christoph Weder
Summary: This paper presents a theoretical investigation on a new actuator design using anisotropic colloidal particles grafted with stimuli-responsive polymer chains. These artificial muscles combine the osmotic actuation principle of hydrogels with the structural alignment of colloidal liquid crystals for directional motion. The study identifies the solubility, degree of polymerization, salt concentration, and grafting density of the polymer chains as important factors for actuator performance and tunability. Computational results suggest that the proposed material matches or exceeds the performances of natural muscles, providing guidelines for the realization of artificial muscles with predefined actuation properties.
JOURNAL OF CHEMICAL PHYSICS
(2023)
Article
Polymer Science
Alina Silvia Chiper, Gabriela Borcia
Summary: This study compares the effects of plasma on polymers exposed to helium and argon gaseous environments in a pulsed dielectric barrier discharge at atmospheric pressure. The results show that plasma treatment can efficiently and remarkably modify the surface properties of polymers, especially cellulose-based materials.
Article
Chemistry, Applied
Shima Tavakoli, Mahshid Kharaziha, Shervin Nemati, Ali Kalateh
Summary: The study developed a novel Kappa carrageenan-coated Starch/cellulose nanofiber hydrogel with enhanced mechanical properties and adjustable biological performance, showing great potential for hemostatic applications.
CARBOHYDRATE POLYMERS
(2021)
Article
Materials Science, Textiles
Nazife Korkmaz Memis, Sibel Kaplan
Summary: This study developed a novel nanocomposite treatment method by applying temperature responsive shape memory polyurethane and cellulose nanowhiskers to polyester fabric, creating a smart fabric with dual responsive performance to moisture and temperature. The treated fabrics exhibited dynamic breathability and sweat absorption, and the mechanical and end use performances of polyester were also enhanced.
JOURNAL OF INDUSTRIAL TEXTILES
(2022)
Article
Chemistry, Physical
Marina Voronova, Darya L. Gurina, Oleg Surov, Anatoly G. Zakharov
Summary: In this study, physical adsorption of polyvinylpyrrolidone (PVP) was used to modify cellulose nanocrystals (CNCs), with a focus on the effect of PVP molecular weight on dispersion in dichloromethane (DCM). Through molecular dynamics simulation, it was found that PCL macromolecules have minimal direct contacts with the CNC surface but are located between PVP macromolecules, which are predominantly situated near the CNC particle surface.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Review
Materials Science, Paper & Wood
Sandra Rodriguez-Fabia, Jonathan Torstensen, Lars Johansson, Kristin Syverud
Summary: This review provides an overview of the hydrophobization of lignocellulosic materials by polymer adsorption and grafting. Radiation-induced grafting is the most environmentally friendly technique, while controlled radical polymerization allows for the synthesis of polymers with complex structures. The choice of modification technique depends on the end-use of the material.
Article
Materials Science, Paper & Wood
Dongwan Son, Seungjun Kim, Jinhyeong Kim, Doyeon Kim, Sujin Ryu, Youngbok Lee, Myungwoong Kim, Hoik Lee
Summary: In this study, a cellulose-based nanofiber membrane with exceptional hydrophilicity and oleophobicity is reported, which allows the penetration of water and rejects organic solvents, avoiding fouling by organic residues. The membrane is fabricated through electrospinning of cellulose acetate and subsequent deacetylation, followed by binding with a zwitterionic copolymer. The resulting membrane exhibits highly selective penetration of the water phase from various oil/water mixtures, with high filtration efficiency and reusability.
Article
Polymer Science
Maryam Mosayebi, Gity Mir Mohamad Sadeghi, Roghieh Jamjah
Summary: The research shows that the shear strength of waterborne polyurethane bio-nanocomposite adhesives can be improved by controlling the oxypropylation degree and nanocrystalline content. WPU2-0.50 wt% exhibits the highest strength among all substrates, with shear strength values of 12.8 and 15.1 MPa for wood-wood substrates.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Review
Chemistry, Multidisciplinary
Xianpeng Yang, Subir Kumar Biswas, Jingquan Han, Supachok Tanpichai, Mei-Chun Li, Chuchu Chen, Sailing Zhu, Atanu Kumar Das, Hiroyuki Yano
Summary: The article focuses on the importance of nanocelluloses in material engineering and the methods of their preparation, as well as the significance of surface and interface engineering in the process of nanocellulose fabrication.
ADVANCED MATERIALS
(2021)
Article
Polymer Science
Ayesha Kausar
Summary: Fullerene nanowhisker, a unique nanomaterial formed by aligned fullerene molecule aggregation, can be used as a polymer reinforcement material with excellent properties.
POLYMER-PLASTICS TECHNOLOGY AND MATERIALS
(2022)
Article
Chemistry, Applied
Elham Neisi, Abbas Dadkhah Tehrani, Hamid Reza Shamlouei
Summary: Supramolecular hydrogels have attracted significant attention due to their versatile approaches for preparation and new facile characterization strategies. In this study, we successfully formed a biocompatible and low-cost supramolecular hydrogel by binding modified cellulose nanowhiskers with gallic acid pendant groups (CNW-GA) with CNW grafted with beta-Cyclodextrin (CNW-g-beta-CD) through HG interaction. We also developed a simple colorimetric characterization method using phenolphthalein (PP) as a visual indicator for confirming HG complexation.
CARBOHYDRATE POLYMERS
(2023)
Article
Materials Science, Paper & Wood
Ezgi M. Dogan-Guner, Gregory T. Schueneman, Meisha L. Shofner, J. Carson Meredith
Summary: Cellulose nanocrystals (CNCs) were modified with isocyanoethyl methacrylate (IEM) to optimize their surface properties, achieving high surface hydroxyl conversion and crystallinity through controlled reaction conditions. The copolymerization of modified CNCs with acrylic monomers enhanced the dispersion and mechanical properties in an acrylic polymer matrix, showing significant improvements in tensile strength and hardness compared to unmodified CNCs.
Article
Chemistry, Multidisciplinary
Mohammed Majdoub, Younes Essamlali, Abdallah Amedlous, Abdelouahed El Gharrak, Mohamed Zahouily
Summary: In this study, new nanocomposite porous membranes based on castor oil-derived polyurethane (PUBCO) and octadecylamine-functionalized cellulose nanocrystals (CNC-ODA) were developed. The nanocomposites exhibited improved thermal stabilities and mechanical properties, showing a change in the nature of the material towards an elastomeric one. The contact angle measurements also indicated a highly hydrophobic nanocomposite.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Polymer Science
Yinglan Zhang, Michael Thomas Mueller, Regine Boldt, Markus Stommel
Summary: In this study, high crystallinity polylactides (PLAs) were irradiated with electron beam to investigate the effects on radical decay and molecular structure transformation. It was found that high crystallinity can inhibit radical reactions and restrict the formation of crosslinking and long-chain branching.
Article
Biochemistry & Molecular Biology
Tunsuda Suparanon, Neeranuch Phusunti, Worasak Phetwarotai
Summary: Plastic garbage is a major environmental issue that affects humans, animals, and their surroundings. The use of biodegradable polymers as substitutes for traditional plastics is an effective solution to address this problem. This study focuses on the chemical modification of microcrystalline cellulose derived from oil palm empty fruit bunch waste and its application as a bio-filler in polylactide composites. The addition of tricresyl phosphate as a plasticizer and flame retardant enhances the toughness and flame inhibition of the composites. The findings suggest that this approach can effectively improve the properties of PLA composites.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)