期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 215, 期 22, 页码 2161-2174出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201400373
关键词
ionic; phase separation; polyurethanes; segmented; waterborne polyurethane dispersions
资金
- U.S. Army Research Laboratory [W911NF-06-2-0014]
- U.S. Army Research Office [W911NF-06-2-0014]
- Bayer MaterialScience
Despite the well-established foundation of polyurethane chemistry in both industry and academia, research continues at a vigorous pace to refine synthetic processes and discover new functional materials. Incorporating ionic groups into polymers is a synthetic parameter capable of tailoring polymer properties and enabling emerging technologies. This review focuses on recent effort in the field of ion-containing segmented polyurethane copolymers. Multiple synthetic strategies to incorporate both cationic and anionic sites, including a particular focus on waterborne polyurethane dispersions and green synthetic methods, are examined. Fundamental structure-property relationships based on ionic structure, content, and placement are explored and many applications, including biomedical products and polymer electrolytes for energy devices are discussed.
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