期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 213, 期 12, 页码 1259-1265出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201200103
关键词
carbon nanotubes; ionic liquid; poly(butyl acrylate); polystyrene; supramolecular structures
资金
- Research Foundation Flanders (FWO)
- EU
- Interreg IV (project Plasmobio'')
- Belgian Federal Science Policy Office [PAI 6/27]
- FNRS-FRFC
Imidazolium end-functionalized poly(butyl acrylate) and polystyrene (co)polymers (Im-PnBuA, Im-PSty, and Im-PnBuA-b-PSty are synthesized via ATRP. The controlled character of the polymerization reactions is highlighted by SEC and MALDI-TOF MS analyses. Subsequently, the polymers are tested as dispersing/compatibilizing agents for CNTs in polymer matrices. When CNTs are challenged with a mixture of Im-PnBuA and Im-PSty, the CNTs are mainly located in the PnBuA phase. In contrast, the Im-PnBuA-b-PSty block copolymer enables CNT confinement in the PSty phase. By selecting the proper ?-imidazolium polymer, it is possible to direct the CNT confinement toward a specific polymer phase within polymer mixtures.
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