4.7 Article

Preparation of silica aerogels using CTAB/SDS as template and their efficient adsorption

期刊

APPLIED SURFACE SCIENCE
卷 353, 期 -, 页码 1031-1036

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ELSEVIER
DOI: 10.1016/j.apsusc.2015.06.204

关键词

Silica aerogels; Sol-gel preparation; Binary cationic nonionic surfactants; Adsorbent

资金

  1. National Program on Key Basic Research Project (973 Program) [2013CB932800]
  2. Ministry of Education of P.R. China [50934003, FRF-MP-09005B]

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Silica aerogels have been successfully synthesized using cationic cetyltrimethylammonium bromide (CTAB) and anionic sodium dodecyl sulfate (SDS) as template. This study provides a novel approach to synthesize silica aerogels. The molar ratio of surfactant mixture was CTAB/SDS = 1.00. The obtained silica aerogels exhibit very low apparent density (0.044 g cm(-3)) and high specific surface area (856 m(2) g(-1)). Surfactant packing parameter theory is used to explain the possible formation mechanism of the silica aerogels using mixed surfactant template. In addition, the adsorption capacity of Rhodamine B on the as-synthesized silica aerogels is as higher as that on the commercial silica aerogels. (C) 2015 Elsevier B.V. All rights reserved.

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