Article
Chemistry, Applied
Fernando G. Buendia, Daniel Araiza, Luis Lopez-Rodriguez, Lauro Oliver Paz-Borbon, Gabriela Diaz
Summary: This study presents a combined theoretical and experimental analysis of the preferred adsorption sites for methanol and methoxy species over Cu, Pt, and bimetallic Cu-Pt clusters supported on CeO2(111). The results show that methanol adsorption is slightly favored over the CuPt/CeO2(111) system compared to the pristine surface, and methoxy species preferentially adsorb over the metallic clusters. In-situ DRIFTS experiments confirm the adsorption of methanol and methoxy species on Cu, Pt, and bimetallic Cu-Pt nanoparticles supported on CeO2 octahedra.
Article
Chemistry, Physical
Tianyu Liu, Ruijie Yang, Guomeng Zhang, Weihong Wu, Zhengda Yang, Riyi Lin, Xinwei Wang, Ye Jiang
Summary: The reaction mechanism over CeO2-TiO2 catalyst involves both E-R and L-H mechanisms, with NH2NO species playing a key role as an intermediate. DFT calculations provide insights into the adsorption energy, activation energy barrier, and reaction heat for various steps in the process.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Ayesha A. Alkhoori, Omer Elmutasim, Aasif A. Dabbawala, Michalis A. Vasiliades, Klito C. Petallidou, Abdul-Hamid Emwas, Dalaver H. Anjum, Nirpendra Singh, Mark A. Baker, Nikolaos D. Charisiou, Maria A. Goula, Angelos M. Efstathiou, Kyriaki Polychronopoulou
Summary: In this study, the Ni/CeO2/Al2O3 catalyst system was investigated to understand how different synthesis parameters affect interfacial phenomena and CO2 methanation. Key factors such as alumina texture, ceria loading, and synthesis method of supported Ni were examined to determine their influence on catalyst activity and CH4 selectivity. Among the studied catalysts, Ni-20Ce/mpAl showed promising results with high CO2 conversion rate (70%) and CH4 selectivity (>94%) at 350°C. The researchers found that medium- and high-porosity alumina facilitated better dispersion of ceria, while Ni-CeO2 cogrowth resulted in small Ni crystallites that increased in size over the course of the reaction. This catalyst exhibited advantageous features for CO2 methanation, including a high concentration of oxygen vacancies, significant presence of surface Ce3+ species, and strong CO activation capability.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Engineering, Environmental
Huilin Li, Qiang Guo, Yongli Li, Mingbo Fu, Dengchao Tian, Tao Qi
Summary: Efficient, stable, and inexpensive photocatalysts were obtained by synthesizing CeO2@ expanded graphite composites. The composites showed high pollutant removal efficiency, reaction rate, stability, and suitability for water pollution treatment.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Environmental
Jiayou Liu, Xiaoxiang Huang, Linfeng Liu, Qianqian Nie, Zhongchao Tan, Hesheng Yu
Summary: This paper reports the mechanism behind NO removal using UiO-66-NH2, which includes photocatalytic oxidation and subsequent adsorption. The NO reaction pathway and degradation mechanisms are proposed based on experimental results and theoretical calculations. It is found that UiO-66-NH2 has high NO removal efficiency and performs better in an anhydrous environment.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Nanoscience & Nanotechnology
Tianyu Li, Roman Tsyshevsky, Lucas Algrim, Monica McEntee, Erin M. Durke, Bryan Eichhorn, Christopher Karwacki, Michael R. Zachariah, Maija M. Kuklja, Efrain E. Rodriguez
Summary: This study investigates the interaction of DMMP on CeO2 surfaces, revealing that DMMP can dissociate on CeO2 at room temperature based on mass spectroscopy and infrared testing. Two dissociation pathways for DMMP on CeO2 surfaces are identified, with the (111) surface having the lowest activation energy barrier.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Younes Dehmani, Hassane Lgaz, Awad A. Alrashdi, Taibi Lamhasni, Sadik Abouarnadasse, Ill-Min Chung
Summary: A porous zinc oxide (ZnO) was synthesized and used as an adsorbent for phenol removal. Experimental and simulation studies provided insights into the adsorption mechanism, with optimum removal observed at pH=4 and adsorption capacities of 3.61 and 4.51mg/g at 30 degrees and 50 degrees, respectively. The study confirmed the predominance of chemisorption and increased interaction with phenol in the presence of solvent.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Adil Lammini, Ali Dehbi, Hind Omari, Kaoutar ELazhari, Smahane Mehanned, Youssera Bengamra, Younes Dehmani, Oukhrib Rachid, Awad A. Alrashdi, Obey Gotore, Abdelaziz Abdellaoui, Hassane Lgaz
Summary: Water pollution caused by phenolic composites is a significant environmental problem, and the use of synthesized cobalt oxide as an adsorbent can effectively remove phenol. A combination of calculations and simulations was used to study the interaction mechanism between phenol molecules and cobalt oxide surface. Experimental characterization results showed that the adsorption capacity was optimal at pH 4.
ARABIAN JOURNAL OF CHEMISTRY
(2022)
Article
Energy & Fuels
Luyuan Wang, Chengbo Xuan, Xingyu Zhang, Rongfeng Sun, Xingxing Cheng, Zhiqiang Wang, Chunyuan Ma
Summary: A series of coal-based materials were prepared using a hydrothermal method combined with high-temperature CO2 activation. The surface functional groups and pore structure of the materials were optimized through K modification. The investigation found that optimizing the pore structure, functional groups, and surface metal can enhance the NOx adsorption capacity on the surface of the coal-based materials. Oxygen-containing active functional groups with moderately high C-O and R2C=O contents also contribute to the adsorption of NO. This study is significant for NOx adsorption removal technology.
Article
Chemistry, Physical
Supakit Tiewcharoen, Thana Maihom, Jarinya Sittiwong, Jumras Limtrakul
Summary: This study investigated the effects of cation exchange and tetravalent metal substitution in Lewis acidic BEA zeolites on phenol adsorption and tautomerization reactions. It was found that the strongest adsorption interaction occurred when phenol chemisorbed to Li-Sn-BEA due to high charge transfers. The catalytic activity for phenol tautomerization on Sn-BEA can be improved with cation exchange, and the catalytic activity ranking of tetravalent metal centers in BEA was determined to be Zr≈Hf > Sn > Ti.
CHEMICAL PHYSICS LETTERS
(2021)
Article
Nanoscience & Nanotechnology
Kyriaki Polychronopoulou, Ayesha A. AlKhoori, Angelos M. Efstathiou, Maguy Abi Jaoude, C. M. Damaskinos, Mark A. Baker, Alia Almutawa, Dalaver H. Anjum, Michalis A. Vasiliades, Abderrezak Belabbes, Lourdes F. Vega, Abdallah Fathy Zedan, Steven J. Hinder
Summary: Eliminating CO through oxidation over highly active and cost-effective catalysts is important for industrial and environmental processes. Doped CeO2 with transition metals was tested for CO oxidation, showing that Cu-Ce-O catalyst has the highest activity. The involvement of lattice oxygen species in the reaction and the effectiveness of different heteroatoms were investigated and quantified.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Kyriaki Polychronopoulou, Sara AlKhoori, Shaima AlBedwawi, Seba Alareeqi, Aseel G. S. Hussien, Michalis A. Vasiliades, Angelos M. Efstathiou, Klito C. Petallidou, Nirpendra Singh, Dalaver H. Anjum, Lourdes F. Vega, Mark A. Baker
Summary: In this study, the CO2 activation behavior of doped ceria-based metal oxides and the influence of chemical and mechanical strain were investigated using experimental and ab initio modeling approaches. The results showed that mechanical strain increased the CO2 adsorption sites but reduced their thermal stability. Ab initio calculations revealed that doping and tensile strain could enhance CO2 adsorption. Additionally, ball milling of the oxides improved the reducibility of the catalysts and increased the conversion of CH4 and CO2 in a catalytic reaction.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Paul K. Huttunen, Daniela Labadini, Sabrina S. Hafiz, Sumeyra Gokalp, Erich P. Wolff, Sara M. Martell, Michelle Foster
Summary: The mechanism of methanol oxidation on heat treated CeO2 nanoparticles was studied using DRIFTS. The study showed that formate production depends on the presence and transformation of b-methoxy groups, with hydroxyls facilitating the formation of surface methoxy groups and the transformation into bidentate formate groups. The reaction mechanism was elucidated by temperature dependent peak height analysis of the collected DRIFTS spectra.
APPLIED SURFACE SCIENCE
(2021)
Article
Engineering, Environmental
Shengpeng Mo, Jun Li, Riquan Liao, Peng Peng, Jingjing Li, Junliang Wu, Mingli Fu, Lei Liao, Taiming Shen, Qinglin Xie, Daiqi Ye
Summary: Oxygen vacancy engineering plays a vital role in efficient degradation of volatile organic compounds in nanomaterials. The Pt-0.15Ce-Mn catalyst demonstrates superior catalytic activity for toluene oxidation due to more oxygen vacancies, excellent redox ability, and well dispersion of Pt. Introduction of CeO2 NPs induces the generation of more oxygen vacancies and new structure defects, leading to lower formation energy of oxygen vacancy and boosting remarkable catalytic activity for deep toluene oxidation through a synergistic effect of dual oxygen vacancies.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Environmental Sciences
Dengfeng Yan, Tan Li, Peng Liu, Shengpeng Mo, Jinping Zhong, Quanming Ren, Yuhai Sun, Hairong Cheng, Mingli Fu, Junliang Wu, Peirong Chen, Haomin Huang, Daiqi Ye
Summary: In this work, spindle-like CeO2 supports with different contents of oxygen vacancies were prepared by in-situ thermal pyrolysis. The Pt-CeO2 interaction was regulated by the unique physicochemical properties of the modified CeO2 supports. The strong Pt-O-Ce bond on the PCH catalysts enhanced catalytic performance for toluene oxidation and CO tolerance.
Article
Chemistry, Physical
Carla G. Marcoccia, Miguel A. Peluso, Jorge E. Sambeth
MOLECULAR CATALYSIS
(2020)
Article
Environmental Sciences
Cynthia A. Fuentes, Maria V. Gallegos, Juan R. Garcia, Jorge Sambeth, Miguel A. Peluso
WASTE AND BIOMASS VALORIZATION
(2020)
Article
Chemistry, Physical
V Orazi, A. Juan, E. A. Gonzalez, Jorge M. Marchetti, P. Jasen
APPLIED SURFACE SCIENCE
(2020)
Article
Chemistry, Physical
Agustin Salcedo, Beatriz Irigoyen
JOURNAL OF PHYSICAL CHEMISTRY C
(2020)
Article
Chemistry, Applied
Oriana D'Alessandro, Christian Eduardo Byrne, Gonzalo Selmi, Cecilia Deya
Summary: The experimental results on the new anticorrosive alkyd paint formulated with natural zeolitic rock show promising anticorrosive properties with low environmental impact, suitable for use in low corrosive environments. The use of zeolites as anticorrosive pigments in paints shows potential for further research and application in the coatings industry.
PIGMENT & RESIN TECHNOLOGY
(2021)
Article
Chemistry, Physical
Pablo G. Lustemberg, Zhongtian Mao, Agustin Salcedo, Beatriz Irigoyen, M. Veronica Ganduglia-Pirovano, Charles T. Campbell
Summary: Research has shown that cationic Ni atoms in clusters at step edges on the CeO2(111) surface are the most active sites for methane conversion reactions, with their small size and high Ni chemical potential contributing to their activity. Density functional theory calculations have clarified the reasons behind this observation, highlighting the importance of the size and morphology of supported Ni nanoparticles, strong Ni-support bonding, and charge transfer at step edges for high catalytic activity, particularly in the activation barrier for C-H bond cleavage during CH4 dissociative adsorption. This knowledge is expected to inspire the development of more efficient catalysts for these reactions.
Article
Chemistry, Physical
Agustin Salcedo, Pablo G. Lustemberg, Ning Rui, Robert M. Palomino, Zongyuan Liu, Slavomir Nemsak, Sanjaya D. Senanayake, Jose A. Rodriguez, M. Veronica Ganduglia-Pirovano, Beatriz Irigoyen
Summary: Ni/CeO2 catalysts show high activity for methane steam reforming at relatively low temperatures, effectively preventing coke formation, with hydroxyl-assisted CO formation providing a low-barrier pathway to prevent carbon accumulation.
Article
Materials Science, Multidisciplinary
Christian E. Byrne, Oriana D'Alessandro, Cecilia Deya
Summary: The study demonstrates that tara tannins can effectively inhibit aluminum corrosion and form a compact barrier on the aluminum surface. Its anticorrosive properties have been confirmed through electrochemical techniques and humidity chamber testing, making it an environmentally friendly alternative to chromates.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2022)
Article
Materials Science, Multidisciplinary
Christian Byrne, Oriana D'Alessandro, Cecilia Deya
Summary: The addition of tara and quebracho colorado tannins significantly reduces the corrosion rate of aluminum in near-neutral and naturally aerated NaCl solutions. The tannins act as a mixed-type corrosion inhibitor and form a more homogenous and compact layer on the aluminum surface, preventing the adsorption of chlorinated compounds. The experimental results demonstrate the improved corrosion resistance of aluminum in the presence of tannins.
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
(2022)
Article
Materials Science, Multidisciplinary
Christian Byrne, Martin Ramirez, Ezequiel Di Santo, Nicol Cristiano, Cecilia Deya, Oriana D'Alessandro
Summary: The study involved obtaining, characterizing and evaluating the anticorrosive performance of aqueous extracts from perennial plants Rosmarinus officinalis, Laurus nobilis, and Plectranthus coleoides on SAE 1010 steel. The extracts exhibited corrosion inhibition comparable to a commercial pigment, with Plectranthus coleoides showing the best performance.
MATERIA-RIO DE JANEIRO
(2021)
Article
Chemistry, Physical
Carla Romina Luna, Walter Guillermo Reimers, Marcelo Javier Avena, Alfredo Juan
Summary: Through DFT calculations, the study investigated the geometric and electronic properties of delaminated pyrophyllite and layers resulting from various isomorphic substitutions. The results suggest that the layer thickness and band gap decrease with certain substitutions, and the work function decreases as well. Additionally, the presence of certain substituents leads to paramagnetic behavior in the materials.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Chemistry, Physical
Agustin Salcedo, Beatriz Irigoyen
Summary: The water-gas shift reaction is crucial for hydrogen production, especially for meeting the high-purity H2 requirement of PEM fuel cells. Current catalysts in large-scale WGS plants require a two-step process, while Ni-Cu/CeO2 solids show promise for a one-step process in small-scale applications. By studying Ni4-xCux/CeO2(111) systems, it was found that the presence of Cu strengthens the C-O bond and increases the CO dissociation energy, leading to improved selectivity towards WGS.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Chemistry, Applied
C. Byrne, G. J. Selmi, O. D'Alessandro, C. Deya
PROGRESS IN ORGANIC COATINGS
(2020)
Article
Chemistry, Multidisciplinary
Mehdi Yoosefian, Nazanin Etminan, Alfredo Juan, Elnaz Mirhaji
Article
Chemistry, Multidisciplinary
E. Noseda Grau, G. Roman, A. Diaz Company, G. Brizuela, A. Juan, S. Simonetti
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)