Article
Construction & Building Technology
Long Li, Dongxing Xuan, Adebayo Olatunbsoun Sojobi, Songhui Liu, S. H. Chu, Chi Sun Poon
Summary: This study investigated the pre-treatment of recycled aggregates with three nano-silica methods, finding that pre-spraying without air-drying was the most effective in enhancing the mechanical properties and durability of recycled aggregate concrete.
CEMENT & CONCRETE COMPOSITES
(2021)
Review
Chemistry, Physical
Xiaozhen Ma, Ngoc N. Nguyen, Anh V. Nguyen
Summary: This paper provides a critical review of the experimental and theoretical investigations of the particle floatability and stability of the particle-laden interfaces. The study analyzed asymptotic solutions of the Young-Laplace equation for various particle configurations and assessed the outcomes of both theoretical and experimental studies of the particle-laden interface stability.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Shuxin You, Shilong Xing, Chuanhai Jiang
Summary: This study investigates the influence of various-sized CeO2 particles on the microstructure and properties of electrodeposited Ni-CeO2 composite coatings. Compared to microparticles, nanoparticles show better performance in optimizing the surface topography, achieving a homogeneous coating surface, and suppressing texture. Nano coatings possess a more random surface grain orientation, a higher level of grain refinement, and numerous low angle grain boundaries, contributing to the enhancement of the coatings' performance.
MATERIALS CHARACTERIZATION
(2023)
Article
Mechanics
Li Sun, Tianqi Liang, Chunwei Zhang, Jianyun Chen
Summary: This study investigates the compounded shear-thickening fluids (STFs) consisting of needlelike carbon fiber powder (CFP), silicon dioxide (SiO2), and polyethylene glycol (PEG). The compounded STFs exhibit significant rheological behavior and shear-thickening effects, and show excellent energy dissipation capacity and dynamic stability. The key performance index of the compounded STFs is demonstrated to be improved by ten times or even higher, making it a novel type of STFs for engineering practice.
Article
Geosciences, Multidisciplinary
T. Petaja, K. Tabakova, A. Manninen, E. Ezhova, E. O'Connor, D. Moisseev, V. A. Sinclair, J. Backman, J. Levula, K. Luoma, A. Virkkula, M. Paramonov, M. Raty, M. Aijala, L. Heikkinen, M. Ehn, M. Sipila, T. Yli-Juuti, A. Virtanen, M. Ritsche, N. Hickmon, G. Pulik, D. Rosenfeld, D. R. Worsnop, J. Back, M. Kulmala, V. -M. Kerminen
Summary: Research shows that aerosol emissions from the boreal forest biosphere have a significant impact on warm cloud microphysics and cloud-aerosol interactions, potentially mitigating climate change on a continental scale.
Article
Acoustics
Haoran Chu, Lanlan Chen, Dongfang Lu, Yuhua Wang, Xiayu Zheng
Summary: The study verified the potential of ultrasonic pretreatment in improving the floatability of spodumene with different size fractions. It was found that ultrasonic pretreatment significantly enhanced the floatability of coarse particles, but had no clear advantage over traditional methods for fine particles.
ULTRASONICS SONOCHEMISTRY
(2022)
Review
Engineering, Chemical
Vancha Harish, M. M. Ansari, Devesh Tewari, Awadh Bihari Yadav, Neelesh Sharma, Sweta Bawarig, Maria-Luisa Garcia-Betancourt, Ali Karatutlu, Mikhael Bechelany, Ahmed Barhoum
Summary: This comprehensive review explores the cutting-edge advancements in tailoring the size, shape, and functionality of nanoparticles and nanostructures. It covers a wide array of advanced mechanical, physical, chemical, and biological approaches utilized in their production. The review encompasses an extensive range of synthesis methods, including mechanical milling, high-pressure homogenization, physical vapor deposition, and many others.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Engineering, Ocean
Hai-lei Kou, Wen-zhou Diao, Wang-chun Zhang, Jing-bin Zheng, Pengpeng Ni, Bo-An Jang, Chuangzhou Wu
Summary: The study investigated the effects of surface roughness and particle size on the shear behavior of steel pipe piles supporting marine structures. Results show that the surface roughness of steel plate significantly influences the shear behavior between sand and steel, with the interface friction angle increasing with surface roughness.
APPLIED OCEAN RESEARCH
(2021)
Review
Green & Sustainable Science & Technology
Dhanasingh Sivalinga Vijayan, Parthiban Devarajan, Arvindan Sivasuriyan
Summary: In recent years, the revolution of nanotechnology has had a significant impact on various scientific disciplines. The effective utilization of nanotechnology in the construction industry has become a prominent topic, particularly in terms of sustainability. Nanoparticles possess exceptional physical and chemical properties that can enhance the strength, durability, and rheology of concrete, while also mitigating environmental pollution. This paper reviews the literature on nanotechnology applications in construction, focusing on nanoparticles such as silica fume and nano silica, which have proven to be effective in improving concrete properties.
SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS
(2023)
Article
Biochemistry & Molecular Biology
Ki Ha Min, Jin Woo Shin, Mi-Ran Ki, Sung Ho Kim, Kyung Hee Kim, Seung Pil Pack
Summary: Researchers have discovered three new peptides that can mediate biosilica formation, with one showing superior performance at pH 6. They investigated the optimal amount and reaction time of this peptide for biosilica particle formation at pH 6-7. Additionally, they demonstrated that this peptide adsorbed on Escherichia coli cell surfaces can induce the formation of silica shell coating, providing stability against harsh UV treatment.
PROCESS BIOCHEMISTRY
(2021)
Article
Chemistry, Applied
Yao Lu, Yanhui Zhang, Fang Yuan, Yanxiang Gao, Like Mao
Summary: Emulsion gels were prepared using different proteins as emulsifiers and denatured WPI as gelling agent. The study found that gels with WPI at the interface showed the highest gel strength and water holding capacity, while gels with LF at the interface had the highest swelling rate. These findings provide valuable information for designing emulsion gel structures for better delivery of bioactive compounds.
FOOD HYDROCOLLOIDS
(2021)
Article
Chemistry, Physical
Chuanyu Yan, Enzo Moretto, Oussema Kachouri, Jean-Luc Biagi, Jean-Sebastien Thomann, Francois Kayser, Reiner Dieden
Summary: This study demonstrates the use of solid-state nuclear magnetic resonance spectroscopy for studying dehydration and deuterium exchange at the liquid-solid interface. The results provide evidence of complete removal of physically adsorbed water molecules on the silica surface in the presence of DMSO, and satisfactory deuteration of silanol groups in the presence of a DMSO-D2O mixture. Additionally, the study develops a liquid-state NMR-based technique for quantifying moisture and hydroxyls on solids.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Biochemistry & Molecular Biology
Tetsuo Yamaguchi, Taeho Kim, Jin-Kuen Park, Jae-Min Oh
Summary: The release of ferulic acid from surface-functionalized hollow nanoporous silica particles (HNSPs) was studied. HNSPs were synthesized in the presence of polymer and surfactant templates, and the pores and surfaces were modified through silane coupling reactions. The release rates in DI water and ethanol were highest for HNSP, followed by PTS-HNSP, and lowest for OTS-HNSP.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Computer Science, Interdisciplinary Applications
Matthias Brugger, Roland Traxl, Roman Lackner
Summary: Numerical modeling of surface tension requires accurate interface description and efficient equation discretization. Smoothed particle hydrodynamics (SPH) is well-suited for modeling surface tension, but current formulations suffer from spurious currents near the interface, causing instability. A new discretization of the Continuum Surface Force (CSF) model is proposed in this work, conserving total energy and successfully suppressing spurious currents. Numerical tests show improved accuracy and convergence, indicating the stability of the new method.
JOURNAL OF COMPUTATIONAL PHYSICS
(2023)
Article
Mechanics
Jie Shen, Cheng Peng, Zhiming Lu, Lian-Ping Wang
Summary: Understanding the influence of different particle parameters on the two-way interactions between particles and wall-bounded turbulence is important. Particle-resolved direct simulation of particle-laden turbulent channel flow was performed using the lattice Boltzmann method. The results show that particle density and diameter have significant effects on the interactions between particles and the carrier turbulence, affecting variables such as velocity and angular velocity.
INTERNATIONAL JOURNAL OF MULTIPHASE FLOW
(2024)
Article
Multidisciplinary Sciences
Victor V. Volkov, Daniel J. Oliver, Carole C. Perry
NATURE COMMUNICATIONS
(2020)
Article
Chemistry, Physical
Monika Michaelis, Massimo Delle Piane, Dirk Rothenstein, Carole C. Perry, Lucio Colombi Ciacchi
Summary: In this study, four challenges hindering the understanding of ZnO/biomolecule interfaces at the atomic scale were overcome. The adsorption free energies predicted showed remarkable agreement with experimental measurements, revealing the mechanism of interactions between ZnO surface and amino acids.
JOURNAL OF CHEMICAL THEORY AND COMPUTATION
(2021)
Article
Chemistry, Applied
Victor V. Volkov, Carole C. Perry
Summary: This study utilized Raman spectroscopy to investigate the diagnostic capacity of identifying colored chromophores of fungi on paper, exploring the characteristics of chromophores and biochemistry of fungi in different regions. By conducting quantum chemistry calculations and comparing theory with experiment, specific chromophores such as fonsecin, erythroglaucin, and carotenes were identified in fungal filaments. The diverse Raman resonances observed in different spatial regions provide insights into the rich biochemistry of developing fungal structures, essential for understanding the impact of fungi on paper objects and designing new materials based on fungal hyphal mats.
Article
Chemistry, Multidisciplinary
Victor V. Volkov, Jonathan McMaster, Joanna Aizenberg, Carole C. Perry
Summary: Raman difference imaging provides insight on cellular biochemistry in vivo, assessing blood biochemistry at the cellular level. By analyzing Raman microscopic images of hemoglobin distribution in blood cells, pre-calculated tensors are used to interpret electronic transitions responsible for blood color. The technique offers a sensitive diagnostic tool for understanding cellular biochemistry.
Article
Nanoscience & Nanotechnology
Daniel J. Oliver, Victor V. Volkov, Carole C. Perry
Summary: Protein-mediated doping of ZnO with plasmonic nanoparticles allows for control over surfaces, electronic states, carrier dynamics, and spectral fingerprints. The synthesis of ZnO-nano-Au bioinorganic heterostructures using a chimeric polypeptide results in the formation of spherical and nonspherical gold nanoparticles embedded in ZnO. Optical and luminescence spectra reveal a complex palette of plasmon modes and near-infrared spectral fingerprints, indicating an increasing role of surfaces in carrier relaxation. Simulation theory suggests an interinclusion nanogold spacing of 10 nm or less.
ACS APPLIED NANO MATERIALS
(2021)
Article
Biochemistry & Molecular Biology
Victor V. Volkov, Riccardo Chelli, Carole C. Perry
Summary: This study used complexes of Cu2+(d(9)) with proline as a model to investigate the structural flexibility and electronic properties of copper metalloproteins through optical electronic spectra and infrared spectral responses. The moderately hydrated trans conformer was found to be the main structural form of the complex in water, with the antisymmetric stretching mode of the carbonyl moieties playing a dominant role in the spectrally broadened infrared resonance.
Article
Chemistry, Multidisciplinary
Victor V. Volkov, Ayesha Sadaf, Carole C. Perry
Summary: We used Raman microscopy to analyze the structure and chemical composition of a common plant pathogen, Botrytis cinerea. By using density functional theory, we computed Raman tensors specific to important fungal compounds and precursors, and analyzed the differences in distribution within spores and hyphal filaments. Our results suggest convergent evolution of secondary metabolites in plant pathogenic fungi.
Article
Chemistry, Multidisciplinary
Daniel J. Oliver, Victor V. Volkov, Carole C. Perry
Summary: A new approach to analyze band-gap and defect states within semiconductors is introduced using solid state excitation-emission matrices. The technique can deconvolve spectral signatures in 1D spectral space, allowing for the identification of different emission pathways. The method has been demonstrated to be applicable to a variety of inorganic and organic semiconductors.
ADVANCED MATERIALS INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Monika Michaelis, Lorenzo Cupellini, Carl Mensch, Carole C. Perry, Massimo Delle Piane, Lucio Colombi Ciacchi
Summary: The protein folding problem remains unsolved due to the limitations of current structure prediction methods in exploring the conformational ensemble of disordered peptides and proteins. A novel methodology is presented to predict spectroscopic fingerprints and tidy up the conformational ensembles of disordered peptides and regions. This finding has profound implications for the interpretation of experimental spectra and the development of improved structure prediction methods.
Article
Chemistry, Inorganic & Nuclear
Victor V. Volkov, Toby J. Blundell, Stephen Argent, Carole C. Perry
Summary: In this contribution, the structure and properties of hollow hexagonal microcrystals formulated with silicon catecholate anions and tetramethylenediamine cations are explored using X-ray single crystal diffraction, Raman spectroscopy, and quantum chemistry. The research focuses on predicting molecular Raman responses and analyzing experimental Raman images to understand the distribution of chemical components, the effect of catecholate hydrophobicity on water uptake, and strategies for expanding the functional properties of environmentally friendly silicon organic framework (SOF) materials through chemical and post-assembly modifications.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Analytical
Mithun Parambath, Aneeqa Fayyaz, Igor Efimov, Quentin S. Hanley, Carole C. Perry
Summary: This study presents a surface charge imaging method for heterogeneous biosilicas, which allows for the mapping of surface charge and reveals the relationship between surface morphology and local surface charge. The method can be applied in the study of living silicified biological tissues without the need for sectioning and fixation.
Article
Chemistry, Physical
Maryam Nurhuda, Carole C. Perry, Matthew A. Addicoat
Summary: Tight-binding approaches, such as Density Functional Tight Binding (DFTB), provide a balance between force field methods and Density Functional Theory (DFT). DFTB is significantly faster than DFT and can be used for a wide range of systems. The GFN-xTB method extends the applicability of DFTB to Metal-Organic Frameworks (MOFs) by providing parameters for a large number of elements. GFN-xTB offers high accuracy and computational efficiency, making it suitable for screening hypothetical MOF structures.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Victor V. Volkov, Hendrik Heinz, Carole C. Perry
Summary: This study investigates the silica binding activity and structural changes of a hydrophobic heptapeptide sequence, providing insights into its optical responses and thermodynamic properties when interacting with silica surfaces. The findings may contribute to the development of novel artificial bio-silica heterostructures.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Multidisciplinary Sciences
Zhifeng Kuang, Kristi M. Singh, Daniel J. Oliver, Patrick B. Dennis, Carole C. Perry, Rajesh R. Naik
NATURE COMMUNICATIONS
(2020)
Article
Nanoscience & Nanotechnology
Matthew Nicklin, Graham J. Hickman, A. Graham Pockley, Carole C. Perry
ACS APPLIED BIO MATERIALS
(2020)