期刊
LANGMUIR
卷 29, 期 50, 页码 15673-15681出版社
AMER CHEMICAL SOC
DOI: 10.1021/la4034657
关键词
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资金
- National Basic Research Program of China [2014CB932103]
- National Natural Science Foundation of China
- 111 Project [B07004]
- Central University Research Funds
- Program for Changjiang Scholars and the Innovative Research Team in University [PCSIRT: IRT1205]
- Beijing Municipal Commission of Education
Although the fabrication of hierarchical architectures with highly ordered functional units is of great importance for both fundamental science and practical application, the development of one-dimensional (1D) organic hierarchical micro/nanostructures based on low-molecular-weight (LMW) building blocks remains at an early stage. Herein, we report two types of micro/nanoscaled multicomponent fluorescent fiber systems with tunable hierarchical morphologies through a one-step coassembly process. With the aid of hydrogen-bonding motifs, LMW precursors (1,4-bis(5-phenyloxazol-2-yl)benzene (A) and two coassembled building blocks: 4-bromotetrafluorobenzene carboxylic acid (B) and 2,3,4,S,6-pentafluorophenol (C)) have been self-organized into fibers and flexible free-standing films, which show hierarchical micro/nanostructures as well as tunable one-/two-photon luminescence. The disassembly of the multicomponent A.B and A.C fibers occurs at high temperature, which further alters the luminescence properties of the multicomponent materials. Therefore, this work provides a facile wet chemical route for fabricating multicomponent LMW self-assembled fibers and free-standing film systems with tunable hierarchical structures and photoemission behaviors, and such self-organized systems may have potential applications in fields of two-photon luminescence and thermal sensors.
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