Article
Chemistry, Applied
Jonathan S. Cardoso, Zhi Lin, Paulo Brito, Licinio M. Gando-Ferreira
Summary: This article discusses the use of zeolites as fillers in mixed matrix membranes (MMMs) for gas separation. The difficulties in achieving high selectivity and low defects in the zeolite/polymer interface are well-documented. Researchers have found that functionalizing the zeolite surface with silane groups, amine groups, or ionic liquids improves the gas permeability and separation efficiency. This study focuses on a specific case of MMMs using SAPO-34 and compares surface modifications, proposing new membrane modifications and treatments.
SEPARATION AND PURIFICATION REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Petra Bacova, Wei Li, Alireza F. Behbahani, Craig Burkhart, Patrycja Polinska, Manolis Doxastakis, Vagelis Harmandaris
Summary: This study investigated the conformational and dynamical features of unentangled and mildly entangled cis-1,4-polybutadiene melts near an amorphous silica surface through atomistic simulations. The results reveal dynamical heterogeneities on the silica surface and suggest that configurational entropy plays an important role in the dynamic response of polymers confined between silica slabs.
Article
Engineering, Chemical
Nha Minh Nguyen, Quang Thanh Le, Duy Phuc-Hoang Nguyen, Tung Ngoc Nguyen, Thanh Tu Le, Tung Cao-Thanh Pham
Summary: This study synthesized pure silica DDR zeolite membranes on silica porous substrate using an economical and environmentally friendly process. The quality of the membrane depends on the exposed faces of seed crystals and the pH value of the template solution. The preparation process used minimal chemicals and generated no waste.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Chemistry, Physical
Van-Hoan Le, Alexandre Tarantola, Marie-Camille Caumon
Summary: This study aims to interpret the physical mechanisms behind the pressure-induced vibrational frequency shifts of CH4 and N-2 in binary mixtures such as CH4-CO2, N-2-CO2, and CH4-N-2, using two theoretical models and providing a predictive model for the frequency shift of the CH4 nu(1) band as a function of pressure, density, and composition.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Engineering, Chemical
Wahyu Kamal Setiawan, Kung-Yuh Chiang
Summary: In this study, biogenic silica (BSi) was extracted from rice husks and functionalized using three different molecular structure amine groups. The functionalized silica was combined with Pebax-1657 to form mixed matrix membranes (MMMs), which showed significantly improved CO2 permeability and CO2/N2 selectivity compared to Robeson's upper bound 2008. Among them, Pebax/BSi-MAPS-10 was the most reliable membrane. These findings suggest that amine functionalized BSi has great potential for CO2/N2 separation in industrial applications.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Physical
Ze-Yu Du, Yan-Zhao Yu, Ning-Fang Li, Yun-Shan Xue, Ling-Xi Xu, Hua Mei, Yan Xu
Summary: The study successfully synthesized two novel MOFs, among which Zn/Co/Mo-MOF exhibited remarkable CO production rate and a high selectivity of 91.4% for CO2 photoreduction, outperforming most reported MOF-based photocatalysts.
SUSTAINABLE ENERGY & FUELS
(2021)
Article
Engineering, Chemical
Mina Mohammadzadeh, Siamak Pakdel, Jafar Azamat, Hamid Erfan-Niya, Alireza Khataee
Summary: In this study, the performance of a pure silica PWN-type zeolite membrane in the separation of N2 and CO2 gas molecules was investigated using molecular dynamics simulations. The results showed that the Si-PWN membrane exhibited high selectivity for N2 over CO2.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Biochemistry & Molecular Biology
Mohammed Musthafa Kummali, David Cole, Siddharth Gautam
Summary: This study investigates the behavior of ethane and CO2 under different pore structures using molecular dynamics simulations, revealing the significant impact of pore connectivity on fluid behavior.
Article
Chemistry, Inorganic & Nuclear
Meng Jia Yin, Xiao Hong Xiong, Xue Feng Feng, Wen Yuan Xu, Rajamani Krishna, Feng Luo
Summary: To address the challenge of removing trace SO2 from SO2-containing products, the porous cage-based metal-organic framework ECUT-111 exhibits high adsorption capacity, excellent selectivity, and effectiveness under humid conditions, especially showing outstanding performance in SO2/CO2 separation and recycle use.
INORGANIC CHEMISTRY
(2021)
Article
Engineering, Chemical
Ali K. Sekizkardes, Samir Budhathoki, Lingxiang Zhu, Victor Kusuma, Zi Tong, Joshua S. McNally, Janice A. Steckel, Shouliang Yi, David Hopkinson
Summary: The research investigated the molecular-level structure-property relationship in PIM-based blend membranes, finding that using polyphosphazenes with higher ether side chain concentrations can improve compatibility with PIM-1. The experimentally fabricated blend membranes showed high CO2 permeability and improved CO2/N-2 selectivity.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Takumi Shibuya, Kenta Iyoki, Hiroaki Onozuka, Masanori Takemoto, Susumu Tsutsuminai, Takahiko Takewaki, Toru Wakihara, Tatsuya Okubo
Summary: Efficient and economical synthesis methods for CON-type aluminoborosilicate zeolite are in high demand. A dual use of organic structure-directing agents with different roles in the formation of CON-type zeolite is proposed. The intermediate addition method of tetraethylammonium hydroxide (TEAOH) can control competitive structure-directing effects and enhance the crystallization of CON-type zeolite, while N,N,N-trimethyl-(-)-cis-myrtanylammonium hydroxide (TMMAOH) is required in the early stage of crystallization.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Applied
Haimei Xu, Peng Lu, Guangying Fu, Jifa Miao, Jiaqi Zhao, Ruiqin Ding, Lei Zhao, Zhirong Lang, Xiaobo Yang, Valentin Valtchev
Summary: The zeolite community successfully synthesized high-silica LTA-type zeolites after 50 years of research, and found strong interactions between organic structure-directing agents and the framework. Removing the structure-directing agents is difficult and can only be done at high temperatures.
MICROPOROUS AND MESOPOROUS MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xiaojing Wu, Jerome Henin, Laura Baciou, Marc Baaden, Fabien Cailliez, Aurelien de la Lande
Summary: NOX5, a member of the NADPH oxidase family, is involved in the production of reactive oxygen species. Through computer simulations, researchers have uncovered the conformational dynamics and electron transfer mechanisms of NOX5 within a membrane environment. Key molecular mechanisms for superoxide production by NOX5 have been identified, paving the way for further investigation of ET processes in the wide family of NADPH oxidases using computer simulations.
FRONTIERS IN CHEMISTRY
(2021)
Article
Engineering, Chemical
Peipei Zhou, Ting Wu, Zhen Sun, Yinuo Liu, Xinwei Chen, Meihua Zhu, Fei Zhang, Na Hu, Yuqin Li, Tian Gui, Xiangshu Chen, Hidetoshi Kita
Summary: High-silica SSZ-13 membranes were synthesized using different sodium sources, and a pure phase membrane with high gas permeation was obtained using NaCl. The NaCl content influenced the crystal morphology and size, but had little effect on the membrane structure. The optimal membrane exhibited excellent gas permeance and selectivity, as well as hydrothermal stability in a humid environment.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Energy & Fuels
Amer Alanazi, Auby Baban, Muhammad Ali, Alireza Keshavarz, Stefan Iglauer, Hussein Hoteit
Summary: Carbon capture and sequestration (CCS) in geological formations is an important solution for reducing carbon emissions. A study using nuclear magnetic resonance (NMR) explores the residual saturations of CO2, N2, and a CO2/N2 mixture in an Indiana limestone, demonstrating the reduced hydrophilicity of the limestone due to the interaction with CO2. The study also examines the water displacement process in different pore sizes and provides comprehensive information for CCS and enhanced oil recovery (EOR) applications.
Article
Chemistry, Physical
D. T. Mauney, J. D. Mosley, L. R. Madison, A. B. McCoy, M. A. Duncan
JOURNAL OF CHEMICAL PHYSICS
(2016)
Article
Chemistry, Physical
Clotilde M. Lethiec, Lindsey R. Madison, George C. Schatz
JOURNAL OF PHYSICAL CHEMISTRY C
(2016)
Article
Chemistry, Multidisciplinary
Bhavya Sharma, Pradeep Bugga, Lindsey R. Madison, Anne-Isabelle Henry, Martin G. Blaber, Nathan G. Greeneltch, Naihao Chiang, Milan Mrksich, George C. Schatz, Richard P. Van Duyne
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2016)
Article
Chemistry, Multidisciplinary
Nan Jiang, Naihao Chiang, Lindsey R. Madison, Eric A. Pozzi, Michael R. Wasielewski, Tamar Seideman, Mark A. Ratner, Mark C. Hersam, George C. Schatz, Richard P. Van Duyne
Article
Chemistry, Multidisciplinary
Victoria M. Szlag, Matthew J. Styles, Lindsey R. Madison, Antonio R. Campos, Bharat Wagh, Dustin Sprouse, George C. Schatz, Theresa M. Reineke, Christy L. Haynes
Article
Chemistry, Multidisciplinary
Naihao Chiang, Nan Jiang, Lindsey R. Madison, Eric A. Pozzi, Michael R. Wasielewski, Mark A. Ratner, Mark C. Hersam, Tamar Seideman, George C. Schatz, Richard P. Van Duynett
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2017)
Article
Multidisciplinary Sciences
Stephanie M. Craig, Fabian S. Menges, Chinh H. Duong, Joanna K. Denton, Lindsey R. Madison, Anne B. McCoy, Mark A. Johnson
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2017)
Article
Chemistry, Physical
Laura C. Dzugan, Ryan J. DiRisio, Lindsey R. Madison, Anne B. McCoy
FARADAY DISCUSSIONS
(2018)
Article
Chemistry, Physical
Laura C. Dzugan, Ryan J. DiRisio, Lindsey R. Madison, Anne B. McCoy
FARADAY DISCUSSIONS
(2018)
Article
Chemistry, Multidisciplinary
Emily A. Sprague-Klein, Bogdan Negru, Lindsey R. Madison, Scott C. Coste, Brandon K. Rugg, Alanna M. Felts, Michael O. McAnally, Mayukh Banik, Vartkess A. Apkarian, Michael R. Wasielewski, Mark A. Ratner, Tamar Seideman, George C. Schatz, Richard P. Van Duyne
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2018)
News Item
Optics
Christine M. Aikens, Lindsey R. Madison, George C. Schatz
Article
Chemistry, Physical
Victor G. M. Lee, Lindsey R. Madison, Anne B. McCoy
JOURNAL OF PHYSICAL CHEMISTRY A
(2019)
Article
Chemistry, Physical
Ryan J. DiRisio, Jacob M. Finney, Laura C. Dzugan, Lindsey R. Madison, Anne B. McCoy
Summary: An approach for evaluating spectra from GSPA obtained from DMC simulations is extended to improve the description of excited state energies and allow for coupling among vibrational excited states. By extracting internal coordinates from the DMC ground state probability amplitude and developing a compact basis, the method provides good agreement with experimental results, allowing for interpretation of spectral features and their evolution with cluster size and deuteration.
JOURNAL OF PHYSICAL CHEMISTRY A
(2021)
Proceedings Paper
Chemistry, Applied
Lindsey R. Madison, Mark A. Ratner, George C. Schatz
FRONTIERS IN QUANTUM METHODS AND APPLICATIONS IN CHEMISTRY AND PHYSICS
(2015)