Electrochemical Preparation of Pore Wall Modification Gradients across Thin Porous Silicon Layers

Thin film porous silicon layers have been constructed in which the level of chemical modification to the pore walls is altered in a controlled gradient across the material. The gradient modification within such a nanoporous material represents a significant advance over gradients imposed across a flat surface. Gradients of methyl, pentyl acetate, and decyl groups are formed via electrochemical attachment of organohalides with an asymmetric electrode arrangement. The stability and hydrophobicity of the latter two systems have been improved through postprocess end-capping of the porous silicon with methyl groups. Two-dimensional mapping transmission FTIR microspectrophotometry and ATR-FTIR have been employed to characterize these new materials. Cleaving the surface-attached pentyl acetate groups to 5-hydroxypentyl groups leads to materials that can act as efficient visual indicators of the ethanol concentration in water over the range 1-10 vol %.