期刊
LANGMUIR
卷 25, 期 16, 页码 8982-8992出版社
AMER CHEMICAL SOC
DOI: 10.1021/la900659r
关键词
-
资金
- National Science Foundation, Arlington, VA [CHE-0531802, CHE-0600795]
Smaller members of water-soluble sulfonated calixarenes have been extensively explored in the context of host-guest complexation, supramolecular chemistry, and potential sensors. However. larger members especially eight-membered calixarene (CA[8]) has received much less attention because of its floppy nature and tendency to exist as a mixture of conformational isomers. Our continued interest in identifying molecules with an internal cavity as reaction vessels has led LIS to examine the host-guest complexation of CA[8] with photoactive bispyridyl ethylenes. We find that 4,4'-bispyridyl ethylene and 3,3'-bispyridvl ethylene upon complexation to CA[8] arrest the conformational equilibrium and force the latter to adopt a single conformation in solution. During complexation, bispyridyl ethylenes,ire protonated by the sulfonic acid groups of CA[8]. The host-guest complex is stabilized via an electrostatic interaction between the cationic bispyridyl ethylenes and anionic sulfonated calix[8]arene, and we propose the complex to have all inverted capsular structure. This model is also consistent with the electrochemical behavior of 4,4'-dimethylviologen included within CA[8], Rigidification of bispyridyl ethylenes by the host has,I consequence on the excited-state chemistry of the former. Generally, prevalent geometric isomerization of bispyridyl ethylenes are prevented by CA[8] upon complexation.
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