4.6 Article

Fluorescence Behavior of Cysteine-Mediated Ag@CdS Nanocolloids

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LANGMUIR
卷 25, 期 11, 页码 6377-6384

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AMER CHEMICAL SOC
DOI: 10.1021/la8042507

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  1. BARC, India

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Ag@CdS quantum dots were synthesized by a colloidal method. US nanoparticles stabilized by L-Cysteine were doped with varying silver concentrations. Ag@CdS nanoparticles were characterized by UV-visible spectroscopy, steady-state and time-resolved fluorescence, X-ray diffraction, Fourier transform infrared resonance (FTIR), and transmission electron microscopy. The effect of dopant concentration and effect of aging of Ag@CdS colloids were studied. At low silver content, emission was found to enhance, while at high silver content, emission quenching was observed after aging. Ag-CdS nanocolloids exhibited multiexponential decay with tau(2) being a long-lived component. X-ray diffraction spectra of as prepared samples indicated that silver occupies an interstitial position, while for annealed samples, Ag+ ions get oxidized to Ag2+ and substituted for Cd2+ in the US lattice. FTIR studies have shown that cysteine acts as a monodentate ligand for cadmium and silver for as-prepared sample, whereas it acts as a tridentate ligand for annealed samples toward silver. Transmission electron microscopy of as-prepared samples showed spherical-shaped composites with a uniform layer of capping molecules.

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