4.4 Article

Absorption of NO from simulated flue gas by using NaClO2/(NH4)(2)CO3 solutions in a stirred tank reactor

期刊

KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 30, 期 1, 页码 101-104

出版社

KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-012-0121-1

关键词

NO; (NH4)(2)CO3; Absorption; Kinetics

资金

  1. Scientific Problem Tackling Program of Science and Technology Commission of Shanghai Municipality [10dz1201401, 10dz1201402, 11dz1201400]
  2. Fifth Key Subject of Shanghai Education Commission [G51034]
  3. Absorption and Innovation Program of Introduced Technology of Shanghai [Product-40-orientation-28]
  4. Innovation Program of Shanghai Municipal Education Commission [10YZ155]
  5. Shanghai Municipal Education Commission [sdl09008]
  6. Talent Induction Program of Shanghai University of Electric Power [K-2009-03]

向作者/读者索取更多资源

Experiments were performed in a stirred tank reactor to study the absorption kinetics of NO into aqueous solutions of NaClO2/(NH4)(2)CO3 solutions. The absorption process is a fast pseudo-reaction, and the reaction was found to be second-order with respect to NO and first-order with respect to NaClO2, respectively. The frequency factor and the average activation energy of this reaction were 4.56 x 10(11) m(6)/(mol(2) s) and 33.01 kJ/mol respectively. The absorption rate of NO increased with increasing reaction temperature, but decreased with increasing (NH4)(2)CO3 solution.

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