期刊
KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 30, 期 1, 页码 101-104出版社
KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-012-0121-1
关键词
NO; (NH4)(2)CO3; Absorption; Kinetics
资金
- Scientific Problem Tackling Program of Science and Technology Commission of Shanghai Municipality [10dz1201401, 10dz1201402, 11dz1201400]
- Fifth Key Subject of Shanghai Education Commission [G51034]
- Absorption and Innovation Program of Introduced Technology of Shanghai [Product-40-orientation-28]
- Innovation Program of Shanghai Municipal Education Commission [10YZ155]
- Shanghai Municipal Education Commission [sdl09008]
- Talent Induction Program of Shanghai University of Electric Power [K-2009-03]
Experiments were performed in a stirred tank reactor to study the absorption kinetics of NO into aqueous solutions of NaClO2/(NH4)(2)CO3 solutions. The absorption process is a fast pseudo-reaction, and the reaction was found to be second-order with respect to NO and first-order with respect to NaClO2, respectively. The frequency factor and the average activation energy of this reaction were 4.56 x 10(11) m(6)/(mol(2) s) and 33.01 kJ/mol respectively. The absorption rate of NO increased with increasing reaction temperature, but decreased with increasing (NH4)(2)CO3 solution.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据