期刊
KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 25, 期 2, 页码 231-235出版社
KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-008-0041-2
关键词
heteropolyacid catalyst; immobilization; nitrogen-containing mesoporous carbon; 2-propanol conversion reaction; oxidation catalysis
Nitrogen-containing mesoporous carbon (N-MC) with high surface area (= 1, 115 m(2)/g) and large pore volume (=1.18 cm(3)/g) was synthesized by a templating method. The surface of N-MC was then modified to form a positive charge, and thus, to provide sites for the immobilization of [PMo12O40](3-). By taking advantage of the overall negative charge of [PMo12O40](3-), HPMo12O40 (PMo12) was chemically immobilized on the N-MC support as a charge matching component. It was found that the PMo12/N-MC still retained relatively high surface area (=687 m(2)/g) and large pore volume (=0.67 cm(3)/g) even after the immobilization of PMo12. It was also revealed that PMo12 species were finely and molecularly dispersed on the N-MC support via chemical immobilization. In the vapor-phase 2-propanol conversion reaction, the PMo12/N-MC showed a higher conversion than the unsupported PMo12. Furthermore, the PMo12/N-MC showed an enhanced oxidation catalytic activity and a suppressed acid catalytic activity compared to the unsupported PMo12. This catalytic behavior of PMo12/N-MC was due to the molecular dispersion of PMo12 on the N-MC support formed via chemical immobilization by sacrificing the proton.
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