Article
Polymer Science
Alireza Ghasemzadeh, Navid Famili
Summary: This research studied the effect of crystallinity on the final structure of microcellular foam. By controlling the temperature gradient, the crystallization rate can be controlled, thus affecting the formation of cells.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Engineering, Chemical
Yunhan Wen, Lorenz. T. Biegler, Maria P. Ochoa, Logan Matthews, Jeff Ferrio, John Weston, Nima Nikbin
Summary: This study focuses on developing continuous reactor network models for producing rigid polyols under strict product and safety specifications, while determining optimal decision profiles for minimum capital cost. By narrowing down the types of continuous reactors and exploring various decision variables, the study aims to find the most cost-effective solution for producing rigid polyols.
CHEMICAL ENGINEERING SCIENCE
(2021)
Article
Chemistry, Physical
Ling Zhang, Qing Wang, Faxing Xu, Zhenye Wang, Lijian Leng
Summary: This study investigates the dechlorination behavior of rigid PVC plastics (R-PVC) using hydrothermal treatment (HTT). The results show that the hydrothermal temperature is a key factor affecting the dechlorination efficiency. Dechlorination mainly occurs through nucleophilic substitution of chlorine by -OH. Additionally, the presence of CaCO3 affects the dechlorination behavior of R-PVC, distinguishing it from pure PVC resins.
Article
Chemistry, Multidisciplinary
Dhananjay V. Deshmukh, Peter Reichert, Joel Zvick, Celine Labouesse, Valentin Kunzli, Oksana Dudaryeva, Ori Bar-Nur, Mark W. Tibbitt, Jurg Dual
Summary: In this study, an acoustofluidic device was developed to pattern mammalian cells within hydrogel fibers, allowing muscle progenitor cells to be aligned in parallel lines to mimic skeletal muscle structure. Increased formation of myotubes and spontaneous twitching were observed in patterned samples, demonstrating the potential of using this approach for engineering complex 3D tissues in the future.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Engineering, Manufacturing
Karun Kalia, Amir Ameli
Summary: This study reports on the process-microstructure-property relationships of microcellular foams printed using the material extrusion (MEX) additive manufacturing (AM) process. Polylactic acid and thermally expandable microspheres were mixed and extruded, and in situ foaming during the MEX AM process was conducted to investigate the impact of various parameters on the foam's morphology, structure, density, and mechanical behavior. The temperature and residence time were identified as key factors influencing the foaming behavior and resultant properties. The findings provide insights for advancing the MEX AM process as a novel manufacturing approach for producing high-quality foams.
ADDITIVE MANUFACTURING
(2023)
Article
Nanoscience & Nanotechnology
Karun Kalia, Benjamin Francoeur, Alireza Amirkhizi, Amir Ameli
Summary: A facile manufacturing method for in situ foam 3D printing of thermoplastic materials is reported. By incorporating thermally expandable microspheres (TEMs) into the filament, the researchers achieved the in situ foaming during printing, resulting in highly uniform cellular structures. The study also found that the addition of TEM and plasticizer did not significantly affect the critical temperatures of the material, but the foaming process greatly improved its ductility and toughness.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Paper & Wood
Stephanie C. Hernandez, Romain Milotskyi, Shohei Takagi, Elisabeth R. D. Ito, Shiori Suzuki, Naoki Wada, Kenji Takahashi
Summary: Cellulose mixed esters (CMEs) with tunable properties are difficult to produce due to the insolubility of cellulose. A rapid and scalable production method of CMEs was demonstrated using a twin-screw extruder as a flow reactor. By using a co-solvent system and continuous extrusion, cellulose acetate propionate (CAP) was obtained within minutes with high conversion rates.
Article
Engineering, Chemical
Yichong Chen, Dongyang Li, Hong Zhang, Yijie Ling, Kaiwen Wu, Tao Liu, Dongdong Hu, Ling Zhao
Summary: A comprehensive model for the shrinkage behavior of soft TPU elastomer foams has been established, incorporating in situ tensile testing and evaluation of different cell shapes. The study found that hexagonal cells match the actual shrinkage process well and that a high nitrogen content in cells can improve antishrinking ability. Additionally, a method of aging TPU foam under variable ambient vacuum to reduce shrinkage ratio was proposed and validated.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Engineering, Manufacturing
Tim Kuipers, Renbo Su, Jun Wu, Charlie C. L. Wang
Summary: Material Extrusion (MEX) systems with dual-material capability have the potential for various applications. The researchers proposed a new lattice structure called interlaced topologically interlocking lattice (ITIL), which ensures continuous extrusion and interlock. The ITIL demonstrated good performance in terms of applicability and strength, as validated by analytical models and experiments.
ADDITIVE MANUFACTURING
(2022)
Article
Chemistry, Physical
Menglong Xu, Yajie Liu, Yukai Ge, Chongxiang Zhao, Linfeng Wei, Dongdong Hu, Tao Liu, Ling Zhang, Ling Zhao, Chul B. Park
Summary: This study utilized the long-chain branched (LCB) structure in the polyamide 6 (PA6) matrix to prepare low-density microcellular PA6 composite foams with favorable cell morphology. The effects of LCB degree on the rheological behavior, crystallization rate, and gas solubility of CO2 in the PA6 composites were investigated. High-performance PA6 composite foams with small cell size, high cell density, and wide foaming temperature window were successfully obtained through continuous extrusion foaming.
JOURNAL OF SUPERCRITICAL FLUIDS
(2023)
Article
Polymer Science
Samira Maou, Yazid Meftah, Masoud Tayefi, Ahmed Meghezzi, Yves Grohens
Summary: The mechanical and thermal properties of an uncompatibilized blend, i.e., polyvinyl chloride-high-density polyethylene (PVC-HDPE), can be improved by introducing maleic anhydride (MAH) into the blend polymer. The addition of MAH enhances the adhesion between the two immiscible polymers, increases the thermal stability, and raises the glass transition temperature (Tg) of the blend.
JOURNAL OF POLYMER RESEARCH
(2022)
Article
Pharmacology & Pharmacy
Derick Muhindo, Eman A. Ashour, Mashan Almutairi, Poorva H. Joshi, Michael A. Repka
Summary: This study aimed to produce orally administered raloxifene hydrochloride loaded nanostructured lipid carrier formulations with extended drug release using HME technology and probe sonication. The NLCs prepared showed smaller particle sizes, higher entrapment efficiency, and better drug release compared to traditional methods. The formulations demonstrated good physical stability over time, indicating that this technique may be more industry-friendly.
JOURNAL OF DRUG DELIVERY SCIENCE AND TECHNOLOGY
(2021)
Article
Metallurgy & Metallurgical Engineering
Ying Zhao, Jiu-yang Pei, Li-li Guo, Xin-bing Yun, Huai-chao Ma
Summary: The rotational speed of the extrusion wheel has a significant effect on the micromorphology and properties of welds of 6063 Al alloy, accelerating the breakage of oxide on the welding surface and the formation of metallurgical bonding. The tensile strength and elongation of the weld specimen increase with increasing extrusion speed.
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
(2021)
Article
Chemistry, Multidisciplinary
Romain Milotskyi, Gyanendra Sharma, Tetsuo Fujie, Daisuke Hirose, Naoki Wada, Kenji Takahashi
Summary: More energy efficient and greener processes are needed in chemical engineering. Reactive extrusion is a new innovation targeting cleaner and more sustainable processes. This study examined the solubility of microcrystalline cellulose, developed a new method of measuring residence time distribution inside the extruder, performed transesterification of cellulose, and evaluated the effect of cellulose concentration on the properties of cellulose laurate films.
REACTION CHEMISTRY & ENGINEERING
(2023)
Article
Pharmacology & Pharmacy
Esther Jacobs, Kaije Qian, Valerie L. Pietsch, Margarethe Richter, David S. Jones, Gavin P. Andrews, Yiwei Tian
Summary: This paper introduces a novel anhydrous twin-screw extrusion platform technology to address the challenges of developing and scaling up nanoparticle drug delivery systems.
INTERNATIONAL JOURNAL OF PHARMACEUTICS
(2022)
Article
Nanoscience & Nanotechnology
Thomas Close, Gaurav Tulsyan, Carlos A. Diaz, Steven J. Weinstein, Christiaan Richter
NATURE NANOTECHNOLOGY
(2015)
Article
Engineering, Manufacturing
Gaurav Tulsyan, Christiaan Richter, Carlos A. Diaz
PACKAGING TECHNOLOGY AND SCIENCE
(2017)
Article
Agricultural Engineering
Laurent M. Matuana, Omar Faruk, Carlos A. Diaz
BIORESOURCE TECHNOLOGY
(2009)
Article
Materials Science, Composites
Carlos A. Diaz, Kojo A. Afrifah, Shan Jin, Laurent M. Matuana
COMPOSITES SCIENCE AND TECHNOLOGY
(2011)
Article
Engineering, Chemical
Laurent M. Matuana, Carlos A. Diaz
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2010)
Article
Engineering, Chemical
Laurent M. Matuana, Carlos A. Diaz
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2013)
Article
Chemistry, Multidisciplinary
Carlos A. Diaz, Yining Xia, Maria Rubino, Rafael Auras, Krishnamurthy Jayaraman, Joseph Hotchkiss
Meeting Abstract
Chemistry, Multidisciplinary
Maria Rubino, Rafael Auras, Yining Xia, Carlos Diaz, Joseph Hotchikss, Krishnamurthy Jayaraman
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2013)