期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 94, 期 3, 页码 715-718出版社
SPRINGER
DOI: 10.1007/s10973-008-9117-9
关键词
cation exchange; CO2 adsorption; dehydration behavior; NaX zeolite
In this study, NaX synthetic zeolite was modified by following the conventional cation exchange method at 70A degrees C. 82, 81, 79 and 48% of sodium were exchanged with Li+, K+, Ca2(+) and Ce3(+), respectively. Thermal analysis data obtained by TG/DSC was used to evaluate the dehydration behavior of the zeolites. The strongest interaction with water and the highest dehydration enthalpy (Delta H) value were found for Li-exchanged form and compared with the other forms. The temperature required for complete dehydration increased with decreasing cation size (cation size: K+> Ce3+> Ca2(+)> Na+> Li+). CO2 adsorption at 5 and 25A degrees C was also studied and the virial model equation was used to analyze the experimental data to calculate the Henry's law constant, K (o) and isosteric heat of adsorption at zero loading Q (st). K (o) values decreased with increasing temperature and the highest Qst was obtained for K rich zeolite. It was observed that both dehydration and CO2 adsorption properties are related to cation introduced into zeolite structure.
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