期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 93, 期 1, 页码 111-113出版社
SPRINGER
DOI: 10.1007/s10973-007-8825-x
关键词
activation energy; kinetic equation; thermal analysis
The peak temperature (T-p) and different temperature (Delta T) are the basic information in the differential thermal analysis (DTA). Considering the kinetic relation and the heat equilibrium in DTA, a correctional differential kinetic equation (containing T-p and Delta T parameter) is proposed. In the dehydration reaction of CaC2O4 center dot H2O, the activation energy calculated from the new equation showed some smaller than that from Kissinger equation, but some bigger than that from Piloyan equation.
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