期刊
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
卷 73, 期 1, 页码 73-85出版社
SERBIAN CHEMICAL SOC
DOI: 10.2298/JSC0801073C
关键词
dimethyl sulfoxide; 1,4-dimethylbenzene; VLE data; density; viscosity; excess properties
This paper reports the experimental results of isothermal vapor-liquid equilibrium data between 303.15 and 333.15 K, and densities, viscosities, refractive indices from 298.15 to 323.15 K of the dimethyl sulfoxide + 1,4-dimethylbenzene system over the entire range of mixture composition. The obtained PTX data were correlated by the Wilson and NRTL models and estimated by the UNIFAC model. The excess Gibbs energy and activity coefficients were calculated and compared with others excess properties. Excess molar volumes, viscosity deviations and deviations in refractivity were calculated from the experimental data; all the computed quantities were fitted to the Redlich-Kister equation. The resulting excess functions were interpreted in terms of structure and interactions.
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