4.3 Article

On the Mechanism of Electrical Conduction in Cobalt-Doped Zinc Oxide Nanocrystalline Thin Films

期刊

出版社

PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.81.054602

关键词

spin-coating; Co doped ZnO; structure; electrical conductivity; multiphonon hopping

向作者/读者索取更多资源

ZnO and Co-doped ZnO thin films (3 and 11 at. %) were grown on glass substrates by spin coating method and structurally investigated by X-ray diffraction, X-ray photoelectron spectroscopy and UV-vis absorption spectroscopy. It was established that Co enters into ZnO wurtzite lattice by substitution. The electrical conductivity of undoped and Co-doped ZnO nanocrystalline thin films was measured in the temperature range of 300-425 K. The electrical conduction mechanism of the films is explained on the basis of the multiphonon assisted hopping model with a weak electron phonon coupling. We found that the conductivity first increases with incorporation in ZnO structure of an amount of 3 at. % Co but then it decreases when the amount of Co is increased to 11 at. %. This situation is well explained by the fluctuation in the hopping rate.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.3
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Effects of annealing under different atmospheres on structural and optical properties of USCVD grown ZnO nanostructures

E. Kutlu-Narin, P. Narin, A. Yildiz, S. B. Lisesivdin

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS (2020)

Article Chemistry, Physical

A route towards enhanced UV photo-response characteristics of SnO2/p-Si based heterostructures by hydrothermally grown nanorods

Kenan Ozel, Abdullah Atilgan, Nur Efsan Koksal, Abdullah Yildiz

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

Article Physics, Condensed Matter

Al-Ga co-doped ZnO/Si heterojunction diodes

Nur Efsan Koksal, Mohamed Sbeta, Abdullah Atilgan, Abdullah Yildiz

Summary: The study presents a facile method to produce heterojunction diodes by depositing AGZO thin films on Si substrates and examines the impact of AGZO layer thickness on diode performances. While the thickness of AGZO has insignificant effects on structural, morphological, and optical properties, it can effectively enhance device characteristics. Diodes with 125 nm AGZO exhibit improved performance with remarkable rectification properties.

PHYSICA B-CONDENSED MATTER (2021)

Article Energy & Fuels

Optimizing Deposition Parameters of DSSCs Composed of Blue TiO2

Aycan Atli, Irem Sutcu, Z. Kerem Yildiz, Abdullah Yildiz

Summary: A simple deposition process was developed to fabricate dye-sensitized solar cells (DSSCs) with significantly improved power conversion efficiency by soaking the compact layer in a solution and preheating it. These results highlight the critical importance of deposition conditions for enhancing the performance of DSSCs.

IEEE JOURNAL OF PHOTOVOLTAICS (2021)

Review Chemistry, Multidisciplinary

Tin Oxide Electron-Selective Layers for Efficient, Stable, and Scalable Perovskite Solar Cells

Cesur Altinkaya, Erkan Aydin, Esma Ugur, Furkan H. Isikgor, Anand S. Subbiah, Michele De Bastiani, Jiang Liu, Aslihan Babayigit, Thomas G. Allen, Frederic Laquai, Abdullah Yildiz, Stefaan De Wolf

Summary: Tin oxide (SnO2) has emerged as a promising alternative to electron-selective layers (ESLs) in perovskite solar cells (PSCs), offering advantages such as high optical transmission, high carrier mobility, and low-temperature processability. It has the potential to play a key role in large-scale deployment and manufacturing.

ADVANCED MATERIALS (2021)

Article Engineering, Electrical & Electronic

Sol-gel prepared ZnO:Al thin films for heterojunction diodes

O. F. Goktas, N. E. Koksal, O. Kaplan, A. Yildiz

Summary: The sol-gel method was used to fabricate Al-doped ZnO (AZO) thin films on p-Si substrates with smooth surfaces and highly oriented crystal structures. The analysis revealed that the AZO/Si heterojunctions exhibited nonideal diode behavior, with the 80 nm thick AZO layer demonstrating good rectifying properties.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2021)

Article Materials Science, Multidisciplinary

Effect of magnesium content and growth temperature on structural and optical properties of USCVD-grown MgZnO films

E. Kutlu-Narin, P. Narin, A. Yildiz, S. B. Lisesivdin

Summary: The study looked at the effects of magnesium content and growth temperature on the optical and structural properties of magnesium zinc oxide films, finding a linear correlation between magnesium mole fraction and magnesium content in the liquid solution. The peak of the (0002) diffraction for the grown samples shifted to higher angles and became stronger with increasing magnesium content in the liquid solution. Both growth temperature and magnesium content in the liquid solution are crucial parameters in controlling the magnesium mole fraction of the samples.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2021)

Article Energy & Fuels

Carminic acid extracted from cochineal insect as photosensitizer for dye-sensitized solar cells

Yavuz Kocak, Abdullah Yildiz

Summary: Utilizing carminic acid as a photosensitizer in dye-sensitized solar cells showed promising results in terms of light absorption and surface anchoring, but the suppression of electron recombination was found to be inadequate. Quantum chemical calculations confirmed the compatibility of carminic acid with the conduction band edge of TiO2, leading to improved photo-conversion efficiency compared to natural dye-based DSSCs under simulated solar light.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2021)

Article Materials Science, Multidisciplinary

A Self-Powered Ultraviolet Photodetector with Ultrahigh Photoresponsivity (208 mA W-1) based on SnO2 Nanostructures/Si Heterojunctions

Kenan Ozel, Abdullah Yildiz

Summary: The author proposed a novel design scheme by integrating a nanostructured SnO2 layer into the n-SnO2/p-Si heterojunction, resulting in devices with high photoresponsivity, quantum efficiency, and detectivity. These PDs possess self-powered characteristics and exhibit high performance for 311 nm wavelength without any power supply.

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS (2021)

Article Engineering, Electrical & Electronic

W-doped ZnO transparent conducting nanostructures synthesized by hydrothermal method

Abdullah Atilgan, Ahmet Yigit Kurtulus, Mehmet Fatih Oktem, Abdullah Yildiz

Summary: A simple method was employed to synthesize undoped and W-doped ZnO nanostructures, with temperature strongly affecting the structural, optical, and electrical properties of the films. Undoped NSs showed better performance based on transparency and sheet resistance values, and W-doped ZnO was found to be a promising transparent conducting oxide for various applications.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2021)

Article Engineering, Electrical & Electronic

High-detectivity ultraviolet-B photodetector based on SnO2 thin film/Si heterojunction

Kenan Ozel, Abdullah Yildiz

Summary: This study introduces a p-n heterojunction photodetector based on metal oxide materials, demonstrating efficient detection of UV-B light with high detectivity, responsivity, and UV/visible rejection ratio.

SEMICONDUCTOR SCIENCE AND TECHNOLOGY (2021)

Article Chemistry, Physical

Efficient Iron Phosphide Catalyst as a Counter Electrode in Dye-Sensitized Solar Cells

Abdullah Yildiz, Takwa Chouki, Aycan Atli, Moussab Harb, Sammy W. Verbruggen, Rajeshreddy Ninakanti, Saim Emin

Summary: Transition metal phosphides, particularly the Fe2P phase, show comparable solar-to-current conversion efficiency with platinum (Pt) as a counter electrode in dye-sensitized solar cells (DSSCs) while exhibiting improved stability, making them a promising Pt-free alternative for efficient DSSCs.

ACS APPLIED ENERGY MATERIALS (2021)

Article Materials Science, Multidisciplinary

Ultraviolet photodiode fabricated from TiO2 nanorods/p-silicon heterojunction

Betul Sekertekin, Kenan Ozel, Abdullah Atilgan, Abdullah Yildiz

Summary: In this paper, a UV photodiode based on TiO2 nanorods has been successfully fabricated, showing superior UV detection capability. The presented fabrication approach can also be applied to other metal-oxide semiconductor optoelectronic devices.

MATERIALS LETTERS (2022)

Article Chemistry, Physical

Optical and Photosensitive Properties of Flexible n(p)-InSe/In2O3 Heterojunctions

Veaceslav Sprincean, Liviu Leontie, Iuliana Caraman, Dumitru Untila, Mihaela Girtan, Silviu Gurlui, Petru Lisnic, Corneliu Doroftei, Aurelian Carlescu, Felicia Iacomi, Mihail Caraman

Summary: This study investigates the optical characteristics of micrometer-sized flexible InSe/In2O3 heterojunctions and suggests their potential for optoelectronic applications.

MATERIALS (2022)

Article Chemistry, Multidisciplinary

Studies of the Structure and Optical Properties of BaSrMgWO6 Thin Films Deposited by a Spin-Coating Method

Luciana Punga, Abderrahman Abbassi, Mihaela Toma, Teodor Alupului, Corneliu Doroftei, Marius Dobromir, Daniel Timpu, Florica Doroftei, Laura Hrostea, George G. Rusu, Abdelati Razouk, Felicia Iacomi

Summary: Highly transparent BaSrMgWO6 thin films were deposited using spin coating, and their structure and optical properties were investigated after annealing at different temperatures. The films exhibited a nanocrystalline structure with impurity phases, and their optical band gap values were determined from transmittance measurements.

NANOMATERIALS (2022)

暂无数据