3.9 Article

Synthesis of Cellulose-Based Macromolecular Coupling Agent and its Utilization in Poly (butylene succinate)/Wood Flour Composites

期刊

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING
卷 54, 期 6, 页码 639-646

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/03602559.2014.974284

关键词

Cellulose ester; Composites; Hydroxyethyl cellulose; Macromolecular coupling agent; Poly (butylene succinate); Wood flour

资金

  1. State Key Laboratory of Pulp and Paper Engineering [201469]
  2. Doctor Starting Program of Shaanxi University of Science and Technology [BJ11-23]

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A long fatty side chain was introduced into the macromolecule of hydroxyethyl cellulose (HEC) via esterification reaction. The hydrophobicity of hydroxyethyl cellulose lauric acid ester (HECLAE) was enhanced in comparison with HEC. The obtained HECLAE was used as macromolecular coupling agent in poly (butylene succinate)/wood flour composites and exhibited a positive influence on improving the mechanical performance of composites. Besides, HECLAE plays a role as a hydrophobic agent in composites. A significant increase in storage modulus (E') was observed upon the incorporation of treated wood flour. SEM images showed that the dispersion of treated wood flour in PBS matrix was improved.

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