Article
Materials Science, Paper & Wood
Geng Li, Xiao Dai, Yixuan Min, Chang Yu, Tomoyuki Ikai, Lili Zhang, Jun Shen, Yoshio Okamoto
Summary: Researchers developed eight organic-inorganic hybrid bead-type chiral packing materials with high organic contents using a modified Stober process in basic conditions. The preparation conditions significantly affected the organic contents and morphology of the hybrid materials, with those having higher organic content showing better enantioseparation ability.
Article
Engineering, Chemical
Xin Qiu, Wenbei Chen, Yuting Chen, Jian Ke, Yibing Ji, Jianqiu Chen
Summary: In this study, three different chiral ionic liquids were synthesized and used to fabricate a chiral composite membrane for enantioseparation. The filtration conditions were optimized to improve the separation effect of the membrane. Molecular simulation was also conducted to study the separation mechanism and recognition mechanism of different chiral molecules. The prepared chiral membrane showed excellent enantioseparation performance, providing new insights for the design of chiral membranes.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Analytical
Nijuan Liu, Jingjing Liu, Xiaohui Niu, Jia Wang, Ruibin Guo, Zunli Mo
Summary: A facile chiral composite (3D-NGMWCNT@(S,S)-CIL) with excellent electrochemical performance was prepared by integrating 3D-NGMWCNT and (S,S)-CIL. The constructed sensor showed high sensitivity and stability for enantioselective recognition of Trp enantiomers. This novel sensor provides an efficient and convenient strategy for chiral enantioselective recognition.
Article
Chemistry, Physical
Mariana Barbosa, Helvio Simoes, Duarte Miguel E. Prazere
Summary: Functionalization of cellulose with biomolecules can lead to materials with enhanced properties, with the ability to control biological interactions. By efficiently combining relevant biomolecules into cellulose materials, novel functionalities can be achieved, paving the way for advanced medical diagnostic sensors or specialized biomaterials.
Article
Chemistry, Physical
Davis Anum, David K. Bwambok
Summary: This paper describes the synthesis, characterization, and investigation of a fluorescent chiral ionic liquid [TrpC2][NTf2] and its enantiomeric recognition properties for various chiral analytes.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Multidisciplinary
Xiang Li, Yanzhao Yang, Cristian Valenzuela, Xuan Zhang, Pan Xue, Yuan Liu, Changjun Liu, Ling Wang
Summary: Chameleonskin is naturally adaptive and can sense environmental changes and transform them into bioelectrical and optical signals. In this study, a bioinspired mechanochromic chiral nematic nanostructured film with good ionic conductivity was designed and fabricated by infiltrating fluorine-rich ionic liquids (FILs) into a swollen self-assembled cellulose nanocrystal (CNC) film. This film exhibited excellent mechanochromism, good ionic conductivity, and outstanding optical/electrical dual-signal sensing performance.
Article
Chemistry, Multidisciplinary
Peng Zhu, Wei Liu, Baozong Li, Yi Li, Yonggang Yang
Summary: This passage describes a series of newly designed and synthesized pyridinium-based chiral ionic liquid crystals and non-ionic substances, displaying different phases with some exhibiting special phases. Fluoro-substitution can affect clearing points and drive the formation of molecular structures.
Article
Chemistry, Multidisciplinary
Lukas Marcos Celada, Judith Martin, Sergey V. Dvinskikh, Peter Olsen
Summary: Biopolymers, especially cellulose, play a vital role in transitioning to a circular economy and reducing reliance on fossil fuels. However, modifying cellulose hydroxyls is a challenge due to the similarity of their chemical features with water. To address this, we developed bio-based ionic liquids that can activate cellulose without disturbing its crystalline ordering. One specific ionic liquid showed high activation in heterogeneous conditions, resulting in over 30% conversion of cellulose hydroxyls. This work opens new perspectives for cellulose derivatization while maintaining sustainability.
Article
Polymer Science
Julian Radicke, Eliane Roos, Daniel Sebastiani, Martin Brehm, Joerg Kressler
Summary: We report the first example of a chiral polymer-cellulose being dissolved in both enantiomers of a chiral solvent. Six room temperature ionic liquids (ILs) based on imidazolium and 1,2,3-triazolium cations and lactate as chiral anion were synthesized. The ILs were found to be relatively good cellulose solvents with a solubility of up to 18.5 wt.-%. Interestingly, there were significant solubility differences between the enantiomers of the solvent, indicating a pronounced chiral recognition effect.
JOURNAL OF POLYMER SCIENCE
(2023)
Article
Chemistry, Medicinal
Fan Wang, Yuqing Wang, Yixuan Min, Junqing Li, Lili Zhang, Ting Zheng, Jun Shen, Yoshio Okamoto
Summary: A novel cellulose derivative Cel-1 was synthesized and used to prepare a chiral stationary phase (CSP) for high-performance liquid chromatography (HPLC). Cel-1 exhibited excellent chiral recognition ability and enantioselectivity, outperforming commercially available CSPs. The bulky benzothienyl pendants on Cel-1 played a key role in its high chiral recognition ability, particularly in fluorescence quenching.
Article
Chemistry, Multidisciplinary
Yongxin Du, Zunli Mo, Hebing Pei, Wentong Liu, Ruimei Yue, Xinran Wang
Summary: A self-assembled Cu(ii)-coordinated dual-polysaccharide composite was synthesized and used as a chiral selector in the synthesis of a novel chiral carbon nanocomposite. The results showed that the composite exhibited higher selectivity towards tryptophan enantiomers.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Analytical
Huipeng Hou, Shanshan Tang, Yiquan Liu, Wei Wang, Axin Liang, Liquan Sun, Aiqin Luo
Summary: A novel strategy to improve the enantiorecognition ability of chitosan using MoS2-IL nanocomposite was proposed. By optimizing various parameters, successful quantification of enantiomer excess in Trp mixtures was achieved.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Article
Materials Science, Paper & Wood
Yunhao Liang, James E. Hawkins, Michael E. Ries, Peter J. Hine
Summary: This study investigated the dissolution of cotton fibres in the ionic liquid [C2mim][OAc], showing that the resulting coagulated fraction had a crystal structure predominantly of cellulose II. Despite differences in growth patterns of the coagulated fraction for three distinct fibre arrangements, all could be shifted to form master curves using Time-Temperature Superposition, with very similar activation energies determined.
Review
Materials Science, Paper & Wood
Katherine S. Lefroy, Brent S. Murray, Michael E. Ries
Summary: Microgel particles, particularly cellulose microgels, have shown promise as alternative emulsion stabilisers with environmental advantages. The ability of microgels to swell and rearrange on interfaces makes them suitable for long-term stabilization in various industries. However, challenges such as cellulose insolubility and surface activity hinder their full potential as emulsion stabilisers.
Article
Polymer Science
Zhen Xu, Qiwen Zhou, Lixiang Wang, Guangmei Xia, Xingxiang Ji, Jinming Zhang, Jun Zhang, Haq Nawaz, Jie Wang, Jianfeng Peng
Summary: Utilizing used paper cups to produce cellulose-based films with good thermal property, hydrophobicity, and mechanical strength, demonstrates their potential as packaging materials, providing a solution for recycling and valorization of waste paper cups.