期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 33, 期 11, 页码 2155-2165出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2013.03.013
关键词
Perovskite; Ceramics; Ferroelectricity; Piezoelectricity
资金
- National Nature Science Foundation of China [91122020]
Ceramics of the xPb(Zn1/3Nb2/3)O-3-(1-x-Y)Pb(Yb1/2Nb1/2)O-3-yPbTiO(3) (PZN-PYN-PT) ternary system were synthesized using a modified two-step columbite precursor method which can effectively suppress the pyrochlore phase. A morphotropic phase boundary (MPB) region, separating tetragonal and rhombohedral phases in the ternary systems has been determined. The electric properties of the compositions near MPB region were investigated. Dielectric response exhibits relaxor-like characteristics with broad dielectric peaks and dispersive dielectric behavior with respect to frequency and temperature. The phase diagram of the 0.45PZN-(0.55-y)PYN-yPT pseudo-binary system in the composition range of 0.15<0.35 was established based on dielectric measurements. The optimal properties were achieved in the MPB composition of 0.52PZN-0.21PYN-0.27PT with piezoelectric coefficient d(33), dielectric permittivity epsilon', planar electromechanical coupling k(p), dielectric loss tan delta, coercive field E-c, remnant polarization P-r and T-c being of 558 pC/N, 2065, 62%, 0.2%, 19.88 kV/cm, 31.44 mu C/cm(2) and 259.5 degrees C, respectively, showing potential usage in high-temperature electromechanical applications. (c) 2013 Elsevier Ltd. All rights reserved.
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