期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 32, 期 2, 页码 465-470出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2011.09.021
关键词
Sintering; Composites; Grain size; Dielectric properties
资金
- Research Grants Council of the Hong Kong Special Administrative Region, China [411807]
A full range of CaCu3Ti4O12-HfO2 (CCTO-HfO2) composites were prepared by sintering mixtures of the two components at 1000 degrees C for 10 h. X-ray diffraction studies confirmed the two-phase nature of the composites. The evolution of the microstructure in the composites, in particular, the size distribution of CCTO grains, was examined by scanning electron microscopy. The studies showed that, as more HfO2 was added, the abnormal grain growth of CCTO and coarsening of the microstructure were gradually suppressed. As a result, the average CCTO grain size was reduced from 50 to 1 mu m. The measured dielectric constants agree well with the values calculated from Lichtenecker's logarithmic law, using only the dielectric constants of pure CCTO and HfO2 as two end points. The agreement suggests to us that the dielectric constant of CCTO is dominated by domain boundaries within the grains rather than by grain boundaries between the grains. (C) 2011 Elsevier Ltd. All rights reserved.
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