4.7 Article

Sintering and crystallisation of 45S5 Bioglass® powder

期刊

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 29, 期 16, 页码 3299-3306

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2009.06.035

关键词

Sintering; Microstructure-final; Thermal properties; Structural applications; Bioglass (R)

资金

  1. EU [MEIF-CT-2005-024248]

向作者/读者索取更多资源

The sintering process of 45S5 Bioglass (R) powder (mean particle size < 5 mu m) was investigated by using different thermal analysis methods. Heating microscopy and conventional dilatometry techniques showed that bioactive glass sinters in two major steps: a short stage in the temperature range 500-600 degrees C and a longer stage in the range 850-1100 degrees C. The optimal sintering temperature and time were found to be 1050 degrees C and 140 min, respectively. Differential thermal analysis (DTA) showed that Bioglass (R) crystallises at temperatures between 600 and 750 degrees C. The characteristic crystalline phases were identified by Fourier Transformed Infrared Spectroscopy (FTIR), Transmission Electron Microscopy (TEM) and X-Ray Diffraction (XRD). The crystallisation kinetics was studied by DTA, using a non-isothermal method. The Kissinger plot for Bioglass (R) powder heated at different heating rates between 5 and 30 degrees C/min yielded an activation energy of 316 kJ/mol. The average value of Avrami parameter determined using the Augis-Bennett method was 0.95 +/- 0.10, confirming a surface crystallisation mechanism. After sintering at 1050 degrees C for 140 min, the main crystalline phase was found to be Na2Ca2Si3O9. The results of this work are useful for the design of the sintering/crystallisation heat treatment of Bioglass (R) powder which is used for fabricating tissue engineering scaffolds with varying degree of bioactivity. (C) 2009 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

4D Biofabrication of T-Shaped Vascular Bifurcation

Waseem Kitana, Indra Apsite, Jonas Hazur, Aldo R. Boccaccini, Leonid Ionov

Summary: This study reports a 4D biofabrication-based concept for the fabrication of a T-shaped vascular bifurcation using 3D printed shape-changing layers. The tubular structures with various diameters were formed by controlling the parameters precisely. The fabricated T-junction showed minimal leakages and supported excellent cell growth. This approach has the potential to fabricate fully automatic self-actuated vascular bifurcations.

ADVANCED MATERIALS TECHNOLOGIES (2023)

Review Materials Science, Multidisciplinary

Progress on Electrospun Composite Fibers Incorporating Bioactive Glass: An Overview

Farnaz Ghorbani, Theresa Reiter, Liliana Liverani, Dirk W. Schubert, Aldo R. Boccaccini, Judith A. Roether

Summary: Electrospinning is a promising method for designing fibrous tissue engineering scaffolds for hard and soft tissues. Incorporating bioactive cues, such as bioactive glass (BG), into electrospun biopolymer fibers has shown potential in improving fiber properties and enhancing biological performance. This article provides a comprehensive overview of BG-containing electrospun polymer composite fibers and discusses their effects on mechanical properties, biological response, and applications in bone regeneration, wound healing, and drug delivery. The study highlights essential aspects for future translational research in tissue engineering using BG-polymer composite fibers.

ADVANCED ENGINEERING MATERIALS (2023)

Article Engineering, Biomedical

Time-dependent hyper-viscoelastic parameter identification of human articular cartilage and substitute materials

A. Weizel, T. Distler, R. Detsch, A. R. Boccaccini, H. Seitz, S. Budday

Summary: Numerical simulations using appropriate material models and parameters are valuable for understanding the effects of mechanical stimulation on hydrogels for cartilage replacement. In this study, hyperviscoelastic material parameters for human articular cartilage and two replacement materials were identified using COMSOL Multiphysics (R) v. 5.6. The results revealed that ADA-GEL and ChondroFiller(liquid) exhibit faster stress relaxation and lower relaxation time constants compared to cartilage. Additionally, ADA-GEL and ChondroFiller(liquid) have a predominant elastic response, while cartilage has a predominant viscoelastic response.

JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS (2023)

Letter Materials Science, Multidisciplinary

Flexural strength of biopolymer coated bioactive glass (45S5) sintered struts for bone tissue engineering applications

Qaisar Nawaz, Thomas Fiedler, Jonas Biggemann, Tobias Fey, Aldo R. Boccaccini

Summary: In order to improve the mechanical properties of 45S5 bioactive glass struts, the study investigates the fabrication of struts using mold casting and sintering, followed by coating with gelatine and polycaprolactone (PCL). The results show an improvement in flexural strength of the struts after coating with PCL.

MATERIALS LETTERS (2023)

Article Materials Science, Multidisciplinary

Development and Investigation of Mesoporous Bioactive Glass/Zein Coatings Electrodeposited on Titanium Alloy for Biomedical Applications

F. Maciag, T. Moskalewicz, K. Cholewa-Kowalska, Z. Hadzhieva, M. Dziadek, A. Lukaszczyk, A. R. Boccaccini

Summary: The objective of this study was to develop cathodic electrophoretic deposition (EPD) to obtain composite coatings of mesoporous sol-gel glass (MSGG) particles embedded in a zein matrix on Ti-13Nb-13Zr substrates. The EPD process successfully produced uniform coatings with open porosity and good adhesion to the substrates. The coated substrates exhibited improved resistance to electrochemical corrosion, as well as moderate hydrophilicity and roughness. The composite coatings also showed enhanced antibacterial properties and the ability to form hydroxyapatite.

METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE (2023)

Article Nanoscience & Nanotechnology

A 3D-Printed Wound-Healing Material Composed of Alginate Dialdehyde-Gelatin Incorporating Astaxanthin and Borate Bioactive Glass Microparticles

Mahshid Monavari, Shahin Homaeigohar, Rucha Medhekar, Qaisar Nawaz, Mehran Monavari, Kai Zheng, Aldo R. Boccaccini

Summary: In this study, a wound dressing composed of an alginate dialdehyde-gelatin (ADA-GEL) hydrogel incorporated by astaxanthin (ASX) and 70B borate bioactive glass (BBG) microparticles was developed through 3D printing. The composite hydrogel construct, stiffened by ASX and BBG particles, showed prolonged degradation and steady release of ASX, promoting cell adhesion, proliferation, and migration for faster wound healing.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Biochemistry & Molecular Biology

IVM Advances for Early Antral Follicle-Enclosed Oocytes Coupling Reproductive Tissue Engineering to Inductive Influences of Human Chorionic Gonadotropin and Ovarian Surface Epithelium Coculture

Alessia Peserico, Chiara Di Berardino, Giulia Capacchietti, ChiaraCamerano Spelta Rapini, Liliana Liverani, Aldo Roberto Boccaccini, Valentina Russo, Annunziata Mauro, Barbara Barboni

Summary: Comparing with the validated cumulus-oocyte complex (COC) protocol, a three-dimensional (3D) scaffold-mediated follicle-enclosed oocytes (FEO) system was found to optimize in vitro maturation (IVM) for ovine early antral (EA)-derived oocytes. By combining hCG stimulation with ovarian surface epithelium (OSE) cells coculture exclusively on the FEO system, the maturation rate and parthenogenetic activation of EA-derived oocytes were significantly improved. The paracrine factors released specifically from OSE enhanced the hCG-triggering of oocyte maturation mechanisms by acting through the mural compartment, stimulating the EGFR signaling.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2023)

Review Materials Science, Multidisciplinary

Biomaterial strategies to combat implant infections: new perspectives to old challenges

Annabel Braem, Nur Hidayatul Nazirah Kamarudin, Nitu Bhaskar, Zoya Hadzhieva, Andrea Mele, Jeremy Soulie, Denver P. Linklater, Linda Bonilla-Gameros, Aldo R. Boccaccini, Ipsita Roy, Christophe Drouet, Elena P. Ivanova, Diego Mantovani, Bikramjit Basu

Summary: Peri-implant infection is a significant challenge in the clinical field. Researchers are developing biomaterial and bioengineering-based antimicrobial strategies to tackle this issue. However, the development of these approaches is hindered by challenges like biocompatibility concerns, reduced antimicrobial effectiveness, long-term stability issues, and antibiotic resistance development. This review provides insights into current state-of-the-art biomaterial-based antimicrobial approaches and highlights the importance of translational research strategies and regulatory frameworks for clinical implementation. The integration of computational tools and experimental databases using artificial intelligence (AI) is proposed as a vision to accelerate the development of next-generation biomaterial-based antimicrobial strategies.

INTERNATIONAL MATERIALS REVIEWS (2023)

Review Engineering, Biomedical

Aligned Ice Templated Biomaterial Strategies for the Musculoskeletal System

Florencia Diaz, Nicholas Forsyth, Aldo R. Boccaccini

Summary: This review evaluates the work done in the last decade toward the production of aligned pore structures by AIT, focusing on optimizing the biomechanical properties by modifying the pore structure, categorizing by material type and application. The review also discusses related topics including growth factor incorporation, drug delivery applications, and immune system response studies.

ADVANCED HEALTHCARE MATERIALS (2023)

Article Polymer Science

Comparison between the Astaxanthin Release Profile of Mesoporous Bioactive Glass Nanoparticles (MBGNs) and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)/MBGN Composite Microspheres

Arturo E. Aguilar-Rabiela, Shahin Homaeigohar, Eduin I. Gonzalez-Castillo, Mirna L. Sanchez, Aldo R. Boccaccini

Summary: Composite biomaterials combining different biomaterials with unequal release rates have shown potential for drug delivery applications. In this study, mesoporous bioactive glass nanoparticles (MBGN) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) microspheres loaded with Astaxanthin (ASX) were synthesized and compared in terms of ASX release kinetic, ASX entrapment efficiency, and cell viability. The release behavior could be fine-tuned by adjusting the MBGN content in the composite particles, and the composite microspheres exhibited a more prolonged release profile with sustained cytocompatibility.

POLYMERS (2023)

Article Materials Science, Biomaterials

3D-Printed Multifunctional Hydrogels with Phytotherapeutic Properties: Development of Essential Oil-Incorporated ALG-XAN Hydrogels for Wound Healing Applications

Irem Unalan, Stefan Schruefer, Dirk W. Schubert, Aldo R. Boccaccini

Summary: This study aimed to develop 3D-printed hydrogels as multifunctional wound dressings containing phytotherapeutic agents. Results showed that blending xanthan gum (XAN) overcame the challenges associated with sodium alginate (ALG) in terms of printability and shape fidelity. Clove essential oil (CLV) was successfully incorporated into the 3D-printed hydrogels, exhibiting long-term release and enhanced antioxidant and antibacterial activity. Additionally, CLV showed potential anti-inflammatory effects and had no toxic effect on NHDF cells. Overall, this study highlights the potential benefits of incorporating natural phytotherapeutics into 3D-printed hydrogels for wound healing.

ACS BIOMATERIALS SCIENCE & ENGINEERING (2023)

Article Biochemistry & Molecular Biology

Endotenon-Derived Type II Tendon Stem Cells Have Enhanced Proliferative and Tenogenic Potential

Marta Clerici, Vera Citro, Amy L. Byrne, Tina P. Dale, Aldo R. Boccaccini, Giovanna Della Porta, Nicola Maffulli, Nicholas R. Forsyth

Summary: By comparing and contrasting different tendon cell populations, this study found that type II tendon stem cells (TSCs) are the most promising population for expansion due to their enhanced proliferative potential, multipotency, and maintenance of a tendon-specific profile. Furthermore, physoxia promotes enhanced proliferation and maintenance of a tenogenic profile in all tendon-derived cell populations.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2023)

Article Nanoscience & Nanotechnology

Biosynthesis of Zinc Oxide Nanoparticles on l-Carnosine Biofunctionalized Polyacrylonitrile Nanofibers; a Biomimetic Wound Healing Material

Shahin Homaeigohar, Mhd Adel Assad, Amir Hossein Azari, Farnaz Ghorbani, Chloe Rodgers, Matthew J. Dalby, Kai Zheng, Rongyao Xu, Mady Elbahri, Aldo. R. Boccaccini

Summary: The biohybrid nanofibers developed in this study can stimulate the adhesion and proliferation of fibroblast and endothelial cells, showing potential for promoting wound healing and antibacterial activity.

ACS APPLIED BIO MATERIALS (2023)

Article Materials Science, Ceramics

Cotton-wool-like borosilicate glass fibers for tissue regeneration: Preparation, characterization and in vitro bioactivity

Susanta Sengupta, Liliana Liverani, Dusan Galusek, Aldo R. Boccaccini

Summary: Borosilicate glass fibers fabricated by electrospinning in combination with sol-gel processing showed good bioactivity and non-cytotoxic nature in simulated body fluid.

OPEN CERAMICS (2023)

Article Materials Science, Ceramics

Comparison of microstructure, sintering behavior, and biological response of sol-gel and melt-derived 13-93 bioactive glass scaffolds

Q. Nawaz, A. de Pablos-Martin, A. T. Contreras Jaimes, F. Scheffler, T. Wagner, D. S. Brauer, A. R. Boccaccini

Summary: This study compares the properties of scaffolds prepared using sol-gel and melt-derived powders. The microstructure, shrinkage behavior, bioactivity, and cell compatibility of the scaffolds were evaluated. The findings show that sol-gel derived 13-93 scaffolds exhibit similar characteristics to melt-derived scaffolds, and the sol-gel approach offers advantages such as low temperature processing and high purity for fabricating high-quality scaffolds.

OPEN CERAMICS (2023)

Article Materials Science, Ceramics

Phase equilibria in the ZrO2-GdO1.5-TaO2.5 system at 1500 °C

Dan Zhao, Yi Feng, Zhipeng Pi, Fan Zhang

Summary: Phase equilibria in the ZrO2-GdO1.5-TaO2.5 (ZGTO) system were experimentally investigated, and the differences between ZGTO and the existing ZrO2-YO1.5-TaO2.5 (ZYTO) were discussed. The study is useful for thermodynamic assessment of ZGTO and can guide the design of novel thermal barrier coatings materials.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Alumina precipitate along dislocations in rutile single crystal of diffusion couple during cooling from 1200° to 1400°C

Yutaka Ohya, Wingki Mey Hendra, Chika Takai-Yamashita, Takayuki Ban

Summary: Diffusion couples of rutile and corundum single crystals were prepared and examined to study the solid solution and precipitation of corundum in rutile during cooling. Different precipitation forms of corundum were observed under different cooling conditions.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Water-enhanced plasticity of calcium fluoride

Jiaming Zhan, Yunfa Guo, Hao Wang

Summary: This study systematically investigates the mechanical behaviors of calcium fluoride in humid environments. The effects of water on the deformation and plastic enhancement of CaF2 under indentation are explored through microindentation experiments, atomic simulations, and Raman spectroscopy measurement.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Microwave tunability in tin substituted barium titanate

Hangfeng Zhang, Henry Giddens, Theo Graves Saunders, Matteo Palma, Isaac Abrahams, Haixue Yan, Yang Hao

Summary: The relationship between low and high frequency tunabilities in tin substituted barium titanate ceramics was investigated. It was found that there are differences in tunabilities at different frequencies due to the different activities of larger ferroelectric domains and polar nanoclusters.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Boosting energy storage performance in negative temperature coefficient linear-like dielectrics via composite modulation in the superparaelectric state

Kaibiao Xi, Jiacheng Liu, Beibei Song, Huarong Cheng, Yihao Li, Xiaole Yu, Mupeng Zheng, Mankang Zhu, Yudong Hou

Summary: Composite modulation in the superparaelectric state of the BTBZ-CT system is proposed as an effective strategy to achieve both NTCC and excellent energy storage performance in dielectric ceramics. The addition of BZ and CT to BT ferroelectrics can move the SPE state to the normal use temperature zone, resulting in enhanced NTCC characteristics and energy storage performance. Furthermore, intentional precipitation of CT at grain boundaries can refine the grain size, increase the bandgap, and strengthen the local electric field distribution, thereby enhancing the breakdown electric field.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Sinterability of sodium bismuth titanate-based electroceramics at low temperatures

Hamed Salimkhani, Lovro Fulanovic, Till Froemling

Summary: The demand for robust multilayer ceramic capacitors with high-temperature and high-power capabilities is increasing rapidly. However, cost-effective production is a challenge. This study investigates the use of Na0.5Bi0.5TiO3-based materials as promising lead-free options. By adding sintering aids, the sintering temperature of Na0.5Bi0.5TiO3-BaTiO3-CaZrO3-BiAlO3 solid solutions was successfully reduced to 975 degrees C, suitable for co-sintering with Cu electrodes without adverse effects on capacitor properties.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Residual stress and interface debonding behavior in Si3N4w reinforced SiCN composites prepared by the PIP process: A case study

Mingxing Li, Ran Mo, Zeshui Xu, Jie Zhou, Conglin Zhang, Xuefeng Cui, Fang Ye, Laifei Cheng, Ralf Riedel

Summary: Polymer infiltration and pyrolysis is an effective method for preparing ceramic matrix composites. The transformation of polymer to ceramic during the process affects the residual stress and interface behavior in the composites.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Porous spheres enabling excellent high-temperature abradability and long lifetime for abradable seal coating

Yan Kang, Lin Chen, Chang-Jiu Li, Guan-Jun Yang

Summary: A novel abradable seal coating with low hardness and high bonding strength was successfully designed and prepared. This coating has significantly higher abradability and erosion resistance compared to metal-based coatings, and can retain excellent abradability and have a long lifetime during service.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Influence of raw material purity on microstructure and properties of calcia refractory

Qingzhong Song, Xiangdong Zha, Ming Gao, Yingche Ma

Summary: This study analyzes the influence of calcia refractory purity on the properties of calcia crucibles. Higher purity calcia results in well-developed grains and improved hydration resistance, leading to better high-temperature strength and thermal shock resistance. In contrast, lower purity calcia crucibles exhibit inferior properties. Therefore, high-purity calcia is considered a potential refractory for manufacturing oxide crucibles.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Ultra-low thermal conductivity and hydrophobic properties of high entropy β-type quaternary pyrosilicate

Sehreish Abrar, Faisal Nazeer, Zhuang Ma, Ling Liu, Abdul Malik, Mustafa Kamal, Abdullah G. Al-Sehemi

Summary: To raise the operating temperature of Si-based ceramic matrix composites (CMCs), researchers have applied thermal/environmental barrier coating (T/EBCs) materials, typically rare earth silicates. However, the high thermal conductivity and the mismatch of thermal expansion have been major challenges in developing new materials that can offer thermal insulation and environmental protection to CMCs. In this study, entropy engineering was used to create a multicomponent equi-atomic single-phase pyro silicate with extremely low thermal conductivity and enhanced water vapor corrosion resistance. The research findings show the potential of high entropy disilicates in achieving ultra-low thermal conductivity and low weight loss in corrosive environments.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Heterogeneous oxidation behavior and kinetic mechanisms of SiBCN ceramic with structure of MA-SiBCN coated by PDCs-SiBCN

Zi-bo Niu, Daxin Li, Dechang Jia, Zhihua Yang, Kunpeng Lin, Paolo Colombo, Ralf Riedel, Yu Zhou

Summary: In this study, SiBCN ceramics with a special structure were prepared to improve the oxidation resistance. The effect of the structure on oxidation behavior and kinetics was investigated, revealing that the special structure can effectively inhibit heterogeneous oxidation and enhance the oxide layer composition.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Low temperature densification and dielectric characterization of CeO2 ceramics

Melike Donmez, Metehan Erdogan, Cihangir Duran

Summary: The limited densification of CeO2 ceramics was improved by using an anorthite-based glass, resulting in high dielectric constant and quality factor with minimum dielectric loss. The CeO2-(anorthite-based) glass ceramic showed promising results in terms of low temperature densification and microwave properties.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

High speed impact and solid-state deposition of alumina particles: A molecular dynamics study

S. Rahmati, R. G. A. Veiga, J. Mostaghimi, T. Coyle, A. Dolatabadi

Summary: This study provides an atomic-scale description of the high-velocity impact of alpha-Al2O3 particles onto an alpha-Al2O3 substrate during Aerosol Deposition (AD). The results suggest that the crystal orientation plays a crucial role in both plasticity and damage of the nanoparticles. Impact velocity has a direct correlation with plasticity and fragmentation, but adhesion efficiency has only a marginal increase. The crucial element lies in the substrate's surface alterations caused by the fragments left on the substrate after impact.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Long-term ablation mechanisms of the YB4-Al2O3-Si3N4 modified Cf/ HfC-SiC composites at 2600 °C

Bo-Wen Chen, Yan-Mei Kan, De-Wei Ni, Chun-Jing Liao, Hong-Da Wang, Yu-Sheng Ding, Shao-Ming Dong

Summary: This study characterized the long-term and repeated ablation properties of modified Cf/HfC-SiC composites with YB4-Al2O3-Si3N4 under an air plasma torch. The structural stability and viscosity of the oxide layer were found to affect the ablation resistance of the composites. By forming nano c-HfO2 grains and high-viscosity Al-Si-Y-O glassy phase, the structural stability of the oxide layer was improved, resulting in enhanced ablation resistance. However, the oxidation of Si3N4 led to the formation of NO, NO2, and excessive SiO2 glassy phase, which resulted in a porous structure and reduced the viscosity of the oxide layer. Therefore, the addition of Si3N4 decreased the ablation resistance of the composites.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Structure characters, and thermal evolution of electrical and elastic behaviors in xBi(Ni1/2Hf1/2)O3-(1-x)PbTiO3 solid solutions with a tetragonal-pseudocubic phase boundary

Yongxing Wei, Huawei Zhang, Siyuan Dong, Changqing Jin, Chenxing Bai, Junle Dai, Zengzhe Xi, Zhonghua Dai, Zengyun Jian, Li Jin

Summary: In this study, solid solutions of xBi(Ni1/2Hf1/2)O-3-(1 - x)PbTiO3 (xBNH-PT) were synthesized to investigate their phase boundary behaviors and physical properties. The presence of a tetragonal-pseudocubic phase boundary and a spontaneous ferroelectric-relaxor transition at specific compositions were confirmed. The introduction of a tetragonal-pseudocubic phase boundary improved the piezoelectric properties and suppressed the spontaneous ferroelectric-relaxor transition.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2024)