Article
Materials Science, Ceramics
Premysl Stastny, Jana Smieskova, Martin Trunec
Summary: This study describes a method for the production of multilayer tapes using the aqueous epoxy-based gel-tape co-casting of ceramic suspensions. It demonstrates the applicability of this method for the preparation of high-quality fine powder ceramic stacks.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Steven Pirou, Qingjie Wang, Peyman Khajavi, Xanthi Georgolamprou, Sandrine Ricote, Ming Chen, Ragnar Kiebach
Summary: Proton-conducting ceramics have significant potential in the hydrogen market. Symmetrical cells based on barium zirconate/cerate materials demonstrate excellent electrochemical performance and stability for H2 extraction applications.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Review
Biochemistry & Molecular Biology
Andreea Laura Chibac-Scutaru, Sergiu Coseri
Summary: Fuel cells are eco-friendly appliances that convert chemical energy into electricity efficiently. The proton exchange membrane, such as NAFION, plays a crucial role in these devices. However, due to the limitations of NAFION, researchers are now focusing on developing new generation membranes based on natural materials like cellulose. Therefore, a review of recent studies on using cellulose as a material for proton exchange membranes in fuel cells would be highly appreciated by the scientific community.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Review
Chemistry, Physical
Ning Wang, Chunmei Tang, Lei Du, Ruijie Zhu, Lixin Xing, Zhongqian Song, Baoyin Yuan, Lei Zhao, Yoshitaka Aoki, Siyu Ye
Summary: This review provides a comprehensive overview of oxide materials for PCFC cathodes, focusing on their proton uptake, conduction mechanisms, and structure-property relationships. The importance of designing cathode materials with tailorable H+, O2-, and e(-) conductivities for improving PCFC performance is emphasized. The electrochemical performance of these cathode materials in PCFCs is discussed, and the gaps in performance among PCFCs with different types of cathode materials are defined. Perspectives on the development of high-performance PCFCs are also proposed.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Feihong Wang, Shanshan Hao, Binbin Dong, Nianwang Ke, Noor Zamin Khan, Luyuan Hao, Liangjun Yin, Xin Xu, Simeon Agathopoulos
Summary: This study reports on the preparation of ceramic foam membranes with 3D interconnected pores and high PM filtration efficiency, achieved through direct foaming and gel-tape casting. The produced MSCMs contain large and small functional pores for efficient filtration of different particulate matters, with adjustable porosity and bending strength.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Polymer Science
Ekaterina Yu. Safronova, Daria Yu. Voropaeva, Anna A. Lysova, Oleg V. Korchagin, Vera A. Bogdanovskaya, Andrey B. Yaroslavtsev
Summary: By changing the preparation and pretreatment conditions, the properties of Nafion membranes can be optimized. In this study, a Nafion-NMP membrane with higher conductivity and comparable hydrogen permeability was obtained by casting from a Nafion dispersion in N-methyl-2-pyrrolidone. The increase in conductivity is attributed to the optimization of the Nafion-NMP microstructure, which improves the connectivity of the pores and channels system. This leads to an increased capacity of the membrane electrode assembly compared to a commercial Nafion (R) 212 membrane.
Article
Engineering, Chemical
Jietao Wang, Tong Liu, Chunlei Lu, Chengjie Gong, Mengyu Miao, Zhaoling Wei, Yao Wang
Summary: In this study, low-cost, hierarchically oriented bauxite membranes were prepared and showed efficient oil-in-water emulsion separation. The membrane exhibited good separation performance, membrane fouling can be mostly recovered, and the degradation and regeneration mechanism was proposed.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Thermodynamics
Kyle Ferguson, Alexis Dubois, Kevin Albrecht, Robert J. Braun
Summary: The technology landscape in distributed generation is evolving in response to demand for efficient, low-emission, and low-cost power generation. Recent advancements in protonic ceramic fuel cells (PCFCs) offer potential for higher electric efficiencies in stationary power generation systems. The study explores system configurations and performance characteristics of PCFC-based systems for power generation, highlighting the fuel utilization capability and potential for high efficiencies without hybridization.
ENERGY CONVERSION AND MANAGEMENT
(2021)
Review
Nanoscience & Nanotechnology
Aroosa Javed, Paulina Palafox Gonzalez, Venkataraman Thangadurai
Summary: In the 21st century, proton exchange membrane fuel cells (PEMFCs) are a promising source of power generation due to their high efficiency and eco-friendly design. However, the critical component of PEMFCs, proton exchange membranes (PEMs), have drawbacks such as high cost and reduction in proton conductivity at high temperatures. Recent research has focused on modifying PEMs through composite materials to improve their stability and proton conductivity. This article discusses the current developments in membranes for PEMFCs, with emphasis on hybrid membranes based on Nafion, PBI, and other nonfluorinated proton conducting membranes.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Zuzhi Huang, Yang Yang, Haipeng Lv, Caixia Shi, Yihan Ling, Juan Zhou, Shaorong Wang
Summary: One key problem of protonic ceramic fuel cells (PCFCs) is the insufficient mechanical strength of the anode support. This study proposes a design using a nonproton-conducting cermet to enhance the mechanical strength of PCFCs. The research shows that the integrated single cells exhibit high peak power density and satisfactory long-term stability at high temperatures.
JOURNAL OF POWER SOURCES
(2022)
Article
Materials Science, Ceramics
Angelo Oliveira Silva, Dachamir Hotza, Ricardo Machado, Kurosch Rezwan, Michaela Wilhelm
Summary: An asymmetric alumina microfiltration membrane with high performance was prepared by combining freeze and tape casting techniques followed by two sintering steps. The morphology influences were investigated for different solid loadings, additives content and the assembled layer membrane structures. The assembled ceramic membrane had an average pore size between 30 and 50 m, suitable for microfiltration separation with porosity in the range of 26-50% and water flux of 11-32 m(3) m(-2) h(-1) bar(-1).
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Ceramics
S. A. N. Franca Junior, W. Acchar, S. L. A. Dantas, P. H. Chiberio, H. P. A. Alves, M. R. D. Bomio, F. V. Motta, F. Bohn, A. Ferreira, F. Vaz, M. A. Correa
Summary: We conducted a comprehensive investigation on the high-frequency dielectric properties of (ZrO2)100-x(BaTiO3)x heterostructures. By adjusting the content of BaTiO3, we could modify the dielectric constant of the resulting ceramic sheets. Our results demonstrated successful fabrication of heterostructured ceramic sheets and the ability to tailor the electric, structural, and dielectric properties of both ZrO2 and BaTiO3 materials. Furthermore, the evolution of the dielectric constant could be manipulated according to specific technological applications.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Yu He, Yunxiang Cai, Ling Zhang, Kaige Liu, Gang Liu, Bingxi Xiang, Jianpang Zhai, Ling Bing Kong, Tianshu Zhang, Yin Liu
Summary: This study successfully fabricated Al2O3 transparent ceramics through a one-step ball milling process, achieving a thickness of approximately 0.1 mm with uniform texture and no distortion. Dry pressing was found to improve the densification and promote grain growth of bilayer tapes.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Yuan Sun, Hang Xie, Linjing Liu, Qiangwei Kou, Shantao Zhang, Bin Yang, Wenwu Cao, Yunfei Chang
Summary: By integrating crystallographic texture and second-phase toughening strategies, the fracture resistance and mechanical reliability of alumina multilayer composites have been effectively improved. The addition of ZrO2 significantly enhances the mechanical performance of the composites and reduces sensitivity to flaw size. The enhanced mechanical properties are mainly attributed to higher compressive stresses, more crack bifurcations, and longer crack deflection paths within the textured layers.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Yu Ma, Jianbing Huang, Biao He
Summary: Anode-supported thin-film BaZr0.8Y0.2O3-? (BZY) electrolyte protonic ceramic fuel cells (PCFCs) show great potential for commercial application with excellent performance and durability at 500-600?C. A scalable process was developed to fabricate BZY electrolyte matrix with porous/dense bilayer structure, achieving a maximum power density of 170 mW cm-2 at 600?C with optimal NiO impregnation amount of 20 wt%.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
M. Stange, C. Denonville, Y. Larring, A. Brevet, A. Montani, O. Sicardy, J. Mougin, P. O. Larsson
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2017)
Article
Chemistry, Physical
M. Stange, E. Stefan, C. Denonville, Y. Larring, P. M. Rorvik, R. Haugsrud
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2017)
Article
Materials Science, Multidisciplinary
Elena Stefan, Marit Stange, Christelle Denonville, Yngve Larring, Nicolas Hildenbrand, Truls Norby, Reidar Haugsrud
JOURNAL OF MATERIALS SCIENCE
(2017)
Article
Energy & Fuels
Vincent Thoreton, Ove Darell, Aud I. Spjelkavik, Martin Fleissner Sunding, Tommy Mokkelbost, Mehdi Pishahang, Kjell Wiik, Yngve Larring
Article
Energy & Fuels
Vincent Thoreton, Mehdi Pishahang, Tommy Mokkelbost, Kjell Wiik, Yngve Larring
Article
Energy & Fuels
Schalk Cloete, Antonio Giuffrida, Matteo Romano, Paolo Chiesa, Mehdi Pishahang, Yngve Larring
Article
Engineering, Chemical
Wen Xing, Marie-Laure Fontaine, Zuoan Li, Jonathan M. Polfus, Yngve Larring, Christelle Denonville, Emmanuel Nonnet, Adam Stevenson, Partow P. Henriksen, Rune Bredesen
JOURNAL OF MEMBRANE SCIENCE
(2018)
Article
Thermodynamics
Mehdi Pishahang, Yngve Larring, Juan Adanez, Pilar Gayan, Martin Sunding
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2018)
Article
Thermodynamics
Yngve Larring, Mehdi Pishahang, Julian Tolchard, Anna M. Lind, Martin F. Sunding, Ruth E. Stensrod, Marijke Jacobs, Frans Snijkers, Tjalling van der Kolk, Knuth Albertsen
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2020)
Article
Thermodynamics
Lei Liu, Zhenshan Li, Zuoan Li, Yngve Larring, Ye Li, Ningsheng Cai
Summary: The study investigated the redox kinetics of a new perovskite oxygen carrier and found that its oxidation rate is much faster than that of natural manganese ore and ilmenite, with only a fast initial stage observed. The effects of temperature, O2 concentrations, and reducing gas type were explored using MFB-TGA method, providing important insights for reactor design in CLC applications.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Review
Materials Science, Multidisciplinary
Elena Stefan, Belma Talic, Yngve Larring, Andrea Gruber, Thijs A. Peters
Summary: The paper discusses the potential materials challenges of gas turbines fueled with hydrogen, provides an updated overview of the most promising alloys and coatings for this application, and highlights topics requiring further research and development.
INTERNATIONAL MATERIALS REVIEWS
(2022)
Article
Materials Science, Multidisciplinary
Einar Vollestad, Vegar Oygarden, Joachim Seland Graff, Martin Fleissner Sunding, John D. Pietras, Jonathan M. Polfus, Marie-Laure Fontaine
Summary: This study thoroughly investigates the impact of MnO2 as a co-dopant on the sinterability, thermal expansion, crystal structure, and ionic conductivity of ScSZ electrolytes. The results show that the addition of 2 mol% MnO2 significantly enhances the oxide ion conductivity, lowers the peak sintering temperature, and stabilizes the cubic structure. It is also found that manganese predominantly enters the structure as Mn2+ and higher valence states are present at the surface and grain boundaries.
Article
Chemistry, Applied
Manuel Bianco, Markus Linder, Yngve Larring, Fabio Greco, Jan Van Herle
SOLID OXIDE FUEL CELL LIFETIME AND RELIABILITY: CRITICAL CHALLENGES IN FUEL CELLS
(2017)
Proceedings Paper
Green & Sustainable Science & Technology
Stefan Penthor, Tobias Mattisson, Juan Adanez, Stephane Bertolin, Enrica Masi, Yngve Larring, Oyvind Langorgen, Jochen Stroehle, Frans Snijkers, Lieve Geerts, Knuth Albertsen, Gareth Williams, Otmar Bertsch, Olivier Authier, Ytalo Davila, Mahdi Yazdanpanah, Tobias Proell, Anders Lyngfelt, Hermann Hofbauer
13TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, GHGT-13
(2017)
Proceedings Paper
Green & Sustainable Science & Technology
John Morud, Andrew Tobiesen, Schalk Cloete, Yngve Larring, Actor Chikukwa, Mehdi Pishahang
13TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, GHGT-13
(2017)
Article
Materials Science, Ceramics
Dan Zhao, Yi Feng, Zhipeng Pi, Fan Zhang
Summary: Phase equilibria in the ZrO2-GdO1.5-TaO2.5 (ZGTO) system were experimentally investigated, and the differences between ZGTO and the existing ZrO2-YO1.5-TaO2.5 (ZYTO) were discussed. The study is useful for thermodynamic assessment of ZGTO and can guide the design of novel thermal barrier coatings materials.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yutaka Ohya, Wingki Mey Hendra, Chika Takai-Yamashita, Takayuki Ban
Summary: Diffusion couples of rutile and corundum single crystals were prepared and examined to study the solid solution and precipitation of corundum in rutile during cooling. Different precipitation forms of corundum were observed under different cooling conditions.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Jiaming Zhan, Yunfa Guo, Hao Wang
Summary: This study systematically investigates the mechanical behaviors of calcium fluoride in humid environments. The effects of water on the deformation and plastic enhancement of CaF2 under indentation are explored through microindentation experiments, atomic simulations, and Raman spectroscopy measurement.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Hangfeng Zhang, Henry Giddens, Theo Graves Saunders, Matteo Palma, Isaac Abrahams, Haixue Yan, Yang Hao
Summary: The relationship between low and high frequency tunabilities in tin substituted barium titanate ceramics was investigated. It was found that there are differences in tunabilities at different frequencies due to the different activities of larger ferroelectric domains and polar nanoclusters.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Kaibiao Xi, Jiacheng Liu, Beibei Song, Huarong Cheng, Yihao Li, Xiaole Yu, Mupeng Zheng, Mankang Zhu, Yudong Hou
Summary: Composite modulation in the superparaelectric state of the BTBZ-CT system is proposed as an effective strategy to achieve both NTCC and excellent energy storage performance in dielectric ceramics. The addition of BZ and CT to BT ferroelectrics can move the SPE state to the normal use temperature zone, resulting in enhanced NTCC characteristics and energy storage performance. Furthermore, intentional precipitation of CT at grain boundaries can refine the grain size, increase the bandgap, and strengthen the local electric field distribution, thereby enhancing the breakdown electric field.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Hamed Salimkhani, Lovro Fulanovic, Till Froemling
Summary: The demand for robust multilayer ceramic capacitors with high-temperature and high-power capabilities is increasing rapidly. However, cost-effective production is a challenge. This study investigates the use of Na0.5Bi0.5TiO3-based materials as promising lead-free options. By adding sintering aids, the sintering temperature of Na0.5Bi0.5TiO3-BaTiO3-CaZrO3-BiAlO3 solid solutions was successfully reduced to 975 degrees C, suitable for co-sintering with Cu electrodes without adverse effects on capacitor properties.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Mingxing Li, Ran Mo, Zeshui Xu, Jie Zhou, Conglin Zhang, Xuefeng Cui, Fang Ye, Laifei Cheng, Ralf Riedel
Summary: Polymer infiltration and pyrolysis is an effective method for preparing ceramic matrix composites. The transformation of polymer to ceramic during the process affects the residual stress and interface behavior in the composites.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yan Kang, Lin Chen, Chang-Jiu Li, Guan-Jun Yang
Summary: A novel abradable seal coating with low hardness and high bonding strength was successfully designed and prepared. This coating has significantly higher abradability and erosion resistance compared to metal-based coatings, and can retain excellent abradability and have a long lifetime during service.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Qingzhong Song, Xiangdong Zha, Ming Gao, Yingche Ma
Summary: This study analyzes the influence of calcia refractory purity on the properties of calcia crucibles. Higher purity calcia results in well-developed grains and improved hydration resistance, leading to better high-temperature strength and thermal shock resistance. In contrast, lower purity calcia crucibles exhibit inferior properties. Therefore, high-purity calcia is considered a potential refractory for manufacturing oxide crucibles.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Sehreish Abrar, Faisal Nazeer, Zhuang Ma, Ling Liu, Abdul Malik, Mustafa Kamal, Abdullah G. Al-Sehemi
Summary: To raise the operating temperature of Si-based ceramic matrix composites (CMCs), researchers have applied thermal/environmental barrier coating (T/EBCs) materials, typically rare earth silicates. However, the high thermal conductivity and the mismatch of thermal expansion have been major challenges in developing new materials that can offer thermal insulation and environmental protection to CMCs. In this study, entropy engineering was used to create a multicomponent equi-atomic single-phase pyro silicate with extremely low thermal conductivity and enhanced water vapor corrosion resistance. The research findings show the potential of high entropy disilicates in achieving ultra-low thermal conductivity and low weight loss in corrosive environments.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Zi-bo Niu, Daxin Li, Dechang Jia, Zhihua Yang, Kunpeng Lin, Paolo Colombo, Ralf Riedel, Yu Zhou
Summary: In this study, SiBCN ceramics with a special structure were prepared to improve the oxidation resistance. The effect of the structure on oxidation behavior and kinetics was investigated, revealing that the special structure can effectively inhibit heterogeneous oxidation and enhance the oxide layer composition.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Melike Donmez, Metehan Erdogan, Cihangir Duran
Summary: The limited densification of CeO2 ceramics was improved by using an anorthite-based glass, resulting in high dielectric constant and quality factor with minimum dielectric loss. The CeO2-(anorthite-based) glass ceramic showed promising results in terms of low temperature densification and microwave properties.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
S. Rahmati, R. G. A. Veiga, J. Mostaghimi, T. Coyle, A. Dolatabadi
Summary: This study provides an atomic-scale description of the high-velocity impact of alpha-Al2O3 particles onto an alpha-Al2O3 substrate during Aerosol Deposition (AD). The results suggest that the crystal orientation plays a crucial role in both plasticity and damage of the nanoparticles. Impact velocity has a direct correlation with plasticity and fragmentation, but adhesion efficiency has only a marginal increase. The crucial element lies in the substrate's surface alterations caused by the fragments left on the substrate after impact.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Bo-Wen Chen, Yan-Mei Kan, De-Wei Ni, Chun-Jing Liao, Hong-Da Wang, Yu-Sheng Ding, Shao-Ming Dong
Summary: This study characterized the long-term and repeated ablation properties of modified Cf/HfC-SiC composites with YB4-Al2O3-Si3N4 under an air plasma torch. The structural stability and viscosity of the oxide layer were found to affect the ablation resistance of the composites. By forming nano c-HfO2 grains and high-viscosity Al-Si-Y-O glassy phase, the structural stability of the oxide layer was improved, resulting in enhanced ablation resistance. However, the oxidation of Si3N4 led to the formation of NO, NO2, and excessive SiO2 glassy phase, which resulted in a porous structure and reduced the viscosity of the oxide layer. Therefore, the addition of Si3N4 decreased the ablation resistance of the composites.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yongxing Wei, Huawei Zhang, Siyuan Dong, Changqing Jin, Chenxing Bai, Junle Dai, Zengzhe Xi, Zhonghua Dai, Zengyun Jian, Li Jin
Summary: In this study, solid solutions of xBi(Ni1/2Hf1/2)O-3-(1 - x)PbTiO3 (xBNH-PT) were synthesized to investigate their phase boundary behaviors and physical properties. The presence of a tetragonal-pseudocubic phase boundary and a spontaneous ferroelectric-relaxor transition at specific compositions were confirmed. The introduction of a tetragonal-pseudocubic phase boundary improved the piezoelectric properties and suppressed the spontaneous ferroelectric-relaxor transition.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)