期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 161, 期 1, 页码 A1-A5出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.011401jes
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资金
- U.S. Department of Energy, Freedom CAR, and Vehicle Technologies Office
- U.S. Department of Energy Office of Science Laboratory [DE-AC02-06CH11357]
- UChicago Argonne, LLC.
- U.S. Department of Energy's Vehicle Technologies Program
The cathode material Li1.5Ni0.25Mn0.75O2 5 was synthesized through a solid-state reaction. In-situ high energy X-ray diffraction, STEM and electrochemical characterizations confirmed the composite nature of the material. We mainly found that the layered components belonging to the R (3) over barm and C2/m like-phases formed stepwise following the thermal decomposition and reaction of Li2CO3. Solid diffusion at high-temperature with extended calcination times cannot change the composite nature. (C) 2013 The Electrochemical Society. All rights reserved.
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