Article
Materials Science, Ceramics
Zhenlu Yu, Xingyu Qu, Aichun Dou, Yu Zhou, Mingru Su, Yunjian Liu
Summary: Li-excess cation-disordered rocksalt oxides with both cationic and anionic redox capabilities have raised challenges in large polarization and poor rate performance due to anionic evolution and poor electronic conductivity. A facile strategy of carbon coating using moderate mass ratio of carbon precursor and calcination temperature has been shown to significantly improve the electrochemical properties of Ni-based cation-disordered oxides, leading to enhanced specific capacity and rate performance. The carbon coating process increases tetrahedron height for easy Li diffusion, reduces polarization, protects cathode, retards SEI layer thickening, and enhances electronic conductivity.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Multidisciplinary
Linze Li, Zhengyan Lun, Dongchang Chen, Yuan Yue, Wei Tong, Guoying Chen, Gerbrand Ceder, Chongmin Wang
Summary: This study reveals the significant impact of fluorination on the structure and cycling performance of DRX cathodes, illustrating the mechanism of suppressing oxygen loss and improving stability. The novel rocksalt-to-spinel-like structural transformation in the cathode bulk is found to contribute positively to the cycling performance.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Xiaoxia Gou, Zhenkun Hao, Zhimeng Hao, Gaojing Yang, Zhuo Yang, Xinyue Zhang, Zhenhua Yan, Qing Zhao, Jun Chen
Summary: This review summarizes the in situ surface reconstruction strategies of lithium-rich manganese-based layered oxides (LROs). It provides an overview of LROs and discusses the surface challenges they face. Emphasis is placed on in situ self-reconstruction strategies to alleviate the performance degradation of LROs, with a focus on synthesis and characterization methods and the role they play in stabilizing the structures. Finally, prospects for precise/large scale preparations, interphase design, and in-operando characterization approaches for the commercialization of LROs are provided.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Hui Chang, Ying Li, Zi-Kui Fang, Jin-Peng Qu, Yan-Rong Zhu, Ting-Feng Yi
Summary: The study successfully prepared carbon-coated LiMn0.5Fe0.5PO4@Li0.33La0.56TiO3 nanorod composites, with LLTO coating facilitating charge transfer to improve rate performance and cycle stability.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Pallavi Thakur, Khorsed Alam, Prasenjit Sen, Tharangattu N. Narayanan
Summary: By incorporating -OH functionalities into the cathode through polysaccharide addition, the discharge capacity and cyclability of Li-O2 batteries are enhanced. This rational design route provides high capacities for the emergent Li-O2 batteries.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Biochemistry & Molecular Biology
Mihaela-Ramona Buga, Adnana Alina Spinu-Zaulet, Cosmin Giorgian Ungureanu, Raul-Augustin Mitran, Eugeniu Vasile, Mihaela Florea, Florentina Neatu
Summary: Porous silica-based materials show promise as an alternative to graphite anodes for Li-ion batteries, but face challenges such as low coulombic efficiency and irreversible capacity losses. The main strategy to address these challenges is the preparation of carbon-coated SiO2 composites, where the carbon thin layer effectively reduces interfacial impedance.
Article
Chemistry, Physical
Zhenlu Yu, He Huang, Yunjian Liu, Xingyu Qu, Yu Zhou, Aichun Dou, Mingru Su, Hong-Hui Wu, Liang Zhang, Kehua Dai, Zaiping Guo, Tao Wan, Mengyao Li, Dewei Chu
Summary: Li-excess cation-disordered oxide cathodes with high energy density have attracted attention. In this study, it was found that carbon/Al2O3 double coating and partial Al3+ substitution can enhance the capacity and cycling performance of Ni-based cation-disordered oxide cathodes. Carbon coating promotes O redox activity, while Al3+ substitution shortens the band overlap between Ni and O. Additionally, Al2O3 coating and Al3+ doping improve the cycling stability of the cathode material.
Article
Chemistry, Physical
Pengyu Chen, Wei Liu, Hao Wang, Yao Jiang, Xiaobin Niu, Liping Wang
Summary: By fine modification of the C-F bond character and using a high-voltage sulfolane electrolyte, highly reversible CFx cathodes in lithium-ion batteries can be achieved. The improved reversibility comes from the semi-ionic CFx phase, which has a superior bond length and weaker bond energy. The fluorinated graphene CF1.12 is identified as a suitable cathode material, providing an appropriate fluorine content and sufficient semi-ionic C-F bonds for rechargeable LIBs.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Bo Cao, Zhefeng Chen, Hongbin Cao, Chen Zhu, Hongkai Yang, Tianyi Li, Wenqian Xu, Feng Pan, Mingjian Zhang
Summary: Li+/Na+ exchange is an effective method for preparing high-performance Mn-based layered cathodes for Li-ion batteries. However, the detailed structural changes during the ion-exchange process are less studied. This study combines in situ synchrotron X-ray diffraction, density functional theory calculations, and electrochemical tests to investigate the structural changes during the ion-exchange process of an Mn-only layered cathode. The findings reveal the thermodynamic favorability of Li+/Na+ exchange and the presence of two tandem topotactic phase transitions.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Wei-Wei Li, Xiang-Jun Zhang, Jiang-Ju Si, Jie Yang, Xue-Yi Sun
Summary: In this study, spherical LiNi0.9Co0.08Al0.02O2 powders with 0.4 wt% TiO2 coating layer were prepared by impregnation-hydrolysis method. The TiO2 coating layer effectively improved the cycling performance and stability of the electrode at a high discharge ratio.
Article
Chemistry, Physical
Morteza Torabi, S. K. Sadrnezhaad
Summary: This study used NiTi thin film and polypyrrole microfibrils to create flexible and high-power lithium-ion batteries. The microfibrils improved the electron pathway and rate capability, while also enhancing the safety of the batteries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Chang Won Park, Jung-Hun Lee, Jae Kwon Seo, Weerawat To A. Ran, Dongmok Whang, Soo Min Hwang, Young-Jun Kim
Summary: This study introduced graphene/polyvinylidene fluoride (Gr/PVdF) composites in Ni-rich oxide cathodes for LIBs, achieving high cycling stability, improved areal and volumetric capacities, and suggesting a viable strategy for replacing conventional conducting agents and enhancing the electrochemical performance of Ni-rich cathodes.
Article
Polymer Science
Mir Waqas Alam, Amal BaQais, Mohammed M. Rahman, Muhammad Aamir, Alaaedeen Abuzir, Shehla Mushtaq, Muhammad Nasir Amin, Muhammad Shuaib Khan
Summary: In this study, carbon-coated ZnFe2O4 was successfully synthesized and the results showed that carbon coating can effectively alleviate the volume expansion problem of ZnFe2O4 during charging and discharging, thus improving the electrochemical performance of the battery.
Article
Chemistry, Physical
M. G. Moustafa, Moustafa M. S. Sanad
Summary: The ZnAl2O4-coated LiFePO4 electrode prepared via polypropylene glycol-assisted sol-gel method showed improved crystallinity, stability, and electrochemical performance, making it a promising cathode material for future development.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Jijian Xu, Travis P. Pollard, Chongyin Yang, Naveen K. Dandu, Sha Tan, Jigang Zhou, Jian Wang, Xinzi He, Xiyue Zhang, Ai-Min Li, Enyuan Hu, Xiao-Qing Yang, Anh Ngo, Oleg Borodin, Chunsheng Wang
Summary: Liquefying halogen or inter-halogen compounds is crucial for achieving high reversibility in lithium halide cathodes. This can be done using interhalogen compounds with different electronegativity or by lowering the temperature. By demonstrating reversible LiCl conversion-intercalation chemistry in organic electrolytes, high reversible specific capacity is achieved in LiCl-LiBr-graphite cathodes at a lower cost than transition metal oxide cathodes.
Article
Energy & Fuels
Rambabu Sydam, Manoranjan Ojha, Melepurath Deepa
Summary: The addition of a disodium salt of ethylenediamine tetra acetic acid (EDTA) to the ionogel electrolyte addresses the issue of poor efficiency and undesirable stacking in Heptyl viologen (HV) based electrochromic devices, resulting in improved performance metrics and thermal robustness.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2021)
Article
Energy & Fuels
Manoranjan Ojha, Xinhua Liu, Billy Wu, Melepurath Deepa
Summary: The study developed supercapacitors using holey graphitic carbon nano-flakes with high specific capacitance for the first time, achieving significant enhancement in performance by applying a unique structure design and carbon fabric for additional conductivity. The peak energy and power densities of the cell were superior to many reported nano-carbons, demonstrating excellent potential for high-performance energy storage applications.
Article
Chemistry, Physical
Manoranjan Ojha, Billy Wu, Melepurath Deepa
Summary: The research investigates the impact of different electrolytes on the performance of a supercapacitor, with findings indicating that the aqueous H+-ion-based CSA electrolyte outperforms other electrolytes, displaying higher ionic conductivity and transport number for improved energy storage performance.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Sathish Deshagani, Debanjan Maity, Aparajita Das, Melepurath Deepa
Summary: The study utilized a hierarchical heterostructure of NiMoO4PNiMnCo2O4 (Nmop NMCO) and PProDOT to construct a supercapacitor with high specific capacitance, cycle life, and energy density. Coupling the supercapacitor with an electrochromic device enabled efficient energy utilization and energy savings.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Electrochemistry
Ishita Naskar, Sathish Deshagani, Melepurath Deepa
Summary: The ASC constructed from zinc cobaltite micro-star shaped porous superstructure coated with zinc oxide nano stubs and coupled with porous flaky activated carbon from green tea exhibits greatly enhanced performance parameters, with increased specific capacitance, energy and power density. The sub-stoichiometry in the ZnO overlayer enhances electrical conductivity and overall electron circulation, leading to deep electrolyte penetration and sufficient ion-accommodation sites in the composite.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Applied
Debanjan Maity, Saurabh Kumar Pathak, Melepurath Deepa
Summary: Liquid junction solar cell (LJSC) with vertically silicon nanowires (SiNWs) as the primary photosensitizer and co-sensitized with luminescent and narrow gap CdTe nanoparticles, along with cuboidal microstructures of zinc tetraphenyl porphyrin (ZnTPP) dye, demonstrated a maximum power conversion efficiency of 9.09%. The cosensitization approach significantly improved the overall performance of the solar cell by suppressing back electron transfer and enhancing electrical conduction. Optimization of the counter electrode (CE) components revealed that the choice of dopant anion affects the polymer surface properties and overall PCE.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Engineering, Environmental
Ankita Kolay, Heather Flint, Elizabeth A. Gibson, Melepurath Deepa
Summary: This article introduces a tandem photoelectrochemical cell that can capture and convert visible light to near infrared light with high power conversion efficiency. The device consists of a nickel oxide photocathode sensitized with silver bismuth sulfide quantum dots, and a cadmium sulfide-sensitized titania photoanode. Trigonal-selenium sub-microtubes are anchored to the photoanode to enhance conductivity and increase device performance. The study provides insights into the charge flow mechanism in this unique device based on favorable energy level alignment.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Energy & Fuels
Ankita Kolay, Debanjan Maity, Heather Flint, Elizabeth A. Gibson, Melepurath Deepa
Summary: In this study, a cost-effective photoelectrochromic energy conversion unit for self-powered smart window applications was developed. It was found that coating silver nanowires on the V2O5 film can improve the electrochromic and electrochemical performance of the device, resulting in better optical contrast. The novel design of the photoelectrochromic and photovoltaic outputs showed high modulation efficiency and power conversion efficiency.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2022)
Article
Nanoscience & Nanotechnology
Debanjan Maity, Babneet Kaur, Partha Ghosal, Melepurath Deepa
Summary: A unique liquid junction solar cell (LJSC) architecture has been developed, incorporating p-type hole transporting CoS nanoflakes and n-type textured silicon, resulting in a high power conversion efficiency. The use of a ferrocene/ferrocenium redox couple electrolyte and an electrocatalytic counter electrode film anchored with antimony nanostructures on tungsten oxide further enhances the performance.
ACS APPLIED NANO MATERIALS
(2022)
Article
Energy & Fuels
Ishita Naskar, Partha Ghosal, Melepurath Deepa
Summary: In this study, a unique binder-free composite cathode ZnCo2S4@MgCo2O4 is reported, which exhibits high electrical conductivity, fast ion diffusion, and abundant electrolyte-electroactive site interactions, leading to excellent capacitance performance and cycle life. The effect of different electrolytes on the redox behavior is evaluated, and the potential application of this configuration in consumer-electronic-devices is demonstrated.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Sathish Deshagani, Ishita Naskar, Gaurav Ganesh Padval, Partha Ghosal, Melepurath Deepa
Summary: Semiconducting cobalt tungstate and zinc ferrite materials were used to fabricate a high-performance asymmetric supercapacitor (ASC) with high room-temperature electrical conductivities. The study also analyzed the effects of different electrolytes on the performance of the ASC.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Babneet Kaur, Souvik Naskar, Partha Ghosal, Melepurath Deepa
Summary: A non-aqueous zinc ion battery with a wide operational voltage window and high Coulombic efficiency was successfully fabricated. The battery overcomes structural instability and low electrical conductivity issues in both the cathode and the anode by using a conducting polymer layer. The cathode consists of VS4 nanoflowers and carbon nanotubes, outperforming pristine VS4 nanoflowers due to enhanced electrical conductivity, easy electron and ion transfer and transport, effective buffering of volume changes, and better accessibility of active sites. This work lays the foundation for developing zinc ion batteries with ultra-long lifespan and high energy density as advanced energy storage systems.
APPLIED SURFACE SCIENCE
(2023)
Review
Materials Science, Multidisciplinary
Pendyala Naresh Kumar, Aparajita Das, Ankita Kolay, Melepurath Deepa
Summary: This review discusses the strategies for developing low-cost quantum dot solar cells. By effectively utilizing passivation layers, alloyed QDs, and novel catalytic counter electrodes, the power conversion efficiencies have been significantly increased.
MATERIALS ADVANCES
(2022)
Article
Electrochemistry
Souvik Naskar, Melepurath Deepa
Summary: Utilizing a zinc vanadate@textured carbon (ZnV2O4@TC) composite cathode and Zn-anode in a non-aqueous zinc-ion battery (ZIB), along with a ZIF-8 metal-organic framework (MOF) layer at the separator facing the cathode, leads to improved cyclability, rate capability, stability, and durability of the battery system.
BATTERIES & SUPERCAPS
(2022)
Article
Chemistry, Physical
Ankita Kolay, Manoranjan Ojha, Melepurath Deepa
Summary: Anchor ionic liquid-functionalized graphene nanoparticles to silicon nanowires improves solar spectral utilization and enhances power conversion efficiency. The quasi-solid solar cell with this architecture delivers the best PCE with good reproducibility and stability. Detailed characterization explains the improved performance in the presence of IL-GNP and gel electrolyte.
SUSTAINABLE ENERGY & FUELS
(2021)