期刊
POLYMER CHEMISTRY
卷 6, 期 26, 页码 4794-4800出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5py00654f
关键词
-
资金
- National Natural Science Foundation of China [91027040, 21174094, 21374069, 21104051]
Fe(0) powder-catalyzed one-pot reaction was successfully employed to design linear and star polymers in a well-controlled manner by combining ambient temperature living radical polymerization and click chemistry. The polymerization behavior possessed the characteristics of living/controlled radical polymerization: the first-order kinetic plots, narrow molecular weight distribution (PDI < 1.4), the linear relationship between molecular weights and the monomer conversions and the successful chain-extension with a NIPAAM monomer. Furthermore, the NMR and MALDI-TOF-MS data indicated that the Fe(0)catalyzed one-pot strategy is different from our reported Cu(0)-catalyzed one-pot strategies to make the targeted polymers.
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