期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 156, 期 9, 页码 B1004-B1021出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3148331
关键词
charge exchange; electrochemical electrodes; hydrogen; nickel compounds; oxidation; solid oxide fuel cells; surface chemistry; yttrium compounds; zirconium compounds
资金
- Office of Naval Research [N00014-051-0339]
A computational model is developed to represent the coupled behavior of elementary chemistry, electrochemistry, and transport in the vicinity of solid-oxide fuel cell three-phase boundaries. The model is applied to assist the development and evaluation of H-2 charge-transfer reaction mechanisms for Ni-yttria-stabilized zirconia (YSZ) anodes. Elementary chemistry and surface transport for the Ni and YSZ surfaces are derived from prior literature. Previously published patterned-anode experiments [J. Mizusaki , Solid State Ionics, 70/71, 52 (1994)] are used to evaluate alternative electrochemical charge-transfer mechanisms. The results show that a hydrogen-spillover mechanism can explain the Mizusaki polarization measurements over wide ranges of gas-phase composition with both anodic and cathodic biases.
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